Novel aryl-substituted silanes Part II: Synthesis and characterization of diaryl silicon dihydrides

Binder J, Fischer RC, Flock M, Stammler H-G, Torvisco A, Uhlig F (2016)
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS 191(3): 478-487.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Abstract / Bemerkung
A series of novel and previously published silicon dihydrides, R2SiH2 (R = benzyl, fluorenyl, p-tolyl, p-n-butyl, p-biphenyl, m-tolyl, o-tolyl, 2,4-xylyl, 2,6-xylyl, p-biphenyl, 1-naphthyl, 9-anthracenyl), were synthesized and characterized using H-1, C-13, and Si-29 NMR spectroscopy. Effects of substituent bulk on Si-29 NMR shifts are compared between reported silicon dihydrides species and novel dihydrides herein. In addition, single crystal X-ray diffraction was employed to elucidate the molecular structure of all solid silicon dihydrides and the at room temperature liquid p-tolyl(2)SiH(2). These compounds display non-covalent intermolecular interactions in the form of edge to face, pi-pi stacking, and CH3 center dot center dot center dot pi interactions. The dependency of substituent type on the nature of interactions present will be highlighted and discussed.
Stichworte
solid state structures; Silicon dihydrides; intermolecular interactions; Si-29 NMR
Erscheinungsjahr
2016
Zeitschriftentitel
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
Band
191
Ausgabe
3
Seite(n)
478-487
ISSN
1042-6507
eISSN
1563-5325
Page URI
https://pub.uni-bielefeld.de/record/2917154

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Binder J, Fischer RC, Flock M, Stammler H-G, Torvisco A, Uhlig F. Novel aryl-substituted silanes Part II: Synthesis and characterization of diaryl silicon dihydrides. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS. 2016;191(3):478-487.
Binder, J., Fischer, R. C., Flock, M., Stammler, H. - G., Torvisco, A., & Uhlig, F. (2016). Novel aryl-substituted silanes Part II: Synthesis and characterization of diaryl silicon dihydrides. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 191(3), 478-487. doi:10.1080/10426507.2015.1094657
Binder, J., Fischer, R. C., Flock, M., Stammler, H. - G., Torvisco, A., and Uhlig, F. (2016). Novel aryl-substituted silanes Part II: Synthesis and characterization of diaryl silicon dihydrides. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS 191, 478-487.
Binder, J., et al., 2016. Novel aryl-substituted silanes Part II: Synthesis and characterization of diaryl silicon dihydrides. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 191(3), p 478-487.
J. Binder, et al., “Novel aryl-substituted silanes Part II: Synthesis and characterization of diaryl silicon dihydrides”, PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, vol. 191, 2016, pp. 478-487.
Binder, J., Fischer, R.C., Flock, M., Stammler, H.-G., Torvisco, A., Uhlig, F.: Novel aryl-substituted silanes Part II: Synthesis and characterization of diaryl silicon dihydrides. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS. 191, 478-487 (2016).
Binder, Judith, Fischer, Roland C., Flock, Michaela, Stammler, Hans-Georg, Torvisco, Ana, and Uhlig, Frank. “Novel aryl-substituted silanes Part II: Synthesis and characterization of diaryl silicon dihydrides”. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS 191.3 (2016): 478-487.