Poly-Lewis-acids based on bowl-shaped tribenzotriquinacene

Tomaschautzky J, Neumann B, Stammler H-G, Mitzel NW (2017)
DALTON TRANSACTIONS 46(4): 1112-1123.

Download
Es wurde kein Volltext hochgeladen. Nur Publikationsnachweis!
Zeitschriftenaufsatz | Veröffentlicht | Englisch
Abstract / Bemerkung
Several derivatives of bowl-shaped tribenzotriquinacenes with Lewis-acidic atoms are reported. Six acetylene functions were attached to the benzene rings and these can carry six SnMe3 or SiMe3 groups. Direct functionalization of the benzhydrylic positions with the silyl groups of tribenzotriquinacene in in situ Grignard reactions is reported. Such silyl groups carry various substituents; the Si-H functional species were shown to be convertible into Si-F, Si-Cl and Si-Br functional compounds. The benzhydrylic positions were also substituted by allyl and p-iodo-phenyl functions; the first were further functionalized with a variety of silyl groups (SiCl3, SiMeCl2, SiF3, SiMeF2), the latter with trimethylsilylethynyl substituents and this product desilylated to a tris-(p-ethynyl-phenyl) tribenzotriquinacene. The complexation of a SbCl3 unit by a tribenzotriquinacene derivative with a new chelating tris-arene binding motif of the antimony atom is also reported.
Erscheinungsjahr
Zeitschriftentitel
DALTON TRANSACTIONS
Band
46
Ausgabe
4
Seite(n)
1112-1123
ISSN
eISSN
PUB-ID

Zitieren

Tomaschautzky J, Neumann B, Stammler H-G, Mitzel NW. Poly-Lewis-acids based on bowl-shaped tribenzotriquinacene. DALTON TRANSACTIONS. 2017;46(4):1112-1123.
Tomaschautzky, J., Neumann, B., Stammler, H. - G., & Mitzel, N. W. (2017). Poly-Lewis-acids based on bowl-shaped tribenzotriquinacene. DALTON TRANSACTIONS, 46(4), 1112-1123. doi:10.1039/c6dt04350j
Tomaschautzky, J., Neumann, B., Stammler, H. - G., and Mitzel, N. W. (2017). Poly-Lewis-acids based on bowl-shaped tribenzotriquinacene. DALTON TRANSACTIONS 46, 1112-1123.
Tomaschautzky, J., et al., 2017. Poly-Lewis-acids based on bowl-shaped tribenzotriquinacene. DALTON TRANSACTIONS, 46(4), p 1112-1123.
J. Tomaschautzky, et al., “Poly-Lewis-acids based on bowl-shaped tribenzotriquinacene”, DALTON TRANSACTIONS, vol. 46, 2017, pp. 1112-1123.
Tomaschautzky, J., Neumann, B., Stammler, H.-G., Mitzel, N.W.: Poly-Lewis-acids based on bowl-shaped tribenzotriquinacene. DALTON TRANSACTIONS. 46, 1112-1123 (2017).
Tomaschautzky, Janek, Neumann, Beate, Stammler, Hans-Georg, and Mitzel, Norbert W. “Poly-Lewis-acids based on bowl-shaped tribenzotriquinacene”. DALTON TRANSACTIONS 46.4 (2017): 1112-1123.

1 Zitation in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

44 References

Daten bereitgestellt von Europe PubMed Central.


Kuck, Angew. Chem., Int. Ed. 23(), 1984

Schuster, Tetrahedron 57(), 2001

Zhou, Synlett (), 2005
Enantiomerically Pure Tribenzotriquinacenes through Stereoselective Synthesis.
Greschner W, Neumann B, Stammler HG, Groger H, Kuck D., Angew. Chem. Int. Ed. Engl. 54(46), 2015
PMID: 26404021
Apical Functionalization of Tribenzotriquinacenes.
Dhara A, Weinmann J, Krause AM, Beuerle F., Chemistry 22(35), 2016
PMID: 27444414

Markopoulos, Angew. Chem., Int. Ed. 124(), 2012

Beaudoin, Synthesis (), 2015
Facile Assembly of Chiral Metallosquares by Using Enantiopure Tribenzotriquinacene Corner Motifs.
Xu WR, Xia GJ, Chow HF, Cao XP, Kuck D., Chemistry 21(34), 2015
PMID: 26126897
Dynamic covalent assembly of tribenzotriquinacenes into molecular cubes.
Klotzbach S, Scherpf T, Beuerle F., Chem. Commun. (Camb.) 50(83), 2014
PMID: 24968326

Bredenkötter, Chem. – Eur. J. 20(), 2014
C3v-symmetrical tribenzotriquinacenes as hosts for C60 and C70 in solution and in the solid state.
Georghiou PE, Dawe LN, Tran HA, Strube J, Neumann B, Stammler HG, Kuck D., J. Org. Chem. 73(22), 2008
PMID: 18850747
Chirality-Assisted Synthesis of a Very Large Octameric Hydrogen-Bonded Capsule.
Beaudoin D, Rominger F, Mastalerz M., Angew. Chem. Int. Ed. Engl. 55(50), 2016
PMID: 27862733

Beer, Angew. Chem., Int. Ed. 113(), 2001

Katz, J. Am. Chem. Soc. 89(), 1967

Katz, J. Org. Chem. 50(), 1985

Katz, Organometallics 6(), 1987

Katz, J. Org. Chem. 54(), 1989
Dialkylaluminium-, -gallium-, and -indium-based poly-Lewis acids with a 1,8-diethynylanthracene backbone.
Chmiel J, Neumann B, Stammler HG, Mitzel NW., Chemistry 16(39), 2010
PMID: 20827789
Mechanism of host-guest complex formation and identification of intermediates through NMR titration and diffusion NMR spectroscopy.
Lamm JH, Niermeier P, Mix A, Chmiel J, Neumann B, Stammler HG, Mitzel NW., Angew. Chem. Int. Ed. Engl. 53(30), 2014
PMID: 24925835

Lamm, Eur. J. Inorg. Chem. 26(), 2014

Haag, J. Am. Chem. Soc. 117(), 1995

Sakurai, J. Am. Chem. Soc. 112(), 1990

Rüdinger, Organometallics 11(), 1992

Merker, J. Am. Chem. Soc. 85(), 1963

Merker, J. Org. Chem. 29(), 1964

Menshutkin, Zh. Russ. Fiz. Khim. Ova. Chast. Khim. 43((1298), 1911

Smith, J. Chem. Soc. Trans. 41(), 1882

Peyronel, Gazz. Chim. Ital. 98(), 1968

Bombieri, Inorg. Chim. Acta 6(), 1972

Demalde, Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 28(), 1972

Szyamnski, Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 28(), 1969

Pohl, Angew. Chem. 99(), 1987

Schmidbaur, Organometallics 6(), 1987
Strong Closed-Shell Interactions in Inorganic Chemistry.
Pyykko P., Chem. Rev. 97(3), 1997
PMID: 11848883

Schmidbaur, Chem. Ber. 123(), 1990

Schuster, Angew. Chem., Int. Ed. 12(), 1991

Dolomanov, J. Appl. Crystallogr. 42(), 2009
A short history of SHELX.
Sheldrick GM., Acta Crystallogr., A, Found. Crystallogr. 64(Pt 1), 2007
PMID: 18156677

Export

Markieren/ Markierung löschen
Markierte Publikationen

Open Data PUB

Web of Science

Dieser Datensatz im Web of Science®

Quellen

PMID: 28045169
PubMed | Europe PMC

Suchen in

Google Scholar