Groundwater responses to recharge in the Gacka Area, Croatia, as revealed by stable isotopes, tritium, CFCs and noble gases

Han L-F, Roller-Lutz Z, Hunjak T, Lutz HO, Matsumoto T, Aggarwal P (2017)
GEOCHEMICAL JOURNAL 51(5): 391-407.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Autor*in
Han, Liang-Feng; Roller-Lutz, Zvjezdana; Hunjak, Tamara; Lutz, Hans OttoUniBi; Matsumoto, Takuya; Aggarwal, Pradeep
Abstract / Bemerkung
Due to their extreme anisotropy and heterogeneity, the hydrogeological characterization of karst terrains is notoriously difficult. Approximately 50% of Croatia consist of karst aquifers, in particular the touristically important region along the Adriatic coast. Being an important water reservoir for this area, we have chosen the Gacka area of Croatia as a typical example. We studied the mixing of groundwater and the responses to recharge in several karst springs by using environmental tracers, including stable isotopes in water (O-18, H-2), tritium (H-3), chlorofluorocarbons (CFCs) and noble gases (He-3, He-4, Ne, Ar, Kr, Xe). The variation of the stable isotopic signal (delta O-18 and delta H-2) in the spring discharges provides qualitative information on the mixing of waters with different transit time. Assuming piston flow in the system, the CFC and H-3 data indicate that the waters contain mainly post-1980 recharge. The CFC concentrations in the spring waters were found to be significantly different between wet and dry weather periods. The higher CFC values during the wet weather period indicate that the waters contained some water components that have relatively short mean residence times. An important finding of the study was that the sole application of tritium-helium methods does not permit an accurate age determination. This is due to mass exchange between liquid and gaseous phases occurring in karst aquifer systems particularly in dry weather periods. During such a dry weather period, more space in the karst groundwater system is not filled with water compared with a wet weather period. It is shown in this study, however, that the combined use of stable isotopes (O-18, H-2), tritium, CFCs and noble gases is able to account for groundwater mixing and responses to recharge in this specific scenario. Compared to single-tracer studies, multi-tracer techniques will allow a much better understanding and characterization of these systems. This information is vital for the assessment of resources and potential contamination of the groundwater in this special environment.
Stichworte
groundwater dating and mixing; environmental tracers; multiple tracer; techniques; karst; Croatia
Erscheinungsjahr
2017
Zeitschriftentitel
GEOCHEMICAL JOURNAL
Band
51
Ausgabe
5
Seite(n)
391-407
ISSN
0016-7002
eISSN
1880-5973
Page URI
https://pub.uni-bielefeld.de/record/2916581

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Han L-F, Roller-Lutz Z, Hunjak T, Lutz HO, Matsumoto T, Aggarwal P. Groundwater responses to recharge in the Gacka Area, Croatia, as revealed by stable isotopes, tritium, CFCs and noble gases. GEOCHEMICAL JOURNAL. 2017;51(5):391-407.
Han, L. - F., Roller-Lutz, Z., Hunjak, T., Lutz, H. O., Matsumoto, T., & Aggarwal, P. (2017). Groundwater responses to recharge in the Gacka Area, Croatia, as revealed by stable isotopes, tritium, CFCs and noble gases. GEOCHEMICAL JOURNAL, 51(5), 391-407. doi:10.2343/geochemj.2.0440
Han, L. - F., Roller-Lutz, Z., Hunjak, T., Lutz, H. O., Matsumoto, T., and Aggarwal, P. (2017). Groundwater responses to recharge in the Gacka Area, Croatia, as revealed by stable isotopes, tritium, CFCs and noble gases. GEOCHEMICAL JOURNAL 51, 391-407.
Han, L.-F., et al., 2017. Groundwater responses to recharge in the Gacka Area, Croatia, as revealed by stable isotopes, tritium, CFCs and noble gases. GEOCHEMICAL JOURNAL, 51(5), p 391-407.
L.-F. Han, et al., “Groundwater responses to recharge in the Gacka Area, Croatia, as revealed by stable isotopes, tritium, CFCs and noble gases”, GEOCHEMICAL JOURNAL, vol. 51, 2017, pp. 391-407.
Han, L.-F., Roller-Lutz, Z., Hunjak, T., Lutz, H.O., Matsumoto, T., Aggarwal, P.: Groundwater responses to recharge in the Gacka Area, Croatia, as revealed by stable isotopes, tritium, CFCs and noble gases. GEOCHEMICAL JOURNAL. 51, 391-407 (2017).
Han, Liang-Feng, Roller-Lutz, Zvjezdana, Hunjak, Tamara, Lutz, Hans Otto, Matsumoto, Takuya, and Aggarwal, Pradeep. “Groundwater responses to recharge in the Gacka Area, Croatia, as revealed by stable isotopes, tritium, CFCs and noble gases”. GEOCHEMICAL JOURNAL 51.5 (2017): 391-407.

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