Novel aryl-substituted silanes Part II: Synthesis and characterization of diaryl silicon dihydrides

Binder J, Fischer RC, Flock M, Stammler H-G, Torvisco A, Uhlig F (2016)
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS 191(3): 478-487.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
A series of novel and previously published silicon dihydrides, R2SiH2 (R = benzyl, fluorenyl, p-tolyl, p-n-butyl, p-biphenyl, m-tolyl, o-tolyl, 2,4-xylyl, 2,6-xylyl, p-biphenyl, 1-naphthyl, 9-anthracenyl), were synthesized and characterized using H-1, C-13, and Si-29 NMR spectroscopy. Effects of substituent bulk on Si-29 NMR shifts are compared between reported silicon dihydrides species and novel dihydrides herein. In addition, single crystal X-ray diffraction was employed to elucidate the molecular structure of all solid silicon dihydrides and the at room temperature liquid p-tolyl(2)SiH(2). These compounds display non-covalent intermolecular interactions in the form of edge to face, pi-pi stacking, and CH3 center dot center dot center dot pi interactions. The dependency of substituent type on the nature of interactions present will be highlighted and discussed.
Erscheinungsjahr
Zeitschriftentitel
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
Band
191
Ausgabe
3
Seite(n)
478-487
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eISSN
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Binder J, Fischer RC, Flock M, Stammler H-G, Torvisco A, Uhlig F. Novel aryl-substituted silanes Part II: Synthesis and characterization of diaryl silicon dihydrides. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS. 2016;191(3):478-487.
Binder, J., Fischer, R. C., Flock, M., Stammler, H. - G., Torvisco, A., & Uhlig, F. (2016). Novel aryl-substituted silanes Part II: Synthesis and characterization of diaryl silicon dihydrides. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 191(3), 478-487. doi:10.1080/10426507.2015.1094657
Binder, J., Fischer, R. C., Flock, M., Stammler, H. - G., Torvisco, A., and Uhlig, F. (2016). Novel aryl-substituted silanes Part II: Synthesis and characterization of diaryl silicon dihydrides. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS 191, 478-487.
Binder, J., et al., 2016. Novel aryl-substituted silanes Part II: Synthesis and characterization of diaryl silicon dihydrides. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 191(3), p 478-487.
J. Binder, et al., “Novel aryl-substituted silanes Part II: Synthesis and characterization of diaryl silicon dihydrides”, PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, vol. 191, 2016, pp. 478-487.
Binder, J., Fischer, R.C., Flock, M., Stammler, H.-G., Torvisco, A., Uhlig, F.: Novel aryl-substituted silanes Part II: Synthesis and characterization of diaryl silicon dihydrides. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS. 191, 478-487 (2016).
Binder, Judith, Fischer, Roland C., Flock, Michaela, Stammler, Hans-Georg, Torvisco, Ana, and Uhlig, Frank. “Novel aryl-substituted silanes Part II: Synthesis and characterization of diaryl silicon dihydrides”. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS 191.3 (2016): 478-487.