Tridentate Lewis-acids based on triphenylsilane

Tomaschautzky J, Neumann B, Stammler H-G, Mix A, Mitzel NW (2017)
DALTON TRANSACTIONS 46(5): 1645-1659.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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DOI
Autor*in
Tomaschautzky, JanekUniBi; Neumann, BeateUniBi; Stammler, Hans-GeorgUniBi; Mix, AndreasUniBi; Mitzel, Norbert W.UniBi
Einrichtung
Fakultät für Chemie > Anorganische Chemie und Strukturchemie
Abstract / Bemerkung
Several derivatives of the propeller-shaped ortho-substituted triphenylsilanes, carrying metal-or silicon-based acceptor groups, are reported. They were synthesized starting from tris(2-bromophenyl) fluorosilane, tris(2-vinylphenyl) fluorosilane and tris(2-ethynylphenyl) fluorosilane to generate a scope of Lewis-acidic molecules with different cavities. An improved synthetic protocol for donor-free tris(2-lithiophenyl) silanes is described. First attempts in host-guest chemistry to probe the binding between a threefold alane-functionalised ortho-substituted triphenylsilane and a tridentate Lewis-basic guest molecule are presented. The synthesis and a first molecular structure determination in the crystalline state of a bisma-silatriptycene is reported.
Erscheinungsjahr
2017
Zeitschriftentitel
DALTON TRANSACTIONS
Band
46
Ausgabe
5
Seite(n)
1645-1659
ISSN
1477-9226
eISSN
1477-9234
Page URI
https://pub.uni-bielefeld.de/record/2910378

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Tomaschautzky J, Neumann B, Stammler H-G, Mix A, Mitzel NW. Tridentate Lewis-acids based on triphenylsilane. DALTON TRANSACTIONS. 2017;46(5):1645-1659.
Tomaschautzky, J., Neumann, B., Stammler, H. - G., Mix, A., & Mitzel, N. W. (2017). Tridentate Lewis-acids based on triphenylsilane. DALTON TRANSACTIONS, 46(5), 1645-1659. doi:10.1039/c6dt04293g
Tomaschautzky, Janek, Neumann, Beate, Stammler, Hans-Georg, Mix, Andreas, and Mitzel, Norbert W. 2017. “Tridentate Lewis-acids based on triphenylsilane”. DALTON TRANSACTIONS 46 (5): 1645-1659.
Tomaschautzky, J., Neumann, B., Stammler, H. - G., Mix, A., and Mitzel, N. W. (2017). Tridentate Lewis-acids based on triphenylsilane. DALTON TRANSACTIONS 46, 1645-1659.
Tomaschautzky, J., et al., 2017. Tridentate Lewis-acids based on triphenylsilane. DALTON TRANSACTIONS, 46(5), p 1645-1659.
J. Tomaschautzky, et al., “Tridentate Lewis-acids based on triphenylsilane”, DALTON TRANSACTIONS, vol. 46, 2017, pp. 1645-1659.
Tomaschautzky, J., Neumann, B., Stammler, H.-G., Mix, A., Mitzel, N.W.: Tridentate Lewis-acids based on triphenylsilane. DALTON TRANSACTIONS. 46, 1645-1659 (2017).
Tomaschautzky, Janek, Neumann, Beate, Stammler, Hans-Georg, Mix, Andreas, and Mitzel, Norbert W. “Tridentate Lewis-acids based on triphenylsilane”. DALTON TRANSACTIONS 46.5 (2017): 1645-1659.

4 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

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Fusing triphenylphosphine with tetraphenylborate: introducing the 9-phosphatriptycene-10-phenylborate (PTB) anion.
Drover MW, Nagata K, Peters JC., Chem Commun (Camb) 54(57), 2018
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Probing steric influences on electrophilic phosphonium cations: a comparison of [(3,5-(CF3)2C6H3)3PF]+ and [(C6F5)3PF].
LaFortune JHW, Szkop KM, Farinha FE, Johnstone TC, Postle S, Stephan DW., Dalton Trans 47(33), 2018
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