The Tris(pentafluoroethyl)silanide Anion

Schwarze N, Steinhauer S, Neumann B, Stammler H-G, Hoge B (2016)
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55(52): 16156-16160.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
Abstract / Bemerkung
Tris(pentafluoroethyl)silane, which is conveniently accessible by the treatment of Si(C2F5)(3)X (X=Cl, Br) with Bu3SnH, was successfully employed for hydrosilylation reactions. In the presence of a palladium catalyst, hydrosilylation of phenylacetylene with Si(C2F5)(3)H affords the product of an -addition whereas the reaction of trimethylsilylacetylene with the silane leads to the -trans product. Tris(pentafluoroethyl)silane can be deprotonated by sterically demanding bases such as lithium diisopropylamide at low temperatures to give the corresponding silanide ion. The addition of crown ethers or cryptands to this highly reactive species enabled the isolation and characterization of salt-like tris(pentafluoroethyl)silanide at room temperature.
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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
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55
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52
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16156-16160
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Schwarze N, Steinhauer S, Neumann B, Stammler H-G, Hoge B. The Tris(pentafluoroethyl)silanide Anion. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. 2016;55(52):16156-16160.
Schwarze, N., Steinhauer, S., Neumann, B., Stammler, H. - G., & Hoge, B. (2016). The Tris(pentafluoroethyl)silanide Anion. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 55(52), 16156-16160. doi:10.1002/anie.201609096
Schwarze, N., Steinhauer, S., Neumann, B., Stammler, H. - G., and Hoge, B. (2016). The Tris(pentafluoroethyl)silanide Anion. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55, 16156-16160.
Schwarze, N., et al., 2016. The Tris(pentafluoroethyl)silanide Anion. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 55(52), p 16156-16160.
N. Schwarze, et al., “The Tris(pentafluoroethyl)silanide Anion”, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, vol. 55, 2016, pp. 16156-16160.
Schwarze, N., Steinhauer, S., Neumann, B., Stammler, H.-G., Hoge, B.: The Tris(pentafluoroethyl)silanide Anion. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. 55, 16156-16160 (2016).
Schwarze, Nico, Steinhauer, Simon, Neumann, Beate, Stammler, Hans-Georg, and Hoge, Berthold. “The Tris(pentafluoroethyl)silanide Anion”. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55.52 (2016): 16156-16160.

8 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

On Pentakis(pentafluoroethyl)stannate, [Sn(C2 F5 )5 ]- , and the Gas-Free Generation of Pentafluoroethyllithium, LiC2 F5.
Wiesemann M, Klösener J, Neumann B, Stammler HG, Hoge B., Chemistry 24(8), 2018
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Silicon chemistry in zero to three dimensions: from dichlorosilylene to silafullerane.
Teichmann J, Wagner M., Chem Commun (Camb) 54(12), 2018
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Tris(pentafluoroethyl)stannane: Tin Hydride Chemistry with an Electron-Deficient Stannane.
Wiesemann M, Niemann M, Klösener J, Neumann B, Stammler HG, Hoge B., Chemistry 24(11), 2018
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Wiesemann M, Hoge B., Chemistry 24(62), 2018
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Synthesis of N-Heterocycle Substituted Silyl Ligands within the Coordination Sphere of Iron.
Witteman L, Lutz M, Moret ME., Organometallics 37(18), 2018
PMID: 30270963
The Tris(pentafluoroethyl)stannate(II) Anion, [Sn(C2 F5 )3 ]- -Synthesis and Reactivity.
Wiesemann M, Klösener J, Niemann M, Neumann B, Stammler HG, Hoge B., Chemistry 23(58), 2017
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Olaru M, Hesse MF, Rychagova E, Ketkov S, Mebs S, Beckmann J., Angew Chem Int Ed Engl 56(52), 2017
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Pentafluoroethylsilicic Acids.
Schwarze N, Steinhauer S, Neumann B, Stammler HG, Hoge B., Angew Chem Int Ed Engl 55(50), 2016
PMID: 27862761

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