Silylene-Functionalized N-Heterocyclic Carbene (Si−NHC)

Rottschäfer D, Blomeyer S, Neumann B, Stammler H-G, Ghadwal R (2018)
Chemistry - A European Journal 24(2): 380-387.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
Download
Es wurden keine Dateien hochgeladen. Nur Publikationsnachweis!
DOI
Autor*in
Rottschäfer, DennisUniBi; Blomeyer, SebastianUniBi ; Neumann, BeateUniBi; Stammler, Hans-GeorgUniBi; Ghadwal, RajendraUniBi
Einrichtung
Fakultät für Chemie > Anorganische Chemie und Strukturchemie
Erscheinungsjahr
2018
Zeitschriftentitel
Chemistry - A European Journal
Band
24
Ausgabe
2
Seite(n)
380-387
ISSN
0947-6539
eISSN
1521-3765
Page URI
https://pub.uni-bielefeld.de/record/2914558

Zitieren

Rottschäfer D, Blomeyer S, Neumann B, Stammler H-G, Ghadwal R. Silylene-Functionalized N-Heterocyclic Carbene (Si−NHC). Chemistry - A European Journal. 2018;24(2):380-387.
Rottschäfer, D., Blomeyer, S., Neumann, B., Stammler, H. - G., & Ghadwal, R. (2018). Silylene-Functionalized N-Heterocyclic Carbene (Si−NHC). Chemistry - A European Journal, 24(2), 380-387. doi:10.1002/chem.201703530
Rottschäfer, Dennis, Blomeyer, Sebastian, Neumann, Beate, Stammler, Hans-Georg, and Ghadwal, Rajendra. 2018. “Silylene-Functionalized N-Heterocyclic Carbene (Si−NHC)”. Chemistry - A European Journal 24 (2): 380-387.
Rottschäfer, D., Blomeyer, S., Neumann, B., Stammler, H. - G., and Ghadwal, R. (2018). Silylene-Functionalized N-Heterocyclic Carbene (Si−NHC). Chemistry - A European Journal 24, 380-387.
Rottschäfer, D., et al., 2018. Silylene-Functionalized N-Heterocyclic Carbene (Si−NHC). Chemistry - A European Journal, 24(2), p 380-387.
D. Rottschäfer, et al., “Silylene-Functionalized N-Heterocyclic Carbene (Si−NHC)”, Chemistry - A European Journal, vol. 24, 2018, pp. 380-387.
Rottschäfer, D., Blomeyer, S., Neumann, B., Stammler, H.-G., Ghadwal, R.: Silylene-Functionalized N-Heterocyclic Carbene (Si−NHC). Chemistry - A European Journal. 24, 380-387 (2018).
Rottschäfer, Dennis, Blomeyer, Sebastian, Neumann, Beate, Stammler, Hans-Georg, and Ghadwal, Rajendra. “Silylene-Functionalized N-Heterocyclic Carbene (Si−NHC)”. Chemistry - A European Journal 24.2 (2018): 380-387.

4 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

The Viability of C5-Protonated- and C4,C5-Ditopic Carbanionic Abnormal NHCs: A New Dimension in NHC Chemistry.
Rottschäfer D, Ebeler F, Strothmann T, Neumann B, Stammler HG, Mix A, Ghadwal RS., Chemistry 24(15), 2018
PMID: 29363830
Crystalline Radicals Derived from Classical N-Heterocyclic Carbenes.
Rottschäfer D, Neumann B, Stammler HG, van Gastel M, Andrada DM, Ghadwal RS., Angew Chem Int Ed Engl 57(17), 2018
PMID: 29465816
N-Heterocyclic Carbene Analogues of Thiele and Chichibabin Hydrocarbons.
Rottschäfer D, Ho NKT, Neumann B, Stammler HG, van Gastel M, Andrada DM, Ghadwal RS., Angew Chem Int Ed Engl 57(20), 2018
PMID: 29668119
Bis(oxazoline)-derived N-heterocyclic carbene ligated rare-earth metal complexes: synthesis, structure, and polymerization performance.
Pan Y, Zhao A, Li Y, Li W, So YM, Yan X, He G., Dalton Trans 47(39), 2018
PMID: 30027182

126 References

Daten bereitgestellt von Europe PubMed Central.


AUTHOR UNKNOWN, 0
Reactivity in the periphery of functionalised multiple bonds of heavier group 14 elements.
Prasang C, Scheschkewitz D., Chem Soc Rev 45(4), 2015
PMID: 26503807
Dichlorosilylene: a high temperature transient species to an indispensable building block.
Ghadwal RS, Azhakar R, Roesky HW., Acc. Chem. Res. 46(2), 2012
PMID: 23181482
Group 14 hydrides with low valent elements for activation of small molecules.
Mandal SK, Roesky HW., Acc. Chem. Res. 45(2), 2011
PMID: 21882810
N-heterocyclic carbene analogues with low-valent group 13 and group 14 elements: syntheses, structures, and reactivities of a new generation of multitalented ligands.
Asay M, Jones C, Driess M., Chem. Rev. 111(2), 2010
PMID: 21133370
Covalent functionalization of graphene with reactive intermediates.
Park J, Yan M., Acc. Chem. Res. 46(1), 2012
PMID: 23116448

Timms, Chem. Soc. Rev. 25(), 1996
Beyond catalysis: N-heterocyclic carbene complexes as components for medicinal, luminescent, and functional materials applications.
Mercs L, Albrecht M., Chem Soc Rev 39(6), 2010
PMID: 20502793

AUTHOR UNKNOWN, 0
Cyclic (alkyl)(amino)carbenes (CAACs): stable carbenes on the rise.
Soleilhavoup M, Bertrand G., Acc. Chem. Res. 48(2), 2014
PMID: 25515548
Carbene-Stabilized Main Group Radicals and Radical Ions.
Martin CD, Soleilhavoup M, Bertrand G., Chem Sci 4(8), 2013
PMID: 23878717

Rovis, Synlett 24(), 2013
Stable singlet carbenes as mimics for transition metal centers.
Martin D, Soleilhavoup M, Bertrand G., Chem Sci 2(3), 2011
PMID: 21743834
An overview of N-heterocyclic carbenes.
Hopkinson MN, Richter C, Schedler M, Glorius F., Nature 510(7506), 2014
PMID: 24965649

AUTHOR UNKNOWN, 0
New bonding modes of carbon and heavier group 14 atoms Si-Pb.
Frenking G, Tonner R, Klein S, Takagi N, Shimizu T, Krapp A, Pandey KK, Parameswaran P., Chem Soc Rev 43(14), 2014
PMID: 24916774

Tokitoh, Coord. Chem. Rev. 210(), 2000
Stable heavier carbene analogues.
Mizuhata Y, Sasamori T, Tokitoh N., Chem. Rev. 109(8), 2009
PMID: 19630390
Synthesis, structure and reactivity of a donor-stabilised silylene with a bulky bidentate benzamidinato ligand.
Tacke R, Kobelt C, Baus JA, Bertermann R, Burschka C., Dalton Trans 44(33), 2015
PMID: 26228381
New vistas in N-heterocyclic silylene (NHSi) transition-metal coordination chemistry: syntheses, structures and reactivity towards activation of small molecules.
Blom B, Stoelzel M, Driess M., Chemistry 19(1), 2012
PMID: 23229274

AUTHOR UNKNOWN, 0

Staudinger, Chem. Ber. 45(), 1912

Buchner, Chem. Ber. 36(), 1903

Doering, J. Am. Chem. Soc. 76(), 1954

Arduengo, J. Am. Chem. Soc. 113(), 1991

Denk, J. Am. Chem. Soc. 116(), 1994

Kuhn, Chem. Ber. 128(), 1995

AUTHOR UNKNOWN, 0
Stable Carbenes.
Bourissou D, Guerret O, Gabbai FP, Bertrand G., Chem. Rev. 100(1), 2000
PMID: 11749234

Carmalt, 2000

AUTHOR UNKNOWN, 0
Activation of 7-Silanorbornadienes by N-Heterocyclic Carbenes: A Selective Way to N-Heterocyclic-Carbene-Stabilized Silylenes.
Lutters D, Severin C, Schmidtmann M, Muller T., J. Am. Chem. Soc. 138(18), 2016
PMID: 27120697
Synthesis of a Bent 2-Silaallene with a Perturbed Electronic Structure from a Cyclic Alkyl(amino) Carbene-Diiodosilylene.
Li Y, Chan YC, Li Y, Purushothaman I, De S, Parameswaran P, So CW., Inorg Chem 55(17), 2016
PMID: 27560615
Si=Si Double Bonds: Synthesis of an NHC-Stabilized Disilavinylidene.
Ghana P, Arz MI, Das U, Schnakenburg G, Filippou AC., Angew. Chem. Int. Ed. Engl. 54(34), 2015
PMID: 26136260

AUTHOR UNKNOWN, Angew. Chem. 127(), 2015
Carbene-dichlorosilylene stabilized phosphinidenes exhibiting strong intramolecular charge transfer transition.
Roy S, Stollberg P, Herbst-Irmer R, Stalke D, Andrada DM, Frenking G, Roesky HW., J. Am. Chem. Soc. 137(1), 2014
PMID: 25539016
A dihydrodisilene transition metal complex from an N-heterocyclic carbene-stabilized silylene monohydride.
Inoue S, Eisenhut C., J. Am. Chem. Soc. 135(49), 2013
PMID: 24252067
Equilibrium between a cyclotrisilene and an isolable base adduct of a disilenyl silylene.
Cowley MJ, Huch V, Rzepa HS, Scheschkewitz D., Nat Chem 5(10), 2013
PMID: 24056345
A stable singlet biradicaloid siladicarbene: (L:)2Si.
Mondal KC, Roesky HW, Schwarzer MC, Frenking G, Niepotter B, Wolf H, Herbst-Irmer R, Stalke D., Angew. Chem. Int. Ed. Engl. 52(10), 2013
PMID: 23307744

AUTHOR UNKNOWN, Angew. Chem. 125(), 2013

AUTHOR UNKNOWN, 0
Lewis base stabilized dichlorosilylene.
Ghadwal RS, Roesky HW, Merkel S, Henn J, Stalke D., Angew. Chem. Int. Ed. Engl. 48(31), 2009
PMID: 19551793

AUTHOR UNKNOWN, Angew. Chem. 121(), 2009
Silylation of N-heterocyclic carbene with aminochlorosilane and -disilane: dehydrohalogenation vs. Si-Si bond cleavage.
Cui H, Cui C., Dalton Trans 40(44), 2011
PMID: 21984019
Facile access to silyl-functionalized N-heterocyclic olefins with HSiCl3.
Ghadwal RS, Reichmann SO, Engelhardt F, Andrada DM, Frenking G., Chem. Commun. (Camb.) 49(82), 2013
PMID: 24005446
Lewis base mediated dismutation of trichlorosilane.
Singh AP, Ghadwal RS, Roesky HW, Holstein JJ, Dittrich B, Demers JP, Chevelkov V, Lange A., Chem. Commun. (Camb.) 48(61), 2012
PMID: 22735667
Donor-acceptor stabilized silaformyl chloride.
Ghadwal RS, Azhakar R, Roesky HW, Propper K, Dittrich B, Goedecke C, Frenking G., Chem. Commun. (Camb.) 48(66), 2012
PMID: 22786582
Donor-acceptor-stabilized silicon analogue of an acid anhydride.
Ghadwal RS, Azhakar R, Roesky HW, Propper K, Dittrich B, Klein S, Frenking G., J. Am. Chem. Soc. 133(44), 2011
PMID: 21999232

AUTHOR UNKNOWN, 0
Intramolecular C-N bond activation and ring-expansion reactions of N-heterocyclic carbenes.
Hemberger P, Bodi A, Berthel JH, Radius U., Chemistry 21(4), 2014
PMID: 25430962
Room temperature ring expansion of N-heterocyclic carbenes and B-B bond cleavage of diboron(4) compounds.
Pietsch S, Paul U, Cade IA, Ingleson MJ, Radius U, Marder TB., Chemistry 21(25), 2015
PMID: 25960171

AUTHOR UNKNOWN, 0
Synthesis of 4- and 4,5-functionalized imidazol-2-ylidenes from a single 4,5-unsubstituted imidazol-2-ylidene.
Mendoza-Espinosa D, Donnadieu B, Bertrand G., J. Am. Chem. Soc. 132(21), 2010
PMID: 20443633
Abnormal reactivity of an N-heterocyclic carbene (NHC) with a phosphaalkene: a route to a 4-phosphino-substituted NHC.
Bates JI, Kennepohl P, Gates DP., Angew. Chem. Int. Ed. Engl. 48(52), 2009
PMID: 19937891

AUTHOR UNKNOWN, Angew. Chem. 121(), 2009
Normal-to-abnormal rearrangement of an N-heterocyclic carbene with a silylene transition metal complex.
Ghadwal RS, Rottschafer D, Andrada DM, Frenking G, Schurmann CJ, Stammler HG., Dalton Trans 46(24), 2017
PMID: 28590484
A facile route to functionalized N-heterocyclic carbenes (NHCs) with NHC base-stabilized dichlorosilylene.
Ghadwal RS, Roesky HW, Granitzka M, Stalke D., J. Am. Chem. Soc. 132(29), 2010
PMID: 20608639
Carbon-based two electron σ-donor ligands beyond classical N-heterocyclic carbenes.
Ghadwal RS., Dalton Trans 45(41), 2016
PMID: 27427200
A viable anionic N-heterocyclic dicarbene.
Wang Y, Xie Y, Abraham MY, Wei P, Schaefer HF 3rd, Schleyer Pv, Robinson GH., J. Am. Chem. Soc. 132(41), 2010
PMID: 20863065

AUTHOR UNKNOWN, 0

Waters, Coord. Chem. Rev. 293-294(), 2015

Nasr, Coord. Chem. Rev. 316(), 2016
A Stable Anionic Dithiolene Radical.
Wang Y, Hickox HP, Xie Y, Wei P, Blair SA, Johnson MK, Schaefer HF 3rd, Robinson GH., J. Am. Chem. Soc. 139(20), 2017
PMID: 28482154

AUTHOR UNKNOWN, 0
Synthesis and structural investigation of R2Si (R = Me, Ph) bridged di-N-heterocyclic carbenes.
Ghadwal RS, Reichmann SO, Carl E, Herbst-Irmer R., Dalton Trans 43(36), 2014
PMID: 25101953
Abnormal carbene-silicon halide complexes.
Wang Y, Xie Y, Wei P, Schaefer HF 3rd, Robinson GH., Dalton Trans 45(14), 2015
PMID: 26605692
Synthesis of mixed silylene-carbene chelate ligands from N-heterocyclic silylcarbenes mediated by nickel.
Tan G, Enthaler S, Inoue S, Blom B, Driess M., Angew. Chem. Int. Ed. Engl. 54(7), 2014
PMID: 25557655

AUTHOR UNKNOWN, Angew. Chem. 127(), 2015
Synthesis and characterization of [PhC(NtBu)2]SiCl: a stable monomeric chlorosilylene.
So CW, Roesky HW, Magull J, Oswald RB., Angew. Chem. Int. Ed. Engl. 45(24), 2006
PMID: 16671135

AUTHOR UNKNOWN, Angew. Chem. 118(), 2006

AUTHOR UNKNOWN, 0

Azhakar, Organometallics 31(), 2012
Facile access to silicon-functionalized bis-silylene titanium(II) complexes.
Blom B, Driess M, Gallego D, Inoue S., Chemistry 18(42), 2012
PMID: 22965659

Sen, Chem. Sci. 3(), 2012
A debut for base stabilized monoalkylsilylenes.
Azhakar R, Ghadwal RS, Roesky HW, Wolf H, Stalke D., Chem. Commun. (Camb.) 48(38), 2012
PMID: 22460291
The group 7 metal carbonyl complexes from a stable heteroleptic silylene PhC(NtBu)2SiNPh2.
Azhakar R, Roesky HW, Holstein JJ, Dittrich B., Dalton Trans 41(39), 2012
PMID: 22914765
From bis(silylene) and bis(germylene) pincer-type nickel(II) complexes to isolable intermediates of the nickel-catalyzed Sonogashira cross-coupling reaction.
Gallego D, Bruck A, Irran E, Meier F, Kaupp M, Driess M, Hartwig JF., J. Am. Chem. Soc. 135(41), 2013
PMID: 24053603
Pushing the σ-donor strength in iridium pincer complexes: bis(silylene) and bis(germylene) ligands are stronger donors than bis(phosphorus(III)) ligands.
Bruck A, Gallego D, Wang W, Irran E, Driess M, Hartwig JF., Angew. Chem. Int. Ed. Engl. 51(46), 2012
PMID: 23073912

AUTHOR UNKNOWN, Angew. Chem. 124(), 2012

AUTHOR UNKNOWN, 0

Verlinden, Eur. J. Inorg. Chem. (), 2015

Liske, Organometallics 32(), 2013

AUTHOR UNKNOWN, 0

Chan, Eur. J. Inorg. Chem. (), 2015
From an Isolable Acyclic Phosphinosilylene Adduct to Donor-Stabilized Si=E Compounds (E=O, S, Se).
Hansen K, Szilvasi T, Blom B, Irran E, Driess M., Chemistry 21(52), 2015
PMID: 26592863
From Silylone to an Isolable Monomeric Silicon Disulfide Complex.
Xiong Y, Yao S, Muller R, Kaupp M, Driess M., Angew. Chem. Int. Ed. Engl. 54(35), 2015
PMID: 26148938

AUTHOR UNKNOWN, Angew. Chem. 127(), 2015
Unique Approach to Copper(I) Silylene Chalcogenone Complexes.
Parvin N, Pal S, Khan S, Das S, Pati SK, Roesky HW., Inorg Chem 56(3), 2017
PMID: 28085259
Synthesis and characterization of [[PhC(NBu(t))2]Si(S)SBu(t)]: a silicon thioester analogue with the Si(=S)-S-skeleton.
So CW, Roesky HW, Oswald RB, Pal A, Jones PG., Dalton Trans (45), 2007
PMID: 18271477

AUTHOR UNKNOWN, 0
Facile Construction of Yttrium Pentasulfides from Yttrium Alkyl Precursors: Synthesis, Mechanism, and Reactivity.
Zhang F, Zhang J, Zhou X., Inorg Chem 56(4), 2017
PMID: 28165721

Srinivas, RSC Adv. 5(), 2015

AUTHOR UNKNOWN, 0

Nelson, Organometallics 33(), 2014
Reactivity studies of silylene [PhC(NtBu)2](C5Me5)Si - reactions with [M(COD)Cl]2 (M = Rh(i), Ir(i)), S, Se, Te, and BH3.
Kaufmann S, Schafer S, Gamer MT, Roesky PW., Dalton Trans 46(27), 2017
PMID: 28489092

Wenski, Chem. Unserer Zeit 37(), 2003

AUTHOR UNKNOWN, 0

Timms, Inorg. Chem. 7(), 1968
Ionic S(N)i-Si Nucleophilic Substitution in N-Methylaniline-Induced Si-Si Bond Cleavages of Si2Cl6.
Zhang J, Xie J, Lee ME, Zhang L, Zuo Y, Feng S., Chemistry 22(14), 2016
PMID: 26916362
A Disilene Base Adduct with a Dative Si-Si Single Bond.
Schweizer JI, Scheibel MG, Diefenbach M, Neumeyer F, Wurtele C, Kulminskaya N, Linser R, Auner N, Schneider S, Holthausen MC., Angew. Chem. Int. Ed. Engl. 55(5), 2015
PMID: 26696311

AUTHOR UNKNOWN, Angew. Chem. 128(), 2016
Chloride-induced aufbau of perchlorinated cyclohexasilanes from Si2Cl6: a mechanistic scenario.
Tillmann J, Meyer L, Schweizer JI, Bolte M, Lerner HW, Wagner M, Holthausen MC., Chemistry 20(30), 2014
PMID: 24771318
Neutral pentacoordinate silicon fluorides derived from amidinate, guanidinate, and triazapentadienate ligands and base-induced disproportionation of Si2Cl6 to stable silylenes.
Ghadwal RS, Propper K, Dittrich B, Jones PG, Roesky HW., Inorg Chem 50(1), 2010
PMID: 21126009
The perchlorinated silanes Si2Cl6 and Si3Cl8 as sources of SiCl2.
Meyer-Wegner F, Nadj A, Bolte M, Auner N, Wagner M, Holthausen MC, Lerner HW., Chemistry 17(17), 2011
PMID: 21425370
IPr3 Si3 Cl5 (+) : A Highly Reactive Cation with Silanide Character.
Uhlemann F, Schnepf A., Chemistry 22(31), 2016
PMID: 27258331

Koe, Angew. Chem. Int. Ed. 37(), 1998

AUTHOR UNKNOWN, Angew. Chem. 110(), 1998
High yield access to silylene RSiCl (R = PhC(NtBu)2) and its reactivity toward alkyne: synthesis of stable disilacyclobutene.
Sen SS, Roesky HW, Stern D, Henn J, Stalke D., J. Am. Chem. Soc. 132(3), 2010
PMID: 20043695

AUTHOR UNKNOWN, 0

Álvarez-Rodríguez, Coord. Chem. Rev. 300(), 2015
Novel transition-metal (M=Cr, Mo, W, Fe) carbonyl complexes with bis(guanidinato)silicon(II) ligands.
Muck FM, Kloss D, Baus JA, Burschka C, Tacke R., Chemistry 20(31), 2014
PMID: 25042407

Blom, Inorg. Chem. Front. 1(), 2014
Facile access to transition-metal-carbonyl complexes with an amidinate-stabilized chlorosilylene ligand.
Azhakar R, Ghadwal RS, Roesky HW, Hey J, Stalke D., Chem Asian J 7(3), 2012
PMID: 22246607
N-heterocyclic carbene stabilized dichlorosilylene transition-metal complexes of V(I), Co(I), and Fe(0).
Ghadwal RS, Azhakar R, Propper K, Holstein JJ, Dittrich B, Roesky HW., Inorg Chem 50(17), 2011
PMID: 21780764

AUTHOR UNKNOWN, 0
Extending N-heterocyclic carbene ligands into the third dimension: a new type of hybrid phosphazane/NHC system.
Roth T, Vasilenko V, Benson CGM, Wadepohl H, Wright DS, Gade LH., Chem Sci 6(4), 2015
PMID: 29308160
Phosphinosilylenes as a novel ligand system for heterobimetallic complexes.
Breit NC, Eisenhut C, Inoue S., Chem. Commun. (Camb.) 52(32), 2016
PMID: 26974121

AUTHOR UNKNOWN, 0

Mata, Chem. Sci. 5(), 2014

Pye, Chem. Sci. 8(), 2017
Selectivity Effects in Bimetallic Catalysis.
Mankad NP., Chemistry 22(17), 2016
PMID: 26879884
Heterobimetallic complexes with redox-active mesoionic carbenes as metalloligands: electrochemical properties, electronic structures and catalysis.
Hettmanczyk L, Manck S, Hoyer C, Hohloch S, Sarkar B., Chem. Commun. (Camb.) 51(54), 2015
PMID: 26063482
Consistent structures and interactions by density functional theory with small atomic orbital basis sets.
Grimme S, Brandenburg JG, Bannwarth C, Hansen A., J Chem Phys 143(5), 2015
PMID: 26254642

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0
Material in PUB:
In sonstiger Relation
Silylene-Functionalized N-Heterocyclic Carbene (Si−NHC)
Rottschäfer D, Blomeyer S, Neumann B, Stammler H-G, Ghadwal R (2018)
Chemistry - A European Journal 24(2): 285-285.
Export

Markieren/ Markierung löschen
Markierte Publikationen

Open Data PUB

Web of Science

Dieser Datensatz im Web of Science®
Quellen

PMID: 28833705
PubMed | Europe PMC

Suchen in

Google Scholar