Pentafluoroethyl Bismuth Compounds

Solyntjes S, Bader J, Neumann B, Stammler H-G, Ignat'ev N, Hoge B (2017)
CHEMISTRY-A EUROPEAN JOURNAL 23(7): 1557-1567.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
Download
Es wurden keine Dateien hochgeladen. Nur Publikationsnachweis!
DOI
Autor*in
Solyntjes, SvenUniBi; Bader, JuliaUniBi; Neumann, BeateUniBi; Stammler, Hans-GeorgUniBi; Ignat'ev, Nikolai; Hoge, BertholdUniBi
Einrichtung
Fakultät für Chemie > Anorganische Chemie und Strukturchemie
Fakultät für Chemie > Anorganische Chemie II
Abstract / Bemerkung
A series of tris-, bis-, and mono(pentafluoroethyl)-bismuthanes of the type (C2F5)(n)BiX3-n (X= F, Cl, Br, I) and transition metal complexes are accessible by a sophisticated pentafluoroethylation protocol. Chemical properties, induced by the strongly electron-withdrawing character of C2F5 groups, are described for representative examples. Moreover, the first molecular structures of perfluoroalkyl bismuthanes and bismuthates obtained by X-ray diffraction are presented.
Stichworte
alkylation; bismuth; fluorine; fluorinated ligands; synthetic methods
Erscheinungsjahr
2017
Zeitschriftentitel
CHEMISTRY-A EUROPEAN JOURNAL
Band
23
Ausgabe
7
Seite(n)
1557-1567
ISSN
0947-6539
eISSN
1521-3765
Page URI
https://pub.uni-bielefeld.de/record/2910392

Zitieren

Solyntjes S, Bader J, Neumann B, Stammler H-G, Ignat'ev N, Hoge B. Pentafluoroethyl Bismuth Compounds. CHEMISTRY-A EUROPEAN JOURNAL. 2017;23(7):1557-1567.
Solyntjes, S., Bader, J., Neumann, B., Stammler, H. - G., Ignat'ev, N., & Hoge, B. (2017). Pentafluoroethyl Bismuth Compounds. CHEMISTRY-A EUROPEAN JOURNAL, 23(7), 1557-1567. doi:10.1002/chem.201604910
Solyntjes, Sven, Bader, Julia, Neumann, Beate, Stammler, Hans-Georg, Ignat'ev, Nikolai, and Hoge, Berthold. 2017. “Pentafluoroethyl Bismuth Compounds”. CHEMISTRY-A EUROPEAN JOURNAL 23 (7): 1557-1567.
Solyntjes, S., Bader, J., Neumann, B., Stammler, H. - G., Ignat'ev, N., and Hoge, B. (2017). Pentafluoroethyl Bismuth Compounds. CHEMISTRY-A EUROPEAN JOURNAL 23, 1557-1567.
Solyntjes, S., et al., 2017. Pentafluoroethyl Bismuth Compounds. CHEMISTRY-A EUROPEAN JOURNAL, 23(7), p 1557-1567.
S. Solyntjes, et al., “Pentafluoroethyl Bismuth Compounds”, CHEMISTRY-A EUROPEAN JOURNAL, vol. 23, 2017, pp. 1557-1567.
Solyntjes, S., Bader, J., Neumann, B., Stammler, H.-G., Ignat'ev, N., Hoge, B.: Pentafluoroethyl Bismuth Compounds. CHEMISTRY-A EUROPEAN JOURNAL. 23, 1557-1567 (2017).
Solyntjes, Sven, Bader, Julia, Neumann, Beate, Stammler, Hans-Georg, Ignat'ev, Nikolai, and Hoge, Berthold. “Pentafluoroethyl Bismuth Compounds”. CHEMISTRY-A EUROPEAN JOURNAL 23.7 (2017): 1557-1567.

3 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Carbon monoxide insertion at a heavy p-block element: unprecedented formation of a cationic bismuth carbamoyl.
Ramler J, Poater J, Hirsch F, Ritschel B, Fischer I, Bickelhaupt FM, Lichtenberg C., Chem Sci 10(15), 2019
PMID: 31057745
On Pentakis(pentafluoroethyl)stannate, [Sn(C2 F5 )5 ]- , and the Gas-Free Generation of Pentafluoroethyllithium, LiC2 F5.
Wiesemann M, Klösener J, Neumann B, Stammler HG, Hoge B., Chemistry 24(8), 2018
PMID: 29068093
Pentafluoroethylated Compounds of Silicon, Germanium and Tin.
Wiesemann M, Hoge B., Chemistry 24(62), 2018
PMID: 29722451

51 References

Daten bereitgestellt von Europe PubMed Central.


AUTHOR UNKNOWN, 0

Haartz, J. Am. Chem. Soc. 95(), 1973

Mallouk, Inorg. Chem. 23(), 1984

Larson, Inorg. Chem. 26(), 1987

Christe, J. Fluorine Chem. 101(), 2000

Holleman, 2007

Riedel, 2007

Bell, Aust. J. Chem. 16(), 1963

AUTHOR UNKNOWN, 0

Morrison, Inorg. Chem. 16(), 1977

Juhlke, J. Am. Chem. Soc. 101(), 1979

Guerra, J. Organomet. Chem. 254(), 1983

Naumann, J. Organomet. Chem. 334(), 1987

Pasenok, J. Organomet. Chem. 417(), 1991

Naumann, J. Fluorine Chem. 66(), 1994

Tyrra, Can. J. Chem. 67(), 1989

AUTHOR UNKNOWN, 0

Gassman, J. Org. Chem. 52(), 1987

Ernst, Inorg. Chem. 28(), 1989

Roddick, Chem. Eng. News 75(), 1997

AUTHOR UNKNOWN, 0

Kolomeitsev, Tetrahedron Lett. 44(), 2003

AUTHOR UNKNOWN, 0
Solid-state structure of a Li/F carbenoid: pentafluoroethyllithium.
Waerder B, Steinhauer S, Neumann B, Stammler HG, Mix A, Vishnevskiy YV, Hoge B, Mitzel NW., Angew. Chem. Int. Ed. Engl. 53(43), 2014
PMID: 25205058

AUTHOR UNKNOWN, Angew. Chem. 126(), 2014

AUTHOR UNKNOWN, 0

Chambers, 1973
Trifluoromethyl derivatives of phosphorus, arsenic and sulphur.
BENNETT FW, BRANDT GR, EMELEUS HJ, HASZELDINE RN., Nature 166(4214), 1950
PMID: 15439239

AUTHOR UNKNOWN, 0

Suzuki, 2001

Brodalla, J. Appl. Crystallogr. 18(), 1985

Beagley, J. Mol. Struct. 17(), 1973

Schulz, Organometallics 32(), 2013

Oberhammer, J. Fluorine Chem. 23(), 1983

Bent, Chem. Rev. 61(), 1961

Carty, J. Chem. Soc. Chem. Commun. (), 1979

Hawley, J. Chem. Soc. A (), 1968

AUTHOR UNKNOWN, 0

Amberger, Chem. Ber. 94(), 1961

Balázs, Organometallics 21(), 2002
(2,6-Mes(2)H(3)C(6))(2)BiH, a Stable, Molecular Hydride of a Main Group Element of the Sixth Period, and Its Conversion to the Dibismuthene (2,6-Mes(2)H(3)C(6))BiBi(2,6-Mes(2)C(6)H(3)) This work was supported by the National Science Foundation. The Bruker SMART 1000 difractometer was funded in part by NSF Instrumentation Grant CHE-9808259. Mes=2,4,6-Me(3)C(6)H(2).
Hardman NJ, Twamley B, Power PP., Angew. Chem. Int. Ed. Engl. 39(15), 2000
PMID: 10934423

AUTHOR UNKNOWN, Angew. Chem. 112(), 2000

Benjamin, J. Organomet. Chem. 708-709(), 2012

Faraglia, J. Organomet. Chem. 20(), 1969

Allman, J. Organomet. Chem. 166(), 1979

Charmant, Acta Crystallogr. Sect. E 58(), 2002

Clegg, J. Chem. Soc. Dalton Trans. (), 1993

Pfeiffer, Chem. Ber. 37(), 1904

Gilman, J. Am. Chem. Soc. 63(), 1941

Dolomanov, J. Appl. Crystallogr. 42(), 2009
A short history of SHELX.
Sheldrick GM., Acta Crystallogr., A, Found. Crystallogr. 64(Pt 1), 2007
PMID: 18156677
Export

Markieren/ Markierung löschen
Markierte Publikationen

Open Data PUB

Web of Science

Dieser Datensatz im Web of Science®
Quellen

PMID: 27862439
PubMed | Europe PMC

Suchen in

Google Scholar