Pentafluoroethyl Bismuth Compounds

Solyntjes S, Bader J, Neumann B, Stammler H-G, Ignat'ev N, Hoge B (2017)
CHEMISTRY-A EUROPEAN JOURNAL 23(7): 1557-1567.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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DOI
Autor*in
Solyntjes, SvenUniBi; Bader, JuliaUniBi; Neumann, BeateUniBi; Stammler, Hans-GeorgUniBi; Ignat'ev, Nikolai; Hoge, BertholdUniBi
Einrichtung
Fakultät für Chemie > Anorganische Chemie II
Fakultät für Chemie > Anorganische Chemie und Strukturchemie
Abstract / Bemerkung
A series of tris-, bis-, and mono(pentafluoroethyl)-bismuthanes of the type (C2F5)(n)BiX3-n (X= F, Cl, Br, I) and transition metal complexes are accessible by a sophisticated pentafluoroethylation protocol. Chemical properties, induced by the strongly electron-withdrawing character of C2F5 groups, are described for representative examples. Moreover, the first molecular structures of perfluoroalkyl bismuthanes and bismuthates obtained by X-ray diffraction are presented.
Stichworte
alkylation; bismuth; fluorine; fluorinated ligands; synthetic methods
Erscheinungsjahr
2017
Zeitschriftentitel
CHEMISTRY-A EUROPEAN JOURNAL
Band
23
Ausgabe
7
Seite(n)
1557-1567
ISSN
0947-6539
eISSN
1521-3765
Page URI
https://pub.uni-bielefeld.de/record/2910392

Zitieren

Solyntjes S, Bader J, Neumann B, Stammler H-G, Ignat'ev N, Hoge B. Pentafluoroethyl Bismuth Compounds. CHEMISTRY-A EUROPEAN JOURNAL. 2017;23(7):1557-1567.
Solyntjes, S., Bader, J., Neumann, B., Stammler, H. - G., Ignat'ev, N., & Hoge, B. (2017). Pentafluoroethyl Bismuth Compounds. CHEMISTRY-A EUROPEAN JOURNAL, 23(7), 1557-1567. doi:10.1002/chem.201604910
Solyntjes, Sven, Bader, Julia, Neumann, Beate, Stammler, Hans-Georg, Ignat'ev, Nikolai, and Hoge, Berthold. 2017. “Pentafluoroethyl Bismuth Compounds”. CHEMISTRY-A EUROPEAN JOURNAL 23 (7): 1557-1567.
Solyntjes, S., Bader, J., Neumann, B., Stammler, H. - G., Ignat'ev, N., and Hoge, B. (2017). Pentafluoroethyl Bismuth Compounds. CHEMISTRY-A EUROPEAN JOURNAL 23, 1557-1567.
Solyntjes, S., et al., 2017. Pentafluoroethyl Bismuth Compounds. CHEMISTRY-A EUROPEAN JOURNAL, 23(7), p 1557-1567.
S. Solyntjes, et al., “Pentafluoroethyl Bismuth Compounds”, CHEMISTRY-A EUROPEAN JOURNAL, vol. 23, 2017, pp. 1557-1567.
Solyntjes, S., Bader, J., Neumann, B., Stammler, H.-G., Ignat'ev, N., Hoge, B.: Pentafluoroethyl Bismuth Compounds. CHEMISTRY-A EUROPEAN JOURNAL. 23, 1557-1567 (2017).
Solyntjes, Sven, Bader, Julia, Neumann, Beate, Stammler, Hans-Georg, Ignat'ev, Nikolai, and Hoge, Berthold. “Pentafluoroethyl Bismuth Compounds”. CHEMISTRY-A EUROPEAN JOURNAL 23.7 (2017): 1557-1567.

3 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Carbon monoxide insertion at a heavy p-block element: unprecedented formation of a cationic bismuth carbamoyl.
Ramler J, Poater J, Hirsch F, Ritschel B, Fischer I, Bickelhaupt FM, Lichtenberg C., Chem Sci 10(15), 2019
PMID: 31057745
On Pentakis(pentafluoroethyl)stannate, [Sn(C2 F5 )5 ]- , and the Gas-Free Generation of Pentafluoroethyllithium, LiC2 F5.
Wiesemann M, Klösener J, Neumann B, Stammler HG, Hoge B., Chemistry 24(8), 2018
PMID: 29068093
Pentafluoroethylated Compounds of Silicon, Germanium and Tin.
Wiesemann M, Hoge B., Chemistry 24(62), 2018
PMID: 29722451

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