Facile routes to abnormal-NHC-cobalt(II) complexes

Ghadwal R, Lamm J-H, Rottschäfer D, Schuermann CJ, Demeshko S (2017)
DALTON TRANSACTIONS 46(24): 7664-7667.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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DOI
Autor*in
Ghadwal, RajendraUniBi ; Lamm, Jan-Hendrik; Rottschäfer, DennisUniBi; Schuermann, Christian J.; Demeshko, Serhiy
Einrichtung
Fakultät für Chemie > Anorganische Chemie und Strukturchemie
Abstract / Bemerkung
Deprotonation of [IPrPh]I (1) with Co{N(SiMe3)(2)}(2) readily affords the abnormal N-heterocyclic carbene (aNHC) complex (aIPr(Ph))(2)CoI2 (2) (aIPr(Ph) = 1,3-bis(2,6-iPr(2)C(6)H(3))-2-phenyl-imidazol4-ylidene). Treatment of 1 with NaHBEt3 yields (aIPr(Ph)) BEt3 (3) that serves as an aNHC-transfer agent and yields (aIPr(Ph)) Co{N(SiMe3)(2)}(2) (4) on reaction with Co{N(SiMe3)(2)}(2).
Erscheinungsjahr
2017
Zeitschriftentitel
DALTON TRANSACTIONS
Band
46
Ausgabe
24
Seite(n)
7664-7667
ISSN
1477-9226
eISSN
1477-9234
Page URI
https://pub.uni-bielefeld.de/record/2912978

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Ghadwal R, Lamm J-H, Rottschäfer D, Schuermann CJ, Demeshko S. Facile routes to abnormal-NHC-cobalt(II) complexes. DALTON TRANSACTIONS. 2017;46(24):7664-7667.
Ghadwal, R., Lamm, J. - H., Rottschäfer, D., Schuermann, C. J., & Demeshko, S. (2017). Facile routes to abnormal-NHC-cobalt(II) complexes. DALTON TRANSACTIONS, 46(24), 7664-7667. doi:10.1039/c7dt01778b
Ghadwal, Rajendra, Lamm, Jan-Hendrik, Rottschäfer, Dennis, Schuermann, Christian J., and Demeshko, Serhiy. 2017. “Facile routes to abnormal-NHC-cobalt(II) complexes”. DALTON TRANSACTIONS 46 (24): 7664-7667.
Ghadwal, R., Lamm, J. - H., Rottschäfer, D., Schuermann, C. J., and Demeshko, S. (2017). Facile routes to abnormal-NHC-cobalt(II) complexes. DALTON TRANSACTIONS 46, 7664-7667.
Ghadwal, R., et al., 2017. Facile routes to abnormal-NHC-cobalt(II) complexes. DALTON TRANSACTIONS, 46(24), p 7664-7667.
R. Ghadwal, et al., “Facile routes to abnormal-NHC-cobalt(II) complexes”, DALTON TRANSACTIONS, vol. 46, 2017, pp. 7664-7667.
Ghadwal, R., Lamm, J.-H., Rottschäfer, D., Schuermann, C.J., Demeshko, S.: Facile routes to abnormal-NHC-cobalt(II) complexes. DALTON TRANSACTIONS. 46, 7664-7667 (2017).
Ghadwal, Rajendra, Lamm, Jan-Hendrik, Rottschäfer, Dennis, Schuermann, Christian J., and Demeshko, Serhiy. “Facile routes to abnormal-NHC-cobalt(II) complexes”. DALTON TRANSACTIONS 46.24 (2017): 7664-7667.

5 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

The Viability of C5-Protonated- and C4,C5-Ditopic Carbanionic Abnormal NHCs: A New Dimension in NHC Chemistry.
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Rottschäfer D, Ho NKT, Neumann B, Stammler HG, van Gastel M, Andrada DM, Ghadwal RS., Angew Chem Int Ed Engl 57(20), 2018
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