PAA-PAMPS Copolymers as an Efficient Tool to Control CaCO3 Scale Formation
Dietzsch M, Barz M, Schüler T, Klassen S, Schreiber M, Susewind M, Loges N, Lang M, Hellmann N, Fritz M, Fischer K, et al. (2013)
Langmuir 29: 3080.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
Download
![Open access file OA](https://pub.uni-bielefeld.de/images/access_open.png)
Autor*in
Dietzsch, Michael;
Barz, Matthias;
Schüler, Timo;
Klassen, Stefanie;
Schreiber, Martin;
Susewind, Moritz;
Loges, Niklas;
Lang, Michael;
Hellmann, Nadja;
Fritz, Monika;
Fischer, Karl;
Theato, Patrick
Alle
Alle
Einrichtung
Abstract / Bemerkung
Scale formation, the deposition of certain minerals such as CaCO3, MgCO3, and CaSO4 center dot 2H(2)O in industrial facilities and household devices, leads to reduced efficiency or severe damage. Therefore, incrustation is a major problem in everyday life. In recent years, double hydrophilic block copolymers (DHBCs) have been the focus of interest in academia with regard to their antiscaling potential. In this work, we synthesized well-defined blocklike PAA-PAMPS copolymers consisting of acrylic acid (AA) and 2-acrylamido-2-methyl-propane sulfonate (AMPS) units in a one-step reaction by RAFT polymerization. The derived copolymers had dispersities of 1.3 and below. The copolymers have then been investigated in detail regarding their impact on the different stages of the crystallization process of CaCO3. Ca2+ complexation, the first step of a precipitation process, and polyelectrolyte stability in aqueous solution have been investigated by potentiometric measurements, isothermal titration calorimetry (ITC), and dynamic light scattering (DLS). A weak Ca2+ induced copolymer aggregation without concomitant precipitation was observed. Nudeation, early particle growth, and colloidal stability have been monitored in situ with DLS. The copolymers retard or even completely suppress nucleation, most probably by complexation of solution aggregates. In addition, they stabilize existing CaCO3 particles in the nanometer regime. In situ AFM was used as a tool to verify the coordination of the copolymer to the calcite (104) crystal surface and to estimate its potential as a growth inhibitor in a supersaturated CaCO3 environment. All investigated copolymers instantly stopped further crystal growth. The carboxylate richest copolymer as the most promising antiscaling candidate proved its enormous potential in scale inhibition as well in an industrial-filming test (Fresenius standard method).
Erscheinungsjahr
2013
Zeitschriftentitel
Langmuir
Band
29
Seite(n)
3080
Urheberrecht / Lizenzen
ISSN
0743-7463
Page URI
https://pub.uni-bielefeld.de/record/2913806
Zitieren
Dietzsch M, Barz M, Schüler T, et al. PAA-PAMPS Copolymers as an Efficient Tool to Control CaCO3 Scale Formation. Langmuir. 2013;29:3080.
Dietzsch, M., Barz, M., Schüler, T., Klassen, S., Schreiber, M., Susewind, M., Loges, N., et al. (2013). PAA-PAMPS Copolymers as an Efficient Tool to Control CaCO3 Scale Formation. Langmuir, 29, 3080. https://doi.org/10.1021/la4000044
Dietzsch, Michael, Barz, Matthias, Schüler, Timo, Klassen, Stefanie, Schreiber, Martin, Susewind, Moritz, Loges, Niklas, et al. 2013. “PAA-PAMPS Copolymers as an Efficient Tool to Control CaCO3 Scale Formation”. Langmuir 29: 3080.
Dietzsch, M., Barz, M., Schüler, T., Klassen, S., Schreiber, M., Susewind, M., Loges, N., Lang, M., Hellmann, N., Fritz, M., et al. (2013). PAA-PAMPS Copolymers as an Efficient Tool to Control CaCO3 Scale Formation. Langmuir 29, 3080.
Dietzsch, M., et al., 2013. PAA-PAMPS Copolymers as an Efficient Tool to Control CaCO3 Scale Formation. Langmuir, 29, p 3080.
M. Dietzsch, et al., “PAA-PAMPS Copolymers as an Efficient Tool to Control CaCO3 Scale Formation”, Langmuir, vol. 29, 2013, pp. 3080.
Dietzsch, M., Barz, M., Schüler, T., Klassen, S., Schreiber, M., Susewind, M., Loges, N., Lang, M., Hellmann, N., Fritz, M., Fischer, K., Theato, P., Kühnle, A., Schmidt, M., Zentel, R., Tremel, W.: PAA-PAMPS Copolymers as an Efficient Tool to Control CaCO3 Scale Formation. Langmuir. 29, 3080 (2013).
Dietzsch, Michael, Barz, Matthias, Schüler, Timo, Klassen, Stefanie, Schreiber, Martin, Susewind, Moritz, Loges, Niklas, Lang, Michael, Hellmann, Nadja, Fritz, Monika, Fischer, Karl, Theato, Patrick, Kühnle, Angelika, Schmidt, Manfred, Zentel, Rudolf, and Tremel, Wolfgang. “PAA-PAMPS Copolymers as an Efficient Tool to Control CaCO3 Scale Formation”. Langmuir 29 (2013): 3080.
Alle Dateien verfügbar unter der/den folgenden Lizenz(en):
Creative Commons Namensnennung 4.0 International Public License (CC-BY 4.0):
Volltext(e)
Name
Langmuir_29_2013_Dietzsch.pdf
989.25 KB
Access Level
![Open access file OA](https://pub.uni-bielefeld.de/images/access_open.png)
Zuletzt Hochgeladen
2019-09-06T09:18:51Z
MD5 Prüfsumme
ac6514094ade163f11fb805c22a381ae
Daten bereitgestellt von European Bioinformatics Institute (EBI)
3 Zitationen in Europe PMC
Daten bereitgestellt von Europe PubMed Central.
Investigation of the effects of electromagnetic field treatment of hot spring water for scale inhibition using a fibre optic sensor.
Okazaki T, Umeki S, Orii T, Ikeya R, Sakaguchi A, Yamamoto T, Watanabe T, Ueda A, Kuramitz H., Sci Rep 9(1), 2019
PMID: 31341197
Okazaki T, Umeki S, Orii T, Ikeya R, Sakaguchi A, Yamamoto T, Watanabe T, Ueda A, Kuramitz H., Sci Rep 9(1), 2019
PMID: 31341197
Fiber Optic Sensor for Real-Time Sensing of Silica Scale Formation in Geothermal Water.
Okazaki T, Orii T, Ueda A, Ozawa A, Kuramitz H., Sci Rep 7(1), 2017
PMID: 28611412
Okazaki T, Orii T, Ueda A, Ozawa A, Kuramitz H., Sci Rep 7(1), 2017
PMID: 28611412
Core-Crosslinked Polymeric Micelles: Principles, Preparation, Biomedical Applications and Clinical Translation.
Talelli M, Barz M, Rijcken CJ, Kiessling F, Hennink WE, Lammers T., Nano Today 10(1), 2015
PMID: 25893004
Talelli M, Barz M, Rijcken CJ, Kiessling F, Hennink WE, Lammers T., Nano Today 10(1), 2015
PMID: 25893004
References
Daten bereitgestellt von Europe PubMed Central.
Export
Markieren/ Markierung löschen
Markierte Publikationen
Web of Science
Dieser Datensatz im Web of Science®Quellen
PMID: 23387936
PubMed | Europe PMC
Suchen in