From dewetting to wetting molecular layers:C60 on CaCO3(1014) as a case study

Rahe P, Lindner R, Kittelmann M, Nimmrich M, Kühnle A (2012)
Physical Chemistry Chemical Physics 14(18): 6544-6548.

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We report the formation of extended molecular layers of C-60 molecules on a dielectric surface at room temperature. In sharp contrast to previous C-60 adsorption studies on prototypical ionic crystal surfaces, a wetting layer is obtained when choosing the calcite (CaCO3)(10 (1) over bar4) surface as a substrate. Non-contact atomic force microscopy data reveal an excellent match of the hexagonal lattice of the molecular layer with the unit cell dimension of CaCO3(10 (1) over bar4) in the [01 (1) over bar0] direction, while a lattice mismatch along the [(4) over bar(2) over bar 61] direction results in a large-scale moire modulation. Overall, a (2 x 15) wetting layer is obtained. The distinct difference observed microscopically upon C-60 adsorption on CaCO3(10 (1) over bar4) compared to other dielectric surfaces is explained by a macroscopic picture based on surface energies. Our example demonstrates that this simple surface-energy based approach can provide a valuable estimate for choosing molecule-insulator systems suitable for molecular self-assembly at room temperature.
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Physical Chemistry Chemical Physics
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14
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18
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6544-6548
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Rahe P, Lindner R, Kittelmann M, Nimmrich M, Kühnle A. From dewetting to wetting molecular layers:C60 on CaCO3(1014) as a case study. Physical Chemistry Chemical Physics. 2012;14(18):6544-6548.
Rahe, P., Lindner, R., Kittelmann, M., Nimmrich, M., & Kühnle, A. (2012). From dewetting to wetting molecular layers:C60 on CaCO3(1014) as a case study. Physical Chemistry Chemical Physics, 14(18), 6544-6548. doi:10.1039/c2cp40172j
Rahe, P., Lindner, R., Kittelmann, M., Nimmrich, M., and Kühnle, A. (2012). From dewetting to wetting molecular layers:C60 on CaCO3(1014) as a case study. Physical Chemistry Chemical Physics 14, 6544-6548.
Rahe, P., et al., 2012. From dewetting to wetting molecular layers:C60 on CaCO3(1014) as a case study. Physical Chemistry Chemical Physics, 14(18), p 6544-6548.
P. Rahe, et al., “From dewetting to wetting molecular layers:C60 on CaCO3(1014) as a case study”, Physical Chemistry Chemical Physics, vol. 14, 2012, pp. 6544-6548.
Rahe, P., Lindner, R., Kittelmann, M., Nimmrich, M., Kühnle, A.: From dewetting to wetting molecular layers:C60 on CaCO3(1014) as a case study. Physical Chemistry Chemical Physics. 14, 6544-6548 (2012).
Rahe, Philipp, Lindner, Robert, Kittelmann, Markus, Nimmrich, Markus, and Kühnle, Angelika. “From dewetting to wetting molecular layers:C60 on CaCO3(1014) as a case study”. Physical Chemistry Chemical Physics 14.18 (2012): 6544-6548.
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9 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Imaging prototypical aromatic molecules on insulating surfaces: a review.
Hoffmann-Vogel R., Rep Prog Phys 81(1), 2018
PMID: 28958993
On-surface synthesis on a bulk insulator surface.
Richter A, Floris A, Bechstein R, Kantorovich L, Kühnle A., J Phys Condens Matter 30(13), 2018
PMID: 29460853
Adsorption and migration of single metal atoms on the calcite (10.4) surface.
Pinto H, Haapasilta V, Lokhandwala M, Öberg S, Foster AS., J Phys Condens Matter 29(13), 2017
PMID: 28198353
On-surface reactions.
Lindner R, Kühnle A., Chemphyschem 16(8), 2015
PMID: 25965579
Substrate templating guides the photoinduced reaction of C60 on calcite.
Lindner R, Rahe P, Kittelmann M, Gourdon A, Bechstein R, Kühnle A., Angew Chem Int Ed Engl 53(30), 2014
PMID: 24692299
Decisive influence of substitution positions in molecular self-assembly.
Neff JL, Kittelmann M, Bechstein R, Kühnle A., Phys Chem Chem Phys 16(29), 2014
PMID: 24947801
Bimolecular porous supramolecular networks deposited from solution on layered materials: graphite, boron nitride and molybdenum disulphide.
Korolkov VV, Svatek SA, Allen S, Roberts CJ, Tendler SJ, Taniguchi T, Watanabe K, Champness NR, Beton PH., Chem Commun (Camb) 50(64), 2014
PMID: 24969532
Tuning molecular self-assembly on bulk insulator surfaces by anchoring of the organic building blocks.
Rahe P, Kittelmann M, Neff JL, Nimmrich M, Reichling M, Maass P, Kühnle A., Adv Mater 25(29), 2013
PMID: 23907708

52 References

Daten bereitgestellt von Europe PubMed Central.

Molecular architectonic on metal surfaces.
Barth JV., Annu Rev Phys Chem 58(), 2007
PMID: 17430091

Böhringer, Surf. Rev. Lett. 7(), 2000
A homomolecular porous network at a Cu(111) surface.
Pawin G, Wong KL, Kwon KY, Bartels L., Science 313(5789), 2006
PMID: 16917060
Self-assembly of chiral molecular honeycomb networks on Au(111).
Xiao W, Feng X, Ruffieux P, Groning O, Mullen K, Fasel R., J. Am. Chem. Soc. 130(28), 2008
PMID: 18558672

Mohnani, Coord. Chem. Rev. 254(), 2010
Supramolecular architectures on surfaces formed through hydrogen bonding optimized in three dimensions.
Yu M, Kalashnyk N, Xu W, Barattin R, Benjalal Y, Laegsgaard E, Stensgaard I, Hliwa M, Bouju X, Gourdon A, Joachim C, Besenbacher F, Linderoth TR., ACS Nano 4(7), 2010
PMID: 20550141

Rosei, Prog. Surf. Sci. 71(), 2003

Nony, Nanotechnology 15(), 2004
Nucleation and submonolayer growth of C60 on KBr.
Burke SA, Mativetsky JM, Hoffmann R, Grutter P., Phys. Rev. Lett. 94(9), 2005
PMID: 15783979

Burke, J. Phys.: Condens. Matter 21(), 2009

Pakarinen, Phys. Rev. B 80(), 2009

Loske, Phys. Rev. B 82(), 2010

Pawlak, J. Phys. Chem. C 114(), 2010

Rahe, J. Phys. Chem. C 114(), 2010

Kunstmann, Phys. Rev. B 71(), 2005

Nony, Nano Lett. 4(), 2004
Nanoscale pits as templates for building a molecular device.
Mativetsky JM, Burke SA, Fostner S, Grutter P., Small 3(5), 2007
PMID: 17351992

Schütte, Phys. Rev. B 80(), 2009
Functionalized truxenes: adsorption and diffusion of single molecules on the KBr(001) surface.
Such B, Trevethan T, Glatzel T, Kawai S, Zimmerli L, Meyer E, Shluger AL, Amijs CH, de Mendoza P, Echavarren AM., ACS Nano 4(6), 2010
PMID: 20499857

de, J. Phys. Chem. B 102(), 1998

Bauer, Z. Kristallogr. 110(), 1958

Burke, Phys. Rev. B 76(), 2007
Second-layer induced island morphologies in thin-film growth of fullerenes.
Korner M, Loske F, Einax M, Kuhnle A, Reichling M, Maass P., Phys. Rev. Lett. 107(1), 2011
PMID: 21797552

Girifalco, J. Phys. Chem. 96(), 1992

Maxwell, Phys. Rev. B 57(), 1998

Dienel, Adv. Mater. 20(), 2008

Vitos, Surf. Sci. 411(), 1998
Modeling steps and kinks on the surface of calcite.
Kristensen R, Stipp SL, Refson K., J Chem Phys 121(17), 2004
PMID: 15511175

Duffy, J. Mater. Chem. 12(), 2002

de, J. Phys. Chem. B 102(), 1998

Gilman, J. Appl. Phys. 31(), 1960

de, J. Mater. Chem. 13(), 2003

Puchin, J. Phys.: Condens. Matter 13(), 2001

Liu, Surf. Sci. 600(), 2006

Van, J. Chem. Phys. 26(), 1957

Tasker, Philos. Mag. A 39(), 1979

Benson, J. Chem. Phys. 48(), 1968

Shuttleworth, Proc. Phys. Soc., London, Sect. A 62(), 1949

Mackrodt, J. Phys. C: Solid State Phys. 10(), 1977

Heyes, J. Chem. Soc., Faraday Trans. 73(), 1977

Nabok, Phys. Rev. B 77(), 2008

Northrup, Phys. Rev. B 66(), 2002
Concept for support and cleavage of brittle crystals.
Troger L, Schutte J, Ostendorf F, Kuhnle A, Reichling M., Rev Sci Instrum 80(6), 2009
PMID: 19566206

Knudsen, Ann. Phys. (Berlin, Ger.) 28(), 1909

Clausing, Z. Phys. A: Hadrons Nucl. 66(), 1930

Albrecht, J. Appl. Phys. 69(), 1991

Giessibl, Phys. Rev. B 61(), 2000
Sled-type motion on the nanometer scale: determination of dissipation and cohesive energies of c60.
Luthi R, Meyer E, Haefke H, Howald L, Gutmannsbauer W, Guntherodt HJ., Science 266(5193), 1994
PMID: 17836516

Liu, J. Phys. Chem. C 112(), 2008

Rahe, J. Vac. Sci. Technol., B 28(), 2010
Epitaxial growth of C60 on Ag(110) studied by scanning tunneling microscopy and tunneling spectroscopy.
David T, Gimzewski JK, Purdie D, Reihl B, Schlittler RR., Phys. Rev., B Condens. Matter 50(8), 1994
PMID: 9976946

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