Nucleophilic Transfer Reactions of the [Si(C2F5)(3)](-) Moiety
Schwarze N, Steinhauer S, Neumann B, Stammler H-G, Hoge B (2016)
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55(52): 16161-16164.
Zeitschriftenaufsatz
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Abstract / Bemerkung
The tris(pentafluoroethyl)silanide anion is accessible by the deprotonation of Si(C2F5)(3)H at low temperatures. Subsequent quenching of the resulting salt-like compounds with suitable electrophiles, such as transition-metal complexes or Group14 element halides, leads to a plethora of novel tris(pentafluoroethyl)silane derivatives. This underlines the versatility of Li[Si(C2F5)(3)] as a powerful nucleophilic transfer reagent.
Stichworte
fluorine;
nucleophilic transfer reactions;
perfluoroalkyl compounds;
silanides;
silicon
Erscheinungsjahr
2016
Zeitschriftentitel
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Band
55
Ausgabe
52
Seite(n)
16161-16164
ISSN
1433-7851
eISSN
1521-3773
Page URI
https://pub.uni-bielefeld.de/record/2909088
Zitieren
Schwarze N, Steinhauer S, Neumann B, Stammler H-G, Hoge B. Nucleophilic Transfer Reactions of the [Si(C2F5)(3)](-) Moiety. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. 2016;55(52):16161-16164.
Schwarze, N., Steinhauer, S., Neumann, B., Stammler, H. - G., & Hoge, B. (2016). Nucleophilic Transfer Reactions of the [Si(C2F5)(3)](-) Moiety. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 55(52), 16161-16164. doi:10.1002/anie.201609575
Schwarze, Nico, Steinhauer, Simon, Neumann, Beate, Stammler, Hans-Georg, and Hoge, Berthold. 2016. “Nucleophilic Transfer Reactions of the [Si(C2F5)(3)](-) Moiety”. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55 (52): 16161-16164.
Schwarze, N., Steinhauer, S., Neumann, B., Stammler, H. - G., and Hoge, B. (2016). Nucleophilic Transfer Reactions of the [Si(C2F5)(3)](-) Moiety. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55, 16161-16164.
Schwarze, N., et al., 2016. Nucleophilic Transfer Reactions of the [Si(C2F5)(3)](-) Moiety. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 55(52), p 16161-16164.
N. Schwarze, et al., “Nucleophilic Transfer Reactions of the [Si(C2F5)(3)](-) Moiety”, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, vol. 55, 2016, pp. 16161-16164.
Schwarze, N., Steinhauer, S., Neumann, B., Stammler, H.-G., Hoge, B.: Nucleophilic Transfer Reactions of the [Si(C2F5)(3)](-) Moiety. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. 55, 16161-16164 (2016).
Schwarze, Nico, Steinhauer, Simon, Neumann, Beate, Stammler, Hans-Georg, and Hoge, Berthold. “Nucleophilic Transfer Reactions of the [Si(C2F5)(3)](-) Moiety”. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55.52 (2016): 16161-16164.
3 Zitationen in Europe PMC
Daten bereitgestellt von Europe PubMed Central.
Pentafluoroethylated Compounds of Silicon, Germanium and Tin.
Wiesemann M, Hoge B., Chemistry 24(62), 2018
PMID: 29722451
Wiesemann M, Hoge B., Chemistry 24(62), 2018
PMID: 29722451
The Tris(pentafluoroethyl)stannate(II) Anion, [Sn(C2 F5 )3 ]- -Synthesis and Reactivity.
Wiesemann M, Klösener J, Niemann M, Neumann B, Stammler HG, Hoge B., Chemistry 23(58), 2017
PMID: 28671288
Wiesemann M, Klösener J, Niemann M, Neumann B, Stammler HG, Hoge B., Chemistry 23(58), 2017
PMID: 28671288
Pentafluoroethylsilicic Acids.
Schwarze N, Steinhauer S, Neumann B, Stammler HG, Hoge B., Angew Chem Int Ed Engl 55(50), 2016
PMID: 27862761
Schwarze N, Steinhauer S, Neumann B, Stammler HG, Hoge B., Angew Chem Int Ed Engl 55(50), 2016
PMID: 27862761
40 References
Daten bereitgestellt von Europe PubMed Central.
Perfluoroalkylation with Organosilicon Reagents.
Prakash GK, Yudin AK., Chem. Rev. 97(3), 1997
PMID: 11848888
Prakash GK, Yudin AK., Chem. Rev. 97(3), 1997
PMID: 11848888
AUTHOR UNKNOWN, 0
Ruppert, Tetrahedron Lett. 25(), 1984
Prakash, J. Fluorine Chem. 112(), 2001
Wiedemann, Angew. Chem. Int. Ed. 37(), 1998
AUTHOR UNKNOWN, Angew. Chem. 110(), 1998
Olejniczak, J. Fluorine Chem. 129(), 2008
AUTHOR UNKNOWN, 0
Sharp, Inorg. Chem. 11(), 1972
Taming of fluoroform: direct nucleophilic trifluoromethylation of Si, B, S, and C centers.
Prakash GK, Jog PV, Batamack PT, Olah GA., Science 338(6112), 2012
PMID: 23224551
Prakash GK, Jog PV, Batamack PT, Olah GA., Science 338(6112), 2012
PMID: 23224551
Fluorine in pharmaceuticals: looking beyond intuition.
Muller K, Faeh C, Diederich F., Science 317(5846), 2007
PMID: 17901324
Muller K, Faeh C, Diederich F., Science 317(5846), 2007
PMID: 17901324
Synthesis of tris- and tetrakis(pentafluoroethyl)silanes.
Steinhauer S, Bader J, Stammler HG, Ignat'ev N, Hoge B., Angew. Chem. Int. Ed. Engl. 53(20), 2014
PMID: 24692241
Steinhauer S, Bader J, Stammler HG, Ignat'ev N, Hoge B., Angew. Chem. Int. Ed. Engl. 53(20), 2014
PMID: 24692241
AUTHOR UNKNOWN, Angew. Chem. 126(), 2014
AUTHOR UNKNOWN, 0
Synthesis of five- and six-coordinate tris(pentafluoroethyl)fluorosilicates.
Steinhauer S, Stammler HG, Neumann B, Ignat'ev N, Hoge B., Angew. Chem. Int. Ed. Engl. 53(2), 2013
PMID: 24288152
Steinhauer S, Stammler HG, Neumann B, Ignat'ev N, Hoge B., Angew. Chem. Int. Ed. Engl. 53(2), 2013
PMID: 24288152
AUTHOR UNKNOWN, Angew. Chem. 126(), 2014
AUTHOR UNKNOWN, 0
AUTHOR UNKNOWN, 0
Synthesis of chlorosilicates.
Steinhauer S, Bottcher T, Schwarze N, Neumann B, Stammler HG, Hoge B., Angew. Chem. Int. Ed. Engl. 53(48), 2014
PMID: 25256121
Steinhauer S, Bottcher T, Schwarze N, Neumann B, Stammler HG, Hoge B., Angew. Chem. Int. Ed. Engl. 53(48), 2014
PMID: 25256121
AUTHOR UNKNOWN, Angew. Chem. 126(), 2014
AUTHOR UNKNOWN, 0
Solid-state structure of a Li/F carbenoid: pentafluoroethyllithium.
Waerder B, Steinhauer S, Neumann B, Stammler HG, Mix A, Vishnevskiy YV, Hoge B, Mitzel NW., Angew. Chem. Int. Ed. Engl. 53(43), 2014
PMID: 25205058
Waerder B, Steinhauer S, Neumann B, Stammler HG, Mix A, Vishnevskiy YV, Hoge B, Mitzel NW., Angew. Chem. Int. Ed. Engl. 53(43), 2014
PMID: 25205058
AUTHOR UNKNOWN, Angew. Chem. 126(), 2014
AUTHOR UNKNOWN, 0
AUTHOR UNKNOWN, 0
Pentafluoroethyl-substituted α-silanes: model compounds for new insights.
Waerder B, Steinhauer S, Reuter CG, Bader J, Neumann B, Stammler HG, Vishnevskiy YV, Hoge B, Mitzel NW., Dalton Trans 44(29), 2015
PMID: 26132269
Waerder B, Steinhauer S, Reuter CG, Bader J, Neumann B, Stammler HG, Vishnevskiy YV, Hoge B, Mitzel NW., Dalton Trans 44(29), 2015
PMID: 26132269
AUTHOR UNKNOWN, 0
March, 1992
Schubert, Z. Anorg. Allg. Chem. 519(), 1984
AUTHOR UNKNOWN, 0
Tolman, J. Am. Chem. Soc. 92(), 1970
Tolman, J. Am. Chem. Soc. 96(), 1974
Tolman, Chem. Rev. 77(), 1977
Crabtree, 2005
Synthesis and fundamental properties of stable Ph(3)SnSiH(3) and Ph(3)SnGeH(3) hydrides: model compounds for the design of Si-Ge-Sn photonic alloys.
Tice JB, Chizmeshya AV, Groy TL, Kouvetakis J., Inorg Chem 48(13), 2009
PMID: 19496607
Tice JB, Chizmeshya AV, Groy TL, Kouvetakis J., Inorg Chem 48(13), 2009
PMID: 19496607
Adams, J. Organomet. Chem. 323(), 1987
Wiberg, Angew. Chem. Int. Ed. Engl. 25(), 1986
AUTHOR UNKNOWN, Angew. Chem. 98(), 1986
Dolomanov, J. Appl. Crystallogr. 42(), 2009
A short history of SHELX.
Sheldrick GM., Acta Crystallogr., A, Found. Crystallogr. 64(Pt 1), 2007
PMID: 18156677
Sheldrick GM., Acta Crystallogr., A, Found. Crystallogr. 64(Pt 1), 2007
PMID: 18156677
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