Electron beam controlled covalent attachment of small organic molecules to graphene
Markevich A, Kurasch S, Lehtinen O, Reimer O, Feng X, Muellen K, Turchanin A, Khlobystov AN, Kaiser U, Besley E (2016)
NANOSCALE 8(5): 2711-2719.
Zeitschriftenaufsatz
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Autor*in
Markevich, Alexander;
Kurasch, Simon;
Lehtinen, Ossi;
Reimer, OliverUniBi;
Feng, Xinliang;
Muellen, Klaus;
Turchanin, Andrey;
Khlobystov, Andrei N.;
Kaiser, Ute;
Besley, Elena
Abstract / Bemerkung
The electron beam induced functionalization of graphene through the formation of covalent bonds between free radicals of polyaromatic molecules and C=C bonds of pristine graphene surface has been explored using first principles calculations and high-resolution transmission electron microscopy. We show that the energetically strongest attachment of the radicals occurs along the armchair direction in graphene to carbon atoms residing in different graphene sub-lattices. The radicals tend to assume vertical position on graphene substrate irrespective of direction of the bonding and the initial configuration. The "standing up" molecules, covalently anchored to graphene, exhibit two types of oscillatory motion bending and twisting - caused by the presence of acoustic phonons in graphene and dispersion attraction to the substrate. The theoretically derived mechanisms are confirmed by near atomic resolution imaging of individual perchlorocoronene (C24Cl12) molecules on graphene. Our results facilitate the understanding of controlled functionalization of graphene employing electron irradiation as well as mechanisms of attachment of impurities via the processing of graphene nanoelectronic devices by electron beam lithography.
Erscheinungsjahr
2016
Zeitschriftentitel
NANOSCALE
Band
8
Ausgabe
5
Seite(n)
2711-2719
Urheberrecht / Lizenzen
ISSN
2040-3364
eISSN
2040-3372
Page URI
https://pub.uni-bielefeld.de/record/2901587
Zitieren
Markevich A, Kurasch S, Lehtinen O, et al. Electron beam controlled covalent attachment of small organic molecules to graphene. NANOSCALE. 2016;8(5):2711-2719.
Markevich, A., Kurasch, S., Lehtinen, O., Reimer, O., Feng, X., Muellen, K., Turchanin, A., et al. (2016). Electron beam controlled covalent attachment of small organic molecules to graphene. NANOSCALE, 8(5), 2711-2719. doi:10.1039/c5nr07539d
Markevich, Alexander, Kurasch, Simon, Lehtinen, Ossi, Reimer, Oliver, Feng, Xinliang, Muellen, Klaus, Turchanin, Andrey, Khlobystov, Andrei N., Kaiser, Ute, and Besley, Elena. 2016. “Electron beam controlled covalent attachment of small organic molecules to graphene”. NANOSCALE 8 (5): 2711-2719.
Markevich, A., Kurasch, S., Lehtinen, O., Reimer, O., Feng, X., Muellen, K., Turchanin, A., Khlobystov, A. N., Kaiser, U., and Besley, E. (2016). Electron beam controlled covalent attachment of small organic molecules to graphene. NANOSCALE 8, 2711-2719.
Markevich, A., et al., 2016. Electron beam controlled covalent attachment of small organic molecules to graphene. NANOSCALE, 8(5), p 2711-2719.
A. Markevich, et al., “Electron beam controlled covalent attachment of small organic molecules to graphene”, NANOSCALE, vol. 8, 2016, pp. 2711-2719.
Markevich, A., Kurasch, S., Lehtinen, O., Reimer, O., Feng, X., Muellen, K., Turchanin, A., Khlobystov, A.N., Kaiser, U., Besley, E.: Electron beam controlled covalent attachment of small organic molecules to graphene. NANOSCALE. 8, 2711-2719 (2016).
Markevich, Alexander, Kurasch, Simon, Lehtinen, Ossi, Reimer, Oliver, Feng, Xinliang, Muellen, Klaus, Turchanin, Andrey, Khlobystov, Andrei N., Kaiser, Ute, and Besley, Elena. “Electron beam controlled covalent attachment of small organic molecules to graphene”. NANOSCALE 8.5 (2016): 2711-2719.
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