Tuning Molecular Self-Assembly on Bulk Insulator Surfaces by Anchoring of the Organic Building Blocks

Rahe P, Kittelmann M, Neff JL, Nimmrich M, Reichling M, Maass P, Kühnle A (2013)
Advances Materials 25: 3948.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Rahe, Philipp; Kittelmann, Markus; Neff, Julia L.; Nimmrich, Markus; Reichling, Michael; Maass, Philipp; Kühnle, AngelikaUniBi
Abstract / Bemerkung
Molecular self-assembly constitutes a versatile strategy for creating functional structures on surfaces. Tuning the subtle balance between intermolecular and molecule-surface interactions allows structure formation to be tailored at the single-molecule level. While metal surfaces usually exhibit interaction strengths in an energy range that favors molecular self-assembly, dielectric surfaces having low surface energies often lack sufficient interactions with adsorbed molecules. As a consequence, application-relevant, bulk insulating materials pose significant challenges when considering them as supporting substrates for molecular self-assembly. Here, the current status of molecular self-assembly on surfaces of wide-bandgap dielectric crystals, investigated under ultrahigh vacuum conditions at room temperature, is reviewed. To address the major issues currently limiting the applicability of molecular self-assembly principles in the case of dielectric surfaces, a systematic discussion of general strategies is provided for anchoring organic molecules to bulk insulating materials.
Stichworte
self-assembly; molecule-surface interactions; non-contact atomic force; microscopy; molecular adsorption; insulating surfaces
Erscheinungsjahr
2013
Zeitschriftentitel
Advances Materials
Band
25
Seite(n)
3948
ISSN
0935-9648
eISSN
1521-4095
Page URI
https://pub.uni-bielefeld.de/record/2913801

Zitieren

Rahe P, Kittelmann M, Neff JL, et al. Tuning Molecular Self-Assembly on Bulk Insulator Surfaces by Anchoring of the Organic Building Blocks. Advances Materials. 2013;25:3948.
Rahe, P., Kittelmann, M., Neff, J. L., Nimmrich, M., Reichling, M., Maass, P., & Kühnle, A. (2013). Tuning Molecular Self-Assembly on Bulk Insulator Surfaces by Anchoring of the Organic Building Blocks. Advances Materials, 25, 3948. https://doi.org/10.1002/adma.201300604
Rahe, Philipp, Kittelmann, Markus, Neff, Julia L., Nimmrich, Markus, Reichling, Michael, Maass, Philipp, and Kühnle, Angelika. 2013. “Tuning Molecular Self-Assembly on Bulk Insulator Surfaces by Anchoring of the Organic Building Blocks”. Advances Materials 25: 3948.
Rahe, P., Kittelmann, M., Neff, J. L., Nimmrich, M., Reichling, M., Maass, P., and Kühnle, A. (2013). Tuning Molecular Self-Assembly on Bulk Insulator Surfaces by Anchoring of the Organic Building Blocks. Advances Materials 25, 3948.
Rahe, P., et al., 2013. Tuning Molecular Self-Assembly on Bulk Insulator Surfaces by Anchoring of the Organic Building Blocks. Advances Materials, 25, p 3948.
P. Rahe, et al., “Tuning Molecular Self-Assembly on Bulk Insulator Surfaces by Anchoring of the Organic Building Blocks”, Advances Materials, vol. 25, 2013, pp. 3948.
Rahe, P., Kittelmann, M., Neff, J.L., Nimmrich, M., Reichling, M., Maass, P., Kühnle, A.: Tuning Molecular Self-Assembly on Bulk Insulator Surfaces by Anchoring of the Organic Building Blocks. Advances Materials. 25, 3948 (2013).
Rahe, Philipp, Kittelmann, Markus, Neff, Julia L., Nimmrich, Markus, Reichling, Michael, Maass, Philipp, and Kühnle, Angelika. “Tuning Molecular Self-Assembly on Bulk Insulator Surfaces by Anchoring of the Organic Building Blocks”. Advances Materials 25 (2013): 3948.
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