Synthesis of Stable Salts Containing the Hydridophosphate Anion [P(C2F5)(3)F2H](-)

Bader J, Ignat'ev N, Hoge B (2018)
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2018(7): 861-866.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Abstract / Bemerkung
The reaction of the industrial product (C2F5)(3)PF2 with LiAlH4 in THF solution selectively furnished the hydridophosphate anion [P(C2F5)(3)F2H](-). The compound [PPh4][P(C2F5)(3)F2H] is obtained as a colorless solid on a multigram scale by salt metathesis in aqueous THF. Combining [P(C2F5)(3)F2H](-) with various imidazolium and pyridinium cations affords ionic liquids with melting points well below room temperature. (C2F5)(3)PF2 also abstracts hydrides from amines, affording the hydridophosphate anion [P(C2F5)(3)F2H](-) and the corresponding imminium cations which add a second amine moiety by intra- or intermolecular adduct formation.
Stichworte
Hydridophosphates; Anions; Hydride abstraction; Fluorine; Ionic liquids
Erscheinungsjahr
2018
Zeitschriftentitel
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Band
2018
Ausgabe
7
Seite(n)
861-866
ISSN
1434-1948
eISSN
1099-0682
Page URI
https://pub.uni-bielefeld.de/record/2918660

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Bader J, Ignat'ev N, Hoge B. Synthesis of Stable Salts Containing the Hydridophosphate Anion [P(C2F5)(3)F2H](-). EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2018;2018(7):861-866.
Bader, J., Ignat'ev, N., & Hoge, B. (2018). Synthesis of Stable Salts Containing the Hydridophosphate Anion [P(C2F5)(3)F2H](-). EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2018(7), 861-866. doi:10.1002/ejic.201701375
Bader, J., Ignat'ev, N., and Hoge, B. (2018). Synthesis of Stable Salts Containing the Hydridophosphate Anion [P(C2F5)(3)F2H](-). EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2018, 861-866.
Bader, J., Ignat'ev, N., & Hoge, B., 2018. Synthesis of Stable Salts Containing the Hydridophosphate Anion [P(C2F5)(3)F2H](-). EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2018(7), p 861-866.
J. Bader, N. Ignat'ev, and B. Hoge, “Synthesis of Stable Salts Containing the Hydridophosphate Anion [P(C2F5)(3)F2H](-)”, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, vol. 2018, 2018, pp. 861-866.
Bader, J., Ignat'ev, N., Hoge, B.: Synthesis of Stable Salts Containing the Hydridophosphate Anion [P(C2F5)(3)F2H](-). EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2018, 861-866 (2018).
Bader, Julia, Ignat'ev, Nikolai, and Hoge, Berthold. “Synthesis of Stable Salts Containing the Hydridophosphate Anion [P(C2F5)(3)F2H](-)”. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2018.7 (2018): 861-866.

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