Anchoring of organic molecules to a metal surface: HtBDC on Cu(110)

Schunack M, Petersen L, Kühnle A, Laegsgaard E, Stensgaard I, Johannsen I, Besenbacher F (2001)
Physical Review Letters 86(3): 456-459.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
OA 566.13 KB
Schunack, Michael; Petersen, L.; Kühnle, AngelikaUniBi; Laegsgaard, E.; Stensgaard, I.; Johannsen, I.; Besenbacher, Flemming
Abstract / Bemerkung
The interaction of largish molecules with metal surfaces has been studied by combining the imaging and manipulation capabilities of the scanning tunneling microscope (STM). At the atomic scale, the STM results directly reveal that the adsorption of a largish organic molecule can induce a restructuring of a metal surface underneath. This restructuring anchors the molecules on the substrate and is the driving force for a self-assembly process of the molecules into characteristic molecular double rows.
Physical Review Letters
Page URI


Schunack M, Petersen L, Kühnle A, et al. Anchoring of organic molecules to a metal surface: HtBDC on Cu(110). Physical Review Letters. 2001;86(3):456-459.
Schunack, M., Petersen, L., Kühnle, A., Laegsgaard, E., Stensgaard, I., Johannsen, I., & Besenbacher, F. (2001). Anchoring of organic molecules to a metal surface: HtBDC on Cu(110). Physical Review Letters, 86(3), 456-459. doi:10.1103/PhysRevLett.86.456
Schunack, M., Petersen, L., Kühnle, A., Laegsgaard, E., Stensgaard, I., Johannsen, I., and Besenbacher, F. (2001). Anchoring of organic molecules to a metal surface: HtBDC on Cu(110). Physical Review Letters 86, 456-459.
Schunack, M., et al., 2001. Anchoring of organic molecules to a metal surface: HtBDC on Cu(110). Physical Review Letters, 86(3), p 456-459.
M. Schunack, et al., “Anchoring of organic molecules to a metal surface: HtBDC on Cu(110)”, Physical Review Letters, vol. 86, 2001, pp. 456-459.
Schunack, M., Petersen, L., Kühnle, A., Laegsgaard, E., Stensgaard, I., Johannsen, I., Besenbacher, F.: Anchoring of organic molecules to a metal surface: HtBDC on Cu(110). Physical Review Letters. 86, 456-459 (2001).
Schunack, Michael, Petersen, L., Kühnle, Angelika, Laegsgaard, E., Stensgaard, I., Johannsen, I., and Besenbacher, Flemming. “Anchoring of organic molecules to a metal surface: HtBDC on Cu(110)”. Physical Review Letters 86.3 (2001): 456-459.
Alle Dateien verfügbar unter der/den folgenden Lizenz(en):
Copyright Statement:
Dieses Objekt ist durch das Urheberrecht und/oder verwandte Schutzrechte geschützt. [...]
Access Level
OA Open Access
Zuletzt Hochgeladen
MD5 Prüfsumme

18 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Tridecacyclene: A Cyclic Tetramer of Acenaphthylene.
Sumy DP, Dodge NJ, Harrison CM, Finke AD, Whalley AC., Chemistry 22(14), 2016
PMID: 26791961
Growth of an oligopyridine adlayer on Ag(100)--a scanning tunnelling microscopy study.
Waldmann T, Nenon C, Hoster HE, Behm RJ., Phys Chem Chem Phys 13(46), 2011
PMID: 21952443
Elementary structural motifs in a random network of cytosine adsorbed on a gold(111) surface.
Otero R, Lukas M, Kelly RE, Xu W, Laegsgaard E, Stensgaard I, Kantorovich LN, Besenbacher F., Science 319(5861), 2008
PMID: 18079368
Strongly reshaped organic-metal interfaces: tetracyanoethylene on Cu(100).
Bedwani S, Wegner D, Crommie MF, Rochefort A., Phys Rev Lett 101(21), 2008
PMID: 19113430
Molecular architectonic on metal surfaces.
Barth JV., Annu Rev Phys Chem 58(), 2007
PMID: 17430091
Observations of image contrast and dimerization of decacyclene by low temperature scanning tunneling microscopy.
Wesoloski LM, Stieg AZ, Kunitake M, Dultz SC, Gimzewski JK., J Chem Phys 127(17), 2007
PMID: 17994838
Scanning tunneling microscopy manipulation of complex organic molecules on solid surfaces.
Otero R, Rosei F, Besenbacher F., Annu Rev Phys Chem 57(), 2006
PMID: 16599819
Evolution of multilevel order in supramolecular assemblies.
Vonau F, Suhr D, Aubel D, Bouteiller L, Reiter G, Simon L., Phys Rev Lett 94(6), 2005
PMID: 15783753
Scanning tunneling microscopy experiments on single molecular landers.
Moresco F, Gourdon A., Proc Natl Acad Sci U S A 102(25), 2005
PMID: 15956190
X-ray-diffraction characterization of Pt(111) surface nanopatterning induced by C60 adsorption.
Felici R, Pedio M, Borgatti F, Iannotta S, Capozi M, Ciullo G, Stierle A., Nat Mater 4(9), 2005
PMID: 16113682
Trapping and moving metal atoms with a six-leg molecule.
Gross L, Rieder KH, Moresco F, Stojkovic SM, Gourdon A, Joachim C., Nat Mater 4(12), 2005
PMID: 16299509
Mesoscopic chiral reshaping of the Ag(110) surface induced by the organic molecule PVBA.
Pascual JI, Barth JV, Ceballos G, Trimarchi G, De Vita A, Kern K, Rust HP., J Chem Phys 120(24), 2004
PMID: 15268168
Growth of unidirectional molecular rows of cysteine on Au(110)-(1 x 2) driven by adsorbate-induced surface rearrangements.
Kühnle A, Molina LM, Linderoth TR, Hammer B, Besenbacher F., Phys Rev Lett 93(8), 2004
PMID: 15447200
Molecular landers as probes for molecular device-metal surface interactions.
Ghosh SC, Zhu X, Secchi A, Sadhukhan SK, Girdhar NK, Gourdon A., Ann N Y Acad Sci 1006(), 2003
PMID: 14976011
Long jumps in the surface diffusion of large molecules.
Schunack M, Linderoth TR, Rosei F, Laegsgaard E, Stensgaard I, Besenbacher F., Phys Rev Lett 88(15), 2002
PMID: 11955208

32 References

Daten bereitgestellt von Europe PubMed Central.

Building Supramolecular Nanostructures at Surfaces by Hydrogen Bonding Fruitful discussions with A. de Vita, B. Muller, and H. Brune are acknowleged.
Barth JV, Weckesser J, Cai C, Gunter P, Burgi L, Jeandupeux O, Kern K., Angew. Chem. Int. Ed. Engl. 39(7), 2000
PMID: 10767015
Observation of a new Au ( 111 ) reconstruction at the interface of an adsorbed C60 overlayer
Gimzewski, Chemical Physics Letters 213(3-4), 1993
Adsorption of alanine on Cu(001) studied by scanning tunneling microscopy
Zhao, Surface Science 442(2), 1999
Functional organic ultra-thin films for device applications
Seto, Thin Solid Films 273(1-2), 1996
Fabrication of molecular alignment at the specific sites on Cu(111) surfaces using self-assembly phenomena
Furukawa, Surface Science 445(1), 2000
Scanning tunneling microscopy of individual molecules: beyond imaging
Gimzewski, Surface Science 386(1-3), 1997
Acetate on Cu(110): evidence for long-range intermolecular interactions and molecular-induced restructuring of a metal surface
Haq, Surface Science 355(1-3), 1996
2,5,8,11,14,17-Hexa-t-butyldecacyclene and 1,7,13-/1,6,12-tri-t-butyldecacyclene: Possible precursors for bowl-shaped polycyclic arenes
Zimmermann, Tetrahedron Letters 37(46), 1996
Transition Metal-Containing Rotaxanes and Catenanes in Motion: Toward Molecular Machines and Motors
Sauvage, Accounts of Chemical Research 31(10), 1998
Adsorption Structures of 1-Octanethiol on Cu(111) Studied by Scanning Tunneling Microscopy
Driver, Langmuir 16(16), 2000

Besenbacher, Nature 398(6723), 1999
Extended surface chirality from supramolecular assemblies of adsorbed chiral molecules
Lorenzo MO, Baddeley CJ, Muryn C, Raval R., Nature 404(6776), 2000
PMID: 10746721
Self-assembly of nanoparticles into structured spherical and network aggregates
Boal AK, Ilhan F, DeRouchey JE, Thurn-Albrecht T, Russell TP, Rotello VM., Nature 404(6779), 2000
PMID: 10783884
Controlled vertical manipulation of single CO molecules with the scanning tunneling microscope: A route to chemical contrast
Bartels, Applied Physics Letters 71(2), 1997
C60 on Al(111): Covalent bonding and surface reconstruction.
Maxwell AJ, Bruhwiler PA, Andersson S, Arvanitis D, Hernnas B, Karis O, Mancini DC, Martensson N, Gray SM, Johansson MK, Johansson LS., Phys. Rev., B Condens. Matter 52(8), 1995
PMID: 9981826
Growth of C60 on Cu(110) and Ni(110) surfaces: C60-induced interfacial roughening
Murray, Physical Review B 55(15), 1997
Cooperative self-assembly of Au atoms and C60 on Au(110) surfaces.
Gimzewski JK, Modesti S, Schlittler RR., Phys. Rev. Lett. 72(7), 1994
PMID: 10056601
Study of C60/Au(110)-p(6x5) reconstruction from In-plane X-Ray diffraction data
Pedio M, Felici R, Torrelles X, Rudolf P, Capozi M, Rius J, Ferrer S., Phys. Rev. Lett. 85(5), 2000
PMID: 10991469
Theory of alkali-metal-induced reconstructions of fcc(100) surfaces.
Christensen OB, Jacobsen KW., Phys. Rev., B Condens. Matter 45(12), 1992
PMID: 10000452
Butanethiol self-assembly on Au(001): The 1×4 Au missing row, c(2×8) molecular lattice
Poirier, Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures 14(2), 1996
MOLECULAR ELECTRONICS:Bypassing the Transistor Paradigm
Lent, Science 288(5471), 2000
Rotation of a single molecule within a supramolecular bearing
Gimzewski JK, Joachim C, Schlittler RR, Langlais V V, Tang H, Johannsen I I., Science 281(5376), 1998
PMID: 9677189
Electronically configurable molecular-based logic gates
Collier CP, Wong EW, Belohradsky M, Raymo FM, Stoddart JF, Kuekes PJ, Williams RS, Heath JR., Science 285(5426), 1999
PMID: 10411498
Many-atom interactions in metals
NORSKOV, Surface Science 283(1-3), 1993
Nucleation, growth, and structure of fullerene films on Au(111)
ALTMAN, Surface Science 279(1-2), 1992
Positioning single atoms with a scanning tunnelling microscope
Eigler, Nature 344(6266), 1990
Why gold is the noblest of all the metals
Hammer, Nature 376(6537), 1995
Manipulation of Matter at the Atomic and Molecular Levels
Avouris, Accounts of Chemical Research 28(3), 1995
Decacyclene: a molecular propeller with helical crystals
Ho, Chemistry of Materials 5(9), 1993
Atomic and molecular manipulation with the scanning tunneling microscope.
Stroscio JA, Eigler DM., Science 254(5036), 1991
PMID: 17773601


Markieren/ Markierung löschen
Markierte Publikationen

Open Data PUB

Web of Science

Dieser Datensatz im Web of Science®


PMID: 11177854
PubMed | Europe PMC

Suchen in

Google Scholar