Densely Packed Hydrophobic Clustering: Encapsulated Valerates Form a High-Temperature-Stable {Mo-132} Capsule System

Garai S, Bögge H, Merca A, Petina OA, Grego A, Gouzerh P, Haupt ETK, Weinstock IA, Müller A (2016)
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55(23): 6633-6636.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Autor/in
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Abstract / Bemerkung
Porous molecular nanocontainers of {Mo-132}-type Keplerates offer unique opportunities to study a wide variety of relevant phenomena. An impressive example is provided by the highly reactive {Mo-132-CO3} capsule, the reaction of which with valeric acid results in the very easy release of carbon dioxide and the uptake of 24 valerate ions/ligands that are integrated as a densely packed aggregate, thus indicating the unique possibility of hydrophobic clustering inside the cavity. Two-dimensional NMR techniques were used to demonstrate the presence of the 24 valerates and the stability of the capsule up to ca. 100 degrees C. Increasing the number of hydrophobic parts enhances the stability of the whole system. This situation also occurs in biological systems, such as globular proteins or protein pockets.
Stichworte
confinement effects; dense packing; hydrophobic interactions; NMR; spectroscopy; porous capsules
Erscheinungsjahr
2016
Zeitschriftentitel
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Band
55
Ausgabe
23
Seite(n)
6633-6636
ISSN
1433-7851
eISSN
1521-3773
Page URI
https://pub.uni-bielefeld.de/record/2904697

Zitieren

Garai S, Bögge H, Merca A, et al. Densely Packed Hydrophobic Clustering: Encapsulated Valerates Form a High-Temperature-Stable {Mo-132} Capsule System. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. 2016;55(23):6633-6636.
Garai, S., Bögge, H., Merca, A., Petina, O. A., Grego, A., Gouzerh, P., Haupt, E. T. K., et al. (2016). Densely Packed Hydrophobic Clustering: Encapsulated Valerates Form a High-Temperature-Stable {Mo-132} Capsule System. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 55(23), 6633-6636. doi:10.1002/anie.201601140
Garai, S., Bögge, H., Merca, A., Petina, O. A., Grego, A., Gouzerh, P., Haupt, E. T. K., Weinstock, I. A., and Müller, A. (2016). Densely Packed Hydrophobic Clustering: Encapsulated Valerates Form a High-Temperature-Stable {Mo-132} Capsule System. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55, 6633-6636.
Garai, S., et al., 2016. Densely Packed Hydrophobic Clustering: Encapsulated Valerates Form a High-Temperature-Stable {Mo-132} Capsule System. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 55(23), p 6633-6636.
S. Garai, et al., “Densely Packed Hydrophobic Clustering: Encapsulated Valerates Form a High-Temperature-Stable {Mo-132} Capsule System”, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, vol. 55, 2016, pp. 6633-6636.
Garai, S., Bögge, H., Merca, A., Petina, O.A., Grego, A., Gouzerh, P., Haupt, E.T.K., Weinstock, I.A., Müller, A.: Densely Packed Hydrophobic Clustering: Encapsulated Valerates Form a High-Temperature-Stable {Mo-132} Capsule System. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION. 55, 6633-6636 (2016).
Garai, Somenath, Bögge, Hartmut, Merca, Alice, Petina, Olga A., Grego, Alina, Gouzerh, Pierre, Haupt, Erhard T. K., Weinstock, Ira A., and Müller, Achim. “Densely Packed Hydrophobic Clustering: Encapsulated Valerates Form a High-Temperature-Stable {Mo-132} Capsule System”. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55.23 (2016): 6633-6636.

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