Tridentate Lewis-acids based on triphenylsilane
Tomaschautzky J, Neumann B, Stammler H-G, Mix A, Mitzel NW (2017)
DALTON TRANSACTIONS 46(5): 1645-1659.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
Download
Es wurden keine Dateien hochgeladen. Nur Publikationsnachweis!
Autor*in
Abstract / Bemerkung
Several derivatives of the propeller-shaped ortho-substituted triphenylsilanes, carrying metal-or silicon-based acceptor groups, are reported. They were synthesized starting from tris(2-bromophenyl) fluorosilane, tris(2-vinylphenyl) fluorosilane and tris(2-ethynylphenyl) fluorosilane to generate a scope of Lewis-acidic molecules with different cavities. An improved synthetic protocol for donor-free tris(2-lithiophenyl) silanes is described. First attempts in host-guest chemistry to probe the binding between a threefold alane-functionalised ortho-substituted triphenylsilane and a tridentate Lewis-basic guest molecule are presented. The synthesis and a first molecular structure determination in the crystalline state of a bisma-silatriptycene is reported.
Erscheinungsjahr
2017
Zeitschriftentitel
DALTON TRANSACTIONS
Band
46
Ausgabe
5
Seite(n)
1645-1659
ISSN
1477-9226
eISSN
1477-9234
Page URI
https://pub.uni-bielefeld.de/record/2910378
Zitieren
Tomaschautzky J, Neumann B, Stammler H-G, Mix A, Mitzel NW. Tridentate Lewis-acids based on triphenylsilane. DALTON TRANSACTIONS. 2017;46(5):1645-1659.
Tomaschautzky, J., Neumann, B., Stammler, H. - G., Mix, A., & Mitzel, N. W. (2017). Tridentate Lewis-acids based on triphenylsilane. DALTON TRANSACTIONS, 46(5), 1645-1659. doi:10.1039/c6dt04293g
Tomaschautzky, Janek, Neumann, Beate, Stammler, Hans-Georg, Mix, Andreas, and Mitzel, Norbert W. 2017. “Tridentate Lewis-acids based on triphenylsilane”. DALTON TRANSACTIONS 46 (5): 1645-1659.
Tomaschautzky, J., Neumann, B., Stammler, H. - G., Mix, A., and Mitzel, N. W. (2017). Tridentate Lewis-acids based on triphenylsilane. DALTON TRANSACTIONS 46, 1645-1659.
Tomaschautzky, J., et al., 2017. Tridentate Lewis-acids based on triphenylsilane. DALTON TRANSACTIONS, 46(5), p 1645-1659.
J. Tomaschautzky, et al., “Tridentate Lewis-acids based on triphenylsilane”, DALTON TRANSACTIONS, vol. 46, 2017, pp. 1645-1659.
Tomaschautzky, J., Neumann, B., Stammler, H.-G., Mix, A., Mitzel, N.W.: Tridentate Lewis-acids based on triphenylsilane. DALTON TRANSACTIONS. 46, 1645-1659 (2017).
Tomaschautzky, Janek, Neumann, Beate, Stammler, Hans-Georg, Mix, Andreas, and Mitzel, Norbert W. “Tridentate Lewis-acids based on triphenylsilane”. DALTON TRANSACTIONS 46.5 (2017): 1645-1659.
4 Zitationen in Europe PMC
Daten bereitgestellt von Europe PubMed Central.
A Rational Approach to Tetra-Functional Photo-Switches.
Niermeier P, Lamm JH, Mix A, Neumann B, Stammler HG, Mitzel NW., ChemistryOpen 8(3), 2019
PMID: 30886788
Niermeier P, Lamm JH, Mix A, Neumann B, Stammler HG, Mitzel NW., ChemistryOpen 8(3), 2019
PMID: 30886788
Fusing triphenylphosphine with tetraphenylborate: introducing the 9-phosphatriptycene-10-phenylborate (PTB) anion.
Drover MW, Nagata K, Peters JC., Chem Commun (Camb) 54(57), 2018
PMID: 29951661
Drover MW, Nagata K, Peters JC., Chem Commun (Camb) 54(57), 2018
PMID: 29951661
Probing steric influences on electrophilic phosphonium cations: a comparison of [(3,5-(CF3)2C6H3)3PF]+ and [(C6F5)3PF].
LaFortune JHW, Szkop KM, Farinha FE, Johnstone TC, Postle S, Stephan DW., Dalton Trans 47(33), 2018
PMID: 30063062
LaFortune JHW, Szkop KM, Farinha FE, Johnstone TC, Postle S, Stephan DW., Dalton Trans 47(33), 2018
PMID: 30063062
Organotin-based receptors for anions and ion pairs.
Naseer MM, Jurkschat K., Chem Commun (Camb) 53(58), 2017
PMID: 28580478
Naseer MM, Jurkschat K., Chem Commun (Camb) 53(58), 2017
PMID: 28580478
74 References
Daten bereitgestellt von Europe PubMed Central.
Pedersen, J. Am. Chem. Soc. 89(), 1967
Dietrich, Tetrahedron Lett. 10(), 1969
Dietrich, Tetrahedron Lett. 10(), 1969
Vögtle, 1989
Gabard, J. Chem. Soc., Chem. Commun. 21(), 1981
Beer, Angew. Chem. 113(), 2001
Schmidtchen, Angew. Chem. 89(), 1977
Schmidtchen, Chem. Ber. 113(), 1980
Katz, J. Am. Chem. Soc. 89(), 1967
Katz, J. Org. Chem. 50(), 1985
Katz, Organometallics 6(), 1987
Katz, J. Org. Chem. 54(), 1989
Shriver, J. Am. Chem. Soc. 89(), 1967
Layh, Polyhedron 9(), 1990
Uhl, Eur. J. Inorg. Chem. 1(), 1998
Uhl, J. Organomet. Chem. 579(), 1999
Uhl, Organometallics 29(), 2010
Dialkylaluminium-, -gallium-, and -indium-based poly-Lewis acids with a 1,8-diethynylanthracene backbone.
Chmiel J, Neumann B, Stammler HG, Mitzel NW., Chemistry 16(39), 2010
PMID: 20827789
Chmiel J, Neumann B, Stammler HG, Mitzel NW., Chemistry 16(39), 2010
PMID: 20827789
Saied, Organometallics 15(), 1996
The reactions of dialkylgallium hydrides with tert-butylethynylbenzenes--a systematic investigation into the course of hydrogallation reactions.
Uhl W, Claesener M, Haddadpour S, Jasper B, Hepp A., Dalton Trans (4), 2006
PMID: 17213926
Uhl W, Claesener M, Haddadpour S, Jasper B, Hepp A., Dalton Trans (4), 2006
PMID: 17213926
Uhl, Organometallics 21(), 2002
Twofold hydrogallation of C triple bonds c triple bonds by H-GaCl(2)-synthesis of chelating Lewis acids and their application in adduct formation.
Uhl W, Claesener M., Inorg Chem 47(2), 2007
PMID: 18081277
Uhl W, Claesener M., Inorg Chem 47(2), 2007
PMID: 18081277
Hydrogallation of alkynes with H-GaCl2: formation of organoelement dichlorogallium compounds potentially applicable as chelating Lewis acids.
Uhl W, Claesener M., Inorg Chem 47(11), 2007
PMID: 17665906
Uhl W, Claesener M., Inorg Chem 47(11), 2007
PMID: 17665906
Uhl, Organometallics 30(), 2011
Uhl, Organometallics 30(), 2011
Jutzi, Organometallics 28(), 2009
Kilyanek, Organometallics 28(), 2008
Tridentate Lewis Acids Based on 1,3,5-Trisilacyclohexane Backbones and an Example of Their Host-Guest Chemistry.
Weisheim E, Reuter CG, Heinrichs P, Vishnevskiy YV, Mix A, Neumann B, Stammler HG, Mitzel NW., Chemistry 21(35), 2015
PMID: 26213228
Weisheim E, Reuter CG, Heinrichs P, Vishnevskiy YV, Mix A, Neumann B, Stammler HG, Mitzel NW., Chemistry 21(35), 2015
PMID: 26213228
Dialkylaluminium-, -gallium-, and -indium-based poly-Lewis acids with a 1,8-diethynylanthracene backbone.
Chmiel J, Neumann B, Stammler HG, Mitzel NW., Chemistry 16(39), 2010
PMID: 20827789
Chmiel J, Neumann B, Stammler HG, Mitzel NW., Chemistry 16(39), 2010
PMID: 20827789
Mechanism of host-guest complex formation and identification of intermediates through NMR titration and diffusion NMR spectroscopy.
Lamm JH, Niermeier P, Mix A, Chmiel J, Neumann B, Stammler HG, Mitzel NW., Angew. Chem. Int. Ed. Engl. 53(30), 2014
PMID: 24925835
Lamm JH, Niermeier P, Mix A, Chmiel J, Neumann B, Stammler HG, Mitzel NW., Angew. Chem. Int. Ed. Engl. 53(30), 2014
PMID: 24925835
Lamm, Eur. J. Inorg. Chem. 26(), 2014
Altmann, Organometallics 17(), 1998
Schulte, Organometallics 22(), 2003
Newcomb, J. Am. Chem. Soc. 109(), 1987
Newcomb, Tetrahedron Lett. 29(), 1988
Tamao, J. Am. Chem. Soc. 112(), 1990
Tamao, Organometallics 11(), 1992
Brondani, Angew. Chem. 108(), 1996
Jung, Tetrahedron Lett. 29(), 1988
Kameo, Organometallics 34(), 2015
Gualco, Organometallics 34(), 2015
Exceptional steric congestion in an in,in-bis(hydrosilane).
Zong J, Mague JT, Pascal RA Jr., J. Am. Chem. Soc. 135(36), 2013
PMID: 23971948
Zong J, Mague JT, Pascal RA Jr., J. Am. Chem. Soc. 135(36), 2013
PMID: 23971948
Takahashi, J. Chem. Soc., Chem. Commun. (), 1993
Sase, Organometallics 27(), 2008
Chen, J. Organomet. Chem. 193(), 1980
Kuribara, Organometallics 32(), 2013
Dam, J. Organomet. Chem. 55(), 1998
Rot, Organometalics 19(), 2000
Tsuji, Organometalics 25(), 2006
Rh-catalyzed ortho-selective C-H borylation of N-functionalized arenes with silica-supported bridgehead monophosphine ligands.
Kawamorita S, Miyazaki T, Ohmiya H, Iwai T, Sawamura M., J. Am. Chem. Soc. 133(48), 2011
PMID: 22047192
Kawamorita S, Miyazaki T, Ohmiya H, Iwai T, Sawamura M., J. Am. Chem. Soc. 133(48), 2011
PMID: 22047192
Iwai, ACS Catal. 5(), 2015
Bowen, J. Fluorine Chem. 31(), 1986
Humphries, J. Organomet. Chem. 319(), 1987
Molecular structures of the 1,6-disubstituted triptycenes Sb2(C6F4)3 and Bi2(C6F4)3 using gas-phase electron diffraction and ab initio and DFT calculations.
Wann DA, Hinchley SL, Robertson HE, Al-Jabar NA, Massey AG, Rankin DW., Dalton Trans (13), 2005
PMID: 16547540
Wann DA, Hinchley SL, Robertson HE, Al-Jabar NA, Massey AG, Rankin DW., Dalton Trans (13), 2005
PMID: 16547540
Freijee, Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 36(), 1980
Rot, Main Group Met. Chem. 22(), 1999
Uchiyama, Bull. Chem. Soc. Jpn. 82(), 2009
Loomis, Phys. Rev. 81(), 1951
Jerzembeck, Angew. Chem. 114(), 2002
AUTHOR UNKNOWN, 2002
Culmo, 2013
Pregl, 1958
Belcher, Anal. Chim. Acta 13(), 1955
Substituent effects in C6F6-C6H5X stacking interactions.
Gung BW, Amicangelo JC., J. Org. Chem. 71(25), 2006
PMID: 17137351
Gung BW, Amicangelo JC., J. Org. Chem. 71(25), 2006
PMID: 17137351
Klein, Tetrahedron 60(), 2004
Carpita, Eur. J. Org. Chem. (), 2005
Zhou, Adv. Synth. Catal. 391(), 2009
Identifying potent, selective protein tyrosine phosphatase inhibitors from a library of Au(I) complexes.
Karver MR, Krishnamurthy D, Kulkarni RA, Bottini N, Barrios AM., J. Med. Chem. 52(21), 2009
PMID: 19888762
Karver MR, Krishnamurthy D, Kulkarni RA, Bottini N, Barrios AM., J. Med. Chem. 52(21), 2009
PMID: 19888762
Accurate molecular weight determination of small molecules via DOSY-NMR by using external calibration curves with normalized diffusion coefficients.
Neufeld R, Stalke D., Chem Sci 6(6), 2015
PMID: 29142693
Neufeld R, Stalke D., Chem Sci 6(6), 2015
PMID: 29142693
Application of (1)H DOSY for Facile Measurement of Polymer Molecular Weights.
Li W, Chung H, Daeffler C, Johnson JA, Grubbs RH., Macromolecules 45(24), 2012
PMID: 23335819
Li W, Chung H, Daeffler C, Johnson JA, Grubbs RH., Macromolecules 45(24), 2012
PMID: 23335819
Li, Organometallics 29(), 2010
Roth, Angew. Chem. 30(), 1937
Dolomanov, J. Appl. Crystallogr. 42(), 2009
A short history of SHELX.
Sheldrick GM., Acta Crystallogr., A, Found. Crystallogr. 64(Pt 1), 2007
PMID: 18156677
Sheldrick GM., Acta Crystallogr., A, Found. Crystallogr. 64(Pt 1), 2007
PMID: 18156677
Export
Markieren/ Markierung löschen
Markierte Publikationen
Web of Science
Dieser Datensatz im Web of Science®Quellen
PMID: 28098286
PubMed | Europe PMC
Suchen in
Google Scholar