Substrate Templating Guides the Photoinduced Reaction of C-60 on Calcite

Lindner R, Rahe P, Kittelmann M, Gourdon A, Bechstein R, Kühnle A (2014)
Angewandte Chemie. International Edition 53(30): 7952-7955.

Download
OA 4.35 MB
Zeitschriftenaufsatz | Veröffentlicht | Englisch
Volltext vorhanden für diesen Nachweis
Autor
; ; ; ; ;
Abstract / Bemerkung
A substrate-guided photochemical reaction of C-60 fullerenes on calcite, a bulk insulator, investigated by non-contact atomic force microscopy is presented. The success of the covalent linkage is evident from a shortening of the intermolecular distances, which is clearly expressed by the disappearance of the moire pattern. Furthermore, UV/Vis spectroscopy and mass spectrometry measurements carried out on thick films demonstrate the ability of our setup for initiating the photoinduced reaction. The irradiation of C-60 results in well-oriented covalently linked domains. The orientation of these domains is dictated by the lattice dimensions of the underlying calcite substrate. Using the lattice mismatch to deliberately steer the direction of the chemical reaction is expected to constitute a general design principle for on-surface synthesis. This work thus provides a strategy for controlled fabrication of oriented, covalent networks on bulk insulators.
Erscheinungsjahr
Zeitschriftentitel
Angewandte Chemie. International Edition
Band
53
Ausgabe
30
Seite(n)
7952-7955
ISSN
eISSN
PUB-ID

Zitieren

Lindner R, Rahe P, Kittelmann M, Gourdon A, Bechstein R, Kühnle A. Substrate Templating Guides the Photoinduced Reaction of C-60 on Calcite. Angewandte Chemie. International Edition. 2014;53(30):7952-7955.
Lindner, R., Rahe, P., Kittelmann, M., Gourdon, A., Bechstein, R., & Kühnle, A. (2014). Substrate Templating Guides the Photoinduced Reaction of C-60 on Calcite. Angewandte Chemie. International Edition, 53(30), 7952-7955. doi:10.1002/anie.201309128
Lindner, R., Rahe, P., Kittelmann, M., Gourdon, A., Bechstein, R., and Kühnle, A. (2014). Substrate Templating Guides the Photoinduced Reaction of C-60 on Calcite. Angewandte Chemie. International Edition 53, 7952-7955.
Lindner, R., et al., 2014. Substrate Templating Guides the Photoinduced Reaction of C-60 on Calcite. Angewandte Chemie. International Edition, 53(30), p 7952-7955.
R. Lindner, et al., “Substrate Templating Guides the Photoinduced Reaction of C-60 on Calcite”, Angewandte Chemie. International Edition, vol. 53, 2014, pp. 7952-7955.
Lindner, R., Rahe, P., Kittelmann, M., Gourdon, A., Bechstein, R., Kühnle, A.: Substrate Templating Guides the Photoinduced Reaction of C-60 on Calcite. Angewandte Chemie. International Edition. 53, 7952-7955 (2014).
Lindner, Robert, Rahe, Philipp, Kittelmann, Markus, Gourdon, Andre, Bechstein, Ralf, and Kühnle, Angelika. “Substrate Templating Guides the Photoinduced Reaction of C-60 on Calcite”. Angewandte Chemie. International Edition 53.30 (2014): 7952-7955.
Alle Dateien verfügbar unter der/den folgenden Lizenz(en):
Copyright Statement:
This Item is protected by copyright and/or related rights. [...]
Volltext(e)
Access Level
OA Open Access
Zuletzt Hochgeladen
2018-09-03T09:10:14Z

4 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

On-surface synthesis on a bulk insulator surface.
Richter A, Floris A, Bechstein R, Kantorovich L, Kühnle A., J Phys Condens Matter 30(13), 2018
PMID: 29460853
Micrometre-long covalent organic fibres by photoinitiated chain-growth radical polymerization on an alkali-halide surface.
Para F, Bocquet F, Nony L, Loppacher C, Féron M, Cherioux F, Gao DZ, Federici Canova F, Watkins MB., Nat Chem 10(11), 2018
PMID: 30150724
On-surface reactions.
Lindner R, Kühnle A., Chemphyschem 16(8), 2015
PMID: 25965579

27 References

Daten bereitgestellt von Europe PubMed Central.

Electronics using hybrid-molecular and mono-molecular devices.
Joachim C, Gimzewski JK, Aviram A., Nature 408(6812), 2000
PMID: 11117734
Molecular architectonic on metal surfaces.
Barth JV., Annu Rev Phys Chem 58(), 2007
PMID: 17430091

Rosei, Prog. Surf. Sci. 71(), 2003

Lucas, Polym. Int. 61(), 2012

Gourdon, Angew. Chem. 120(), 2008
On-surface covalent coupling in ultrahigh vacuum.
Gourdon A., Angew. Chem. Int. Ed. Engl. 47(37), 2008
PMID: 18683834
Atomically precise bottom-up fabrication of graphene nanoribbons.
Cai J, Ruffieux P, Jaafar R, Bieri M, Braun T, Blankenburg S, Muoth M, Seitsonen AP, Saleh M, Feng X, Mullen K, Fasel R., Nature 466(7305), 2010
PMID: 20651687
Nano-architectures by covalent assembly of molecular building blocks.
Grill L, Dyer M, Lafferentz L, Persson M, Peters MV, Hecht S., Nat Nanotechnol 2(11), 2007
PMID: 18654406
Molecular self-assembly from building blocks synthesized on a surface in ultrahigh vacuum: kinetic control and topo-chemical reactions.
Weigelt S, Bombis C, Busse C, Knudsen MM, Gothelf KV, Laegsgaard E, Besenbacher F, Linderoth TR., ACS Nano 2(4), 2008
PMID: 19206595

Weigelt, Angew. Chem. 120(), 2008
Surface synthesis of 2D branched polymer nanostructures.
Weigelt S, Busse C, Bombis C, Knudsen MM, Gothelf KV, Laegsgaard E, Besenbacher F, Linderoth TR., Angew. Chem. Int. Ed. Engl. 47(23), 2008
PMID: 18442149
Synthesis of polyphenylene molecular wires by surface-confined polymerization.
Lipton-Duffin JA, Ivasenko O, Perepichka DF, Rosei F., Small 5(5), 2009
PMID: 19241417
Direct imaging of covalent bond structure in single-molecule chemical reactions.
de Oteyza DG, Gorman P, Chen YC, Wickenburg S, Riss A, Mowbray DJ, Etkin G, Pedramrazi Z, Tsai HZ, Rubio A, Crommie MF, Fischer FR., Science 340(6139), 2013
PMID: 23722428
On-surface azide-alkyne cycloaddition on Cu(111): does it "click" in ultrahigh vacuum?
Bebensee F, Bombis C, Vadapoo SR, Cramer JR, Besenbacher F, Gothelf KV, Linderoth TR., J. Am. Chem. Soc. 135(6), 2013
PMID: 23360358
On-surface covalent linking of organic building blocks on a bulk insulator.
Kittelmann M, Rahe P, Nimmrich M, Hauke CM, Gourdon A, Kuhnle A., ACS Nano 5(10), 2011
PMID: 21899361

Rao, Science 259(), 1993
Polymerized fullerite structures.
Nunez-Regueiro M, Marques L, Hodeau JL, Bethoux O, Perroux M., Phys. Rev. Lett. 74(2), 1995
PMID: 10058348

Park, J. Appl. Phys. 84(), 1998

Onoe, Mol. Cryst. Liq. Cryst. 340(), 2000

Hossain, Solid State Commun. 149(), 2009
From dewetting to wetting molecular layers: C60 on CaCO3(10 14) as a case study.
Rahe P, Lindner R, Kittelmann M, Nimmrich M, Kuhnle A., Phys Chem Chem Phys 14(18), 2012
PMID: 22456713

Rahe, J. Vac. Sci. Technol. B 28(), 2010

Burke, Phys. Rev. B 76(), 2007
Orientational ordering transition in solid C60.
Heiney PA, Fischer JE, McGhie AR, Romanow WJ, Denenstein AM, McCauley Jr JP, Smith AB, Cox DE., Phys. Rev. Lett. 66(22), 1991
PMID: 10043651

AUTHOR UNKNOWN, 0

Export

Markieren/ Markierung löschen
Markierte Publikationen

Open Data PUB

Web of Science

Dieser Datensatz im Web of Science®

Quellen

PMID: 24692299
PubMed | Europe PMC

Suchen in

Google Scholar