Difluorotriorganylphosphoranes for the Synthesis of Fluorophosphonium and Bismuthonium Salts

Solyntjes S, Neumann B, Stammler H-G, Ignat'ev N, Hoge B (2016)
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2016(25): 3999-4010.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Abstract / Bemerkung
Fluoride ion affinities (FIA), provided by DFT calculations, are exceedingly useful for the design of new Lewis acids with defined reactivities. Herein, we report the synthesis, characterization and reactivity of new difluoro(perfluoroorganyl) phosphoranes, which readily abstract fluoride ions from di-fluoro(triorganyl)phosphoranes. Highly reactive fluorobismuthonium cations and the [Ph3Bi(NCCH3)(2)](2+) cation are accessible through the treatment of difluoro(triorganyl) bismuth(V) compounds with the Lewis acidic phosphoranes discussed here.
Stichworte
Phosphorus; Bismuth; Fluorine; Lewis acids; Perfluoroaryls; Structure; elucidation
Erscheinungsjahr
2016
Zeitschriftentitel
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Band
2016
Ausgabe
25
Seite(n)
3999-4010
ISSN
1434-1948
eISSN
1099-0682
Page URI
https://pub.uni-bielefeld.de/record/2907445

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Solyntjes S, Neumann B, Stammler H-G, Ignat'ev N, Hoge B. Difluorotriorganylphosphoranes for the Synthesis of Fluorophosphonium and Bismuthonium Salts. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2016;2016(25):3999-4010.
Solyntjes, S., Neumann, B., Stammler, H. - G., Ignat'ev, N., & Hoge, B. (2016). Difluorotriorganylphosphoranes for the Synthesis of Fluorophosphonium and Bismuthonium Salts. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016(25), 3999-4010. doi:10.1002/ejic.201600539
Solyntjes, S., Neumann, B., Stammler, H. - G., Ignat'ev, N., and Hoge, B. (2016). Difluorotriorganylphosphoranes for the Synthesis of Fluorophosphonium and Bismuthonium Salts. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2016, 3999-4010.
Solyntjes, S., et al., 2016. Difluorotriorganylphosphoranes for the Synthesis of Fluorophosphonium and Bismuthonium Salts. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016(25), p 3999-4010.
S. Solyntjes, et al., “Difluorotriorganylphosphoranes for the Synthesis of Fluorophosphonium and Bismuthonium Salts”, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, vol. 2016, 2016, pp. 3999-4010.
Solyntjes, S., Neumann, B., Stammler, H.-G., Ignat'ev, N., Hoge, B.: Difluorotriorganylphosphoranes for the Synthesis of Fluorophosphonium and Bismuthonium Salts. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2016, 3999-4010 (2016).
Solyntjes, Sven, Neumann, Beate, Stammler, Hans-Georg, Ignat'ev, Nikolai, and Hoge, Berthold. “Difluorotriorganylphosphoranes for the Synthesis of Fluorophosphonium and Bismuthonium Salts”. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2016.25 (2016): 3999-4010.