'All-inclusive' imaging of the rutile TiO2(110) surface using NC-AFM

Bechstein R, González C, Schütte J, Jelínek P, Pérez R, Kühnle A (2009)
Nanotechnology 20(50): 505703.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
Download
OA 1.61 MB
Autor*in
Bechstein, RalfUniBi; González, Cesar; Schütte, Jens; Jelínek, Pavel; Pérez, Ruben; Kühnle, AngelikaUniBi
Abstract / Bemerkung
Non-contact atomic force microscopy (NC-AFM) at true atomic resolution is used to investigate the (110) surface of rutile TiO2. We are able to simultaneously resolve both bridging oxygen and titanium atoms of this prototypical oxide surface. Furthermore, the characteristic defect species, i.e. bridging oxygen vacancies, single and double hydroxyls as well as subsurface defects, are identified in the very same frame. We employ density functional theory (DFT) calculations to obtain a comprehensive understanding of the relation between the tip apex structure and the observed image contrast. Our results provide insight into the physical mechanisms behind atomic-scale contrast, indicating that electrostatic interaction can lead to a far more complex contrast than commonly assumed.
Erscheinungsjahr
2009
Zeitschriftentitel
Nanotechnology
Band
20
Ausgabe
50
Seite(n)
505703
ISSN
0957-4484
Page URI
https://pub.uni-bielefeld.de/record/2913836

Zitieren

Bechstein R, González C, Schütte J, Jelínek P, Pérez R, Kühnle A. 'All-inclusive' imaging of the rutile TiO2(110) surface using NC-AFM. Nanotechnology. 2009;20(50):505703.
Bechstein, R., González, C., Schütte, J., Jelínek, P., Pérez, R., & Kühnle, A. (2009). 'All-inclusive' imaging of the rutile TiO2(110) surface using NC-AFM. Nanotechnology, 20(50), 505703. doi:10.1088/0957-4484/20/50/505703
Bechstein, Ralf, González, Cesar, Schütte, Jens, Jelínek, Pavel, Pérez, Ruben, and Kühnle, Angelika. 2009. “'All-inclusive' imaging of the rutile TiO2(110) surface using NC-AFM”. Nanotechnology 20 (50): 505703.
Bechstein, R., González, C., Schütte, J., Jelínek, P., Pérez, R., and Kühnle, A. (2009). 'All-inclusive' imaging of the rutile TiO2(110) surface using NC-AFM. Nanotechnology 20, 505703.
Bechstein, R., et al., 2009. 'All-inclusive' imaging of the rutile TiO2(110) surface using NC-AFM. Nanotechnology, 20(50), p 505703.
R. Bechstein, et al., “'All-inclusive' imaging of the rutile TiO2(110) surface using NC-AFM”, Nanotechnology, vol. 20, 2009, pp. 505703.
Bechstein, R., González, C., Schütte, J., Jelínek, P., Pérez, R., Kühnle, A.: 'All-inclusive' imaging of the rutile TiO2(110) surface using NC-AFM. Nanotechnology. 20, 505703 (2009).
Bechstein, Ralf, González, Cesar, Schütte, Jens, Jelínek, Pavel, Pérez, Ruben, and Kühnle, Angelika. “'All-inclusive' imaging of the rutile TiO2(110) surface using NC-AFM”. Nanotechnology 20.50 (2009): 505703.
Alle Dateien verfügbar unter der/den folgenden Lizenz(en):
Copyright Statement:
Dieses Objekt ist durch das Urheberrecht und/oder verwandte Schutzrechte geschützt. [...]
Volltext(e)
Access Level
OA Open Access
Zuletzt Hochgeladen
2019-09-06T09:18:52Z
MD5 Prüfsumme
a858b154cc87db025c978a3b2cfa475d


20 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Anchoring of a dye precursor on NiO(001) studied by non-contact atomic force microscopy.
Freund S, Hinaut A, Marinakis N, Constable EC, Meyer E, Housecroft CE, Glatzel T., Beilstein J Nanotechnol 9(), 2018
PMID: 29441269
Polarity compensation mechanisms on the perovskite surface KTaO3(001).
Setvin M, Reticcioli M, Poelzleitner F, Hulva J, Schmid M, Boatner LA, Franchini C, Diebold U., Science 359(6375), 2018
PMID: 29420289
A full monolayer of superoxide: oxygen activation on the unmodified Ca3Ru2O7(001) surface.
Halwidl D, Mayr-Schmölzer W, Setvin M, Fobes D, Peng J, Mao Z, Schmid M, Mittendorfer F, Redinger J, Diebold U., J Mater Chem A Mater 6(14), 2018
PMID: 30009023
Surface point defects on bulk oxides: atomically-resolved scanning probe microscopy.
Setvín M, Wagner M, Schmid M, Parkinson GS, Diebold U., Chem Soc Rev 46(7), 2017
PMID: 28304064
The local electronic properties of individual Pt atoms adsorbed on TiO2(110) studied by Kelvin probe force microscopy and first-principles simulations.
Yurtsever A, Fernández-Torre D, Onoda J, Abe M, Morita S, Sugimoto Y, Pérez R., Nanoscale 9(18), 2017
PMID: 28225121
A DFT study of water adsorption on rutile TiO2 (110) surface: The effects of surface steps.
Zheng T, Wu C, Chen M, Zhang Y, Cummings PT., J Chem Phys 145(4), 2016
PMID: 27475381
Atomic species identification at the (101) anatase surface by simultaneous scanning tunnelling and atomic force microscopy.
Stetsovych O, Todorović M, Shimizu TK, Moreno C, Ryan JW, León CP, Sagisaka K, Palomares E, Matolín V, Fujita D, Perez R, Custance O., Nat Commun 6(), 2015
PMID: 26118408
Characterization of individual molecular adsorption geometries by atomic force microscopy: Cu-TCPP on rutile TiO2 (110).
Jöhr R, Hinaut A, Pawlak R, Sadeghi A, Saha S, Goedecker S, Such B, Szymonski M, Meyer E, Glatzel T., J Chem Phys 143(9), 2015
PMID: 26342363
Identification of adsorbed molecules via STM tip manipulation: CO, H₂O, and O₂ on TiO₂ anatase (101).
Setvin M, Daniel B, Aschauer U, Hou W, Li YF, Schmid M, Selloni A, Diebold U., Phys Chem Chem Phys 16(39), 2014
PMID: 25186563
Identifying tips for intramolecular NC-AFM imaging via in situ fingerprinting.
Sang H, Jarvis SP, Zhou Z, Sharp P, Moriarty P, Wang J, Wang Y, Kantorovich L., Sci Rep 4(), 2014
PMID: 25327642
Probing three-dimensional surface force fields with atomic resolution: Measurement strategies, limitations, and artifact reduction.
Baykara MZ, Dagdeviren OE, Schwendemann TC, Mönig H, Altman EI, Schwarz UD., Beilstein J Nanotechnol 3(), 2012
PMID: 23019560
Recent trends in surface characterization and chemistry with high-resolution scanning force methods.
Barth C, Foster AS, Henry CR, Shluger AL., Adv Mater 23(4), 2011
PMID: 21254251
Single-molecule switching with non-contact atomic force microscopy.
Schütte J, Bechstein R, Rahe P, Langhals H, Rohlfing M, Kühnle A., Nanotechnology 22(24), 2011
PMID: 21508456
'Sub-atomic' resolution of non-contact atomic force microscope images induced by a heterogeneous tip structure: a density functional theory study.
Campbellová A, Ondráček M, Pou P, Pérez R, Klapetek P, Jelínek P., Nanotechnology 22(29), 2011
PMID: 21685559
NC-AFM imaging of the TiO(2)(110)-(1 x 1) surface at low temperature.
Yurtsever A, Sugimoto Y, Abe M, Morita S., Nanotechnology 21(16), 2010
PMID: 20348596
Atomic resolution non-contact atomic force microscopy of clean metal oxide surfaces.
Lauritsen JV, Reichling M., J Phys Condens Matter 22(26), 2010
PMID: 21386455
Combined NC-AFM and DFT study of the adsorption geometry of trimesic acid on rutile TiO2(110).
Greuling A, Rahe P, Kaczmarski M, Kühnle A, Rohlfing M., J Phys Condens Matter 22(34), 2010
PMID: 21403252
Unravelling the atomic structure of cross-linked (1 × 2) TiO2(110).
Pieper HH, Venkataramani K, Torbrügge S, Bahr S, Lauritsen JV, Besenbacher F, Kühnle A, Reichling M., Phys Chem Chem Phys 12(39), 2010
PMID: 20714579
Understanding atomic-resolved STM images on TiO2(110)-(1 x 1) surface by DFT calculations.
Sánchez-Sánchez C, González C, Jelinek P, Méndez J, de Andres PL, Martín-Gago JA, López MF., Nanotechnology 21(40), 2010
PMID: 20823501

25 References

Daten bereitgestellt von Europe PubMed Central.


AUTHOR UNKNOWN, 0
Evidence for the Tunneling Site on Transition-Metal Oxides: TiO2(110).
Diebold U, Anderson JF, Ng KO, Vanderbilt D., Phys. Rev. Lett. 77(7), 1996
PMID: 10063047

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0
Chemical identification of point defects and adsorbates on a metal oxide surface by atomic force microscopy.
Lauritsen JV, Foster AS, Olesen GH, Christensen MC, Kuhnle A, Helveg S, Rostrup-Nielsen JR, Clausen BS, Reichling M, Besenbacher F., Nanotechnology 17(14), 2006
PMID: 19661587

AUTHOR UNKNOWN, 0
Imaging water dissociation on TiO2(110): Evidence for inequivalent geminate OH groups.
Zhang Z, Bondarchuk O, Kay BD, White JM, Dohnalek Z., J Phys Chem B 110(43), 2006
PMID: 17064148

AUTHOR UNKNOWN, 0
The role of interstitial sites in the Ti3d defect state in the band gap of titania.
Wendt S, Sprunger PT, Lira E, Madsen GK, Li Z, Hansen JO, Matthiesen J, Blekinge-Rasmussen A, Laegsgaard E, Hammer B, Besenbacher F., Science 320(5884), 2008
PMID: 18535207
Chemical reactions on rutile TiO2(110).
Lun Pang C, Lindsay R, Thornton G., Chem Soc Rev 37(10), 2008
PMID: 18818830

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0
Chemical identification of individual surface atoms by atomic force microscopy.
Sugimoto Y, Pou P, Abe M, Jelinek P, Perez R, Morita S, Custance O., Nature 446(7131), 2007
PMID: 17330040

AUTHOR UNKNOWN, 0
Structure and stability of semiconductor tip apexes for atomic force microscopy.
Pou P, Ghasemi SA, Jelinek P, Lenosky T, Goedecker S, Perez R., Nanotechnology 20(26), 2009
PMID: 19509446
Single atomic contact adhesion and dissipation in dynamic force microscopy.
Oyabu N, Pou P, Sugimoto Y, Jelinek P, Abe M, Morita S, Perez R, Custance O., Phys. Rev. Lett. 96(10), 2006
PMID: 16605762

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0
Interaction of silicon dangling bonds with insulating surfaces.
Foster AS, Gal AY, Gale JD, Lee YJ, Nieminen RM, Shluger AL., Phys. Rev. Lett. 92(3), 2004
PMID: 14753889

AUTHOR UNKNOWN, 0
Export

Markieren/ Markierung löschen
Markierte Publikationen

Open Data PUB

Web of Science

Dieser Datensatz im Web of Science®
Quellen

PMID: 19923656
PubMed | Europe PMC

Suchen in

Google Scholar