Trimethylaluminum: Bonding by Charge and Current Topology
Stammler H-G, Blomeyer S, Berger R, Mitzel NW (2015)
Angewandte Chemie-International Edition 54(46): 13816-13820.
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Abstract / Bemerkung
The charge density distribution of the trimethylaluminum dimer was determined by high-angle X-ray diffraction of a single crystal and quantum-chemical methods and analyzed using the quantum theory of atoms in molecules. The data can be interpreted as Al2Me6 being predominantly ionically bonded, with clear indications of topological asymmetry for the bridging AlC bonds owing to delocalized multicenter bonding. This interpretation is supported by the calculated magnetic response currents. The data shed new light on the bonding situation in this basic organometallic molecule, which was previously described by contradicting interpretations of bonding.
Stichworte
aluminum
Erscheinungsjahr
2015
Zeitschriftentitel
Angewandte Chemie-International Edition
Band
54
Ausgabe
46
Seite(n)
13816-13820
ISSN
1433-7851
eISSN
1521-3773
Page URI
https://pub.uni-bielefeld.de/record/2901027
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Stammler H-G, Blomeyer S, Berger R, Mitzel NW. Trimethylaluminum: Bonding by Charge and Current Topology. Angewandte Chemie-International Edition. 2015;54(46):13816-13820.
Stammler, H. - G., Blomeyer, S., Berger, R., & Mitzel, N. W. (2015). Trimethylaluminum: Bonding by Charge and Current Topology. Angewandte Chemie-International Edition, 54(46), 13816-13820. doi:10.1002/anie.201505665
Stammler, Hans-Georg, Blomeyer, Sebastian, Berger, Raphael, and Mitzel, Norbert W. 2015. “Trimethylaluminum: Bonding by Charge and Current Topology”. Angewandte Chemie-International Edition 54 (46): 13816-13820.
Stammler, H. - G., Blomeyer, S., Berger, R., and Mitzel, N. W. (2015). Trimethylaluminum: Bonding by Charge and Current Topology. Angewandte Chemie-International Edition 54, 13816-13820.
Stammler, H.-G., et al., 2015. Trimethylaluminum: Bonding by Charge and Current Topology. Angewandte Chemie-International Edition, 54(46), p 13816-13820.
H.-G. Stammler, et al., “Trimethylaluminum: Bonding by Charge and Current Topology”, Angewandte Chemie-International Edition, vol. 54, 2015, pp. 13816-13820.
Stammler, H.-G., Blomeyer, S., Berger, R., Mitzel, N.W.: Trimethylaluminum: Bonding by Charge and Current Topology. Angewandte Chemie-International Edition. 54, 13816-13820 (2015).
Stammler, Hans-Georg, Blomeyer, Sebastian, Berger, Raphael, and Mitzel, Norbert W. “Trimethylaluminum: Bonding by Charge and Current Topology”. Angewandte Chemie-International Edition 54.46 (2015): 13816-13820.
4 Zitationen in Europe PMC
Daten bereitgestellt von Europe PubMed Central.
Crystal structure and quantum-chemical calculations of a tri-methyl-aluminium-THF adduct.
Brieger L, Hermann A, Unkelbach C, Strohmann C., Acta Crystallogr E Crystallogr Commun 74(pt 2), 2018
PMID: 29850068
Brieger L, Hermann A, Unkelbach C, Strohmann C., Acta Crystallogr E Crystallogr Commun 74(pt 2), 2018
PMID: 29850068
A systematic examination of classical and multi-center bonding in heteroborane clusters.
Melichar P, Hnyk D, Fanfrlík J., Phys Chem Chem Phys 20(7), 2018
PMID: 29323675
Melichar P, Hnyk D, Fanfrlík J., Phys Chem Chem Phys 20(7), 2018
PMID: 29323675
Homopolar dihydrogen bonding in ligand stabilized diberyllium hydride complexes, Be2(CH3)2H2L2 (L = H(-), CO, N-heterocyclic carbene and CN(-)).
Nijesh K, De S, Parameswaran P., Dalton Trans 45(18), 2016
PMID: 27051892
Nijesh K, De S, Parameswaran P., Dalton Trans 45(18), 2016
PMID: 27051892
90 References
Daten bereitgestellt von Europe PubMed Central.
AUTHOR UNKNOWN, 0
AUTHOR UNKNOWN, 1993
Brookhart, Prog. Inorg. Chem. 36(), 1988
Ghiotto, Organometallics 32(), 2013
Buckton, Liebigs Ann. Suppl. 4(), 1866
Lewis, J. Chem. Phys. 21(), 1953
AUTHOR UNKNOWN, 0
Neutral ligand induced methane elimination from rare-earth metal tetramethylaluminates up to the six-coordinate carbide state.
Venugopal A, Kamps I, Bojer D, Berger RJ, Mix A, Willner A, Neumann B, Stammler HG, Mitzel NW., Dalton Trans (29), 2009
PMID: 20449090
Venugopal A, Kamps I, Bojer D, Berger RJ, Mix A, Willner A, Neumann B, Stammler HG, Mitzel NW., Dalton Trans (29), 2009
PMID: 20449090
Lewis base induced reductions in organolanthanide chemistry.
Bojer D, Venugopal A, Neumann B, Stammler HG, Mitzel NW., Angew. Chem. Int. Ed. Engl. 49(14), 2010
PMID: 20191648
Bojer D, Venugopal A, Neumann B, Stammler HG, Mitzel NW., Angew. Chem. Int. Ed. Engl. 49(14), 2010
PMID: 20191648
AUTHOR UNKNOWN, Angew. Chem. 122(), 2010
Homoleptic rare-earth metal complexes containing Ln-C σ-bonds.
Zimmermann M, Anwander R., Chem. Rev. 110(10), 2010
PMID: 20879714
Zimmermann M, Anwander R., Chem. Rev. 110(10), 2010
PMID: 20879714
C-H activation versus yttrium-methyl cation formation from [Y(AlMe4)3] induced by cyclic polynitrogen bases: solvent and substituent-size effects.
Bojer D, Venugopal A, Mix A, Neumann B, Stammler HG, Mitzel NW., Chemistry 17(22), 2011
PMID: 21503986
Bojer D, Venugopal A, Mix A, Neumann B, Stammler HG, Mitzel NW., Chemistry 17(22), 2011
PMID: 21503986
Substituent size effects in lewis base induced reductions in organolanthanide chemistry.
Bojer D, Neumann B, Stammler HG, Mitzel NW., Chemistry 17(22), 2011
PMID: 21503981
Bojer D, Neumann B, Stammler HG, Mitzel NW., Chemistry 17(22), 2011
PMID: 21503981
Synthesis and stability of homoleptic metal(III) tetramethylaluminates.
Occhipinti G, Meermann C, Dietrich HM, Litlabo R, Auras F, Tornroos KW, Maichle-Mossmer C, Jensen VR, Anwander R., J. Am. Chem. Soc. 133(16), 2011
PMID: 21466201
Occhipinti G, Meermann C, Dietrich HM, Litlabo R, Auras F, Tornroos KW, Maichle-Mossmer C, Jensen VR, Anwander R., J. Am. Chem. Soc. 133(16), 2011
PMID: 21466201
Nieland, Eur. J. Inorg. Chem. (), 2014
Boese, Organometallics 22(), 2003
AUTHOR UNKNOWN, 0
Luminescence phenomena and solid-state structures of trimethyl- and triethylgallium.
Mitzel NW, Lustig C, Berger RJ, Runeberg N., Angew. Chem. Int. Ed. Engl. 41(14), 2002
PMID: 12203520
Mitzel NW, Lustig C, Berger RJ, Runeberg N., Angew. Chem. Int. Ed. Engl. 41(14), 2002
PMID: 12203520
AUTHOR UNKNOWN, Angew. Chem. 114(), 2002
Mitzel, Z. Naturforsch. B 59(), 2004
Almenningen, Acta Chem. Scand. 25(), 1971
Vranka, J. Am. Chem. Soc. 89(), 1967
Byram, J. Chem. Soc. Chem. Commun. (), 1970
Burawoy, Nature 155(), 1945
Pitzer, J. Am. Chem. Soc. 68(), 1946
Cotton, Inorg. Chem. 9(), 1970
Huffmann, J. Chem. Soc. D (), 1971
Dewar, J. Chem. Soc. D (), 1970
McGrady, Organometallics 19(), 2000
AUTHOR UNKNOWN, 0
Hiraoka, J. Cryst. Growth 145(), 1994
Hong, Chin. J. Chem. 16(), 1998
Berthomieu, J. Phys. Chem. A 102(), 1998
Albert, J. Chem. Phys. 70(), 1979
AUTHOR UNKNOWN, 1958
Emsley, 1991
Aarset, J. Phys. Chem. A 103(), 1999
AUTHOR UNKNOWN, 0
Elschenbroich, 2008
House, 2012
Akiba, 2011
AUTHOR UNKNOWN, 0
Mitzel, J. Am. Chem. Soc. 122(), 2000
Three-membered ring or open chain molecule - (F3C)F2SiONMe2 a model for the alpha-effect in silicon chemistry.
Mitzel NW, Vojinovic K, Frohlich R, Foerster T, Robertson HE, Borisenko KB, Rankin DW., J. Am. Chem. Soc. 127(39), 2005
PMID: 16190736
Mitzel NW, Vojinovic K, Frohlich R, Foerster T, Robertson HE, Borisenko KB, Rankin DW., J. Am. Chem. Soc. 127(39), 2005
PMID: 16190736
Scherer, New J. Chem. 30(), 2006
The nature of β-agostic bonding in late-transition-metal alkyl complexes.
Scherer W, Herz V, Bruck A, Hauf C, Reiner F, Altmannshofer S, Leusser D, Stalke D., Angew. Chem. Int. Ed. Engl. 50(12), 2011
PMID: 21387502
Scherer W, Herz V, Bruck A, Hauf C, Reiner F, Altmannshofer S, Leusser D, Stalke D., Angew. Chem. Int. Ed. Engl. 50(12), 2011
PMID: 21387502
AUTHOR UNKNOWN, Angew. Chem. 123(), 2011
Winkelhaus, Z. Anorg. Allg. Chem. 639(), 2013
Hansen, Acta Crystallogr. Sect. A 34(), 1978
AUTHOR UNKNOWN, 0
A short history of SHELX.
Sheldrick GM., Acta Crystallogr., A, Found. Crystallogr. 64(Pt 1), 2007
PMID: 18156677
Sheldrick GM., Acta Crystallogr., A, Found. Crystallogr. 64(Pt 1), 2007
PMID: 18156677
Rankin, 2013
AUTHOR UNKNOWN, 0
Bader, 1990
Popelier, 2000
Matta, 2007
Bader, J. Am. Chem. Soc. 101(), 1979
AUTHOR UNKNOWN, 0
AUTHOR UNKNOWN, 0
The QTAIM approach to chemical bonding between transition metals and carbocyclic rings: a combined experimental and theoretical study of (eta(5)-C5H5)Mn(CO)3, (eta(6)-C6H6)Cr(CO)3, and (E)-{(eta(5)-C5H4)CF=CF(eta(5)-C5H4)}(eta(5)-C5H5)2Fe2.
Farrugia LJ, Evans C, Lentz D, Roemer M., J. Am. Chem. Soc. 131(3), 2009
PMID: 19102692
Farrugia LJ, Evans C, Lentz D, Roemer M., J. Am. Chem. Soc. 131(3), 2009
PMID: 19102692
Metal-metal and metal-ligand bonding at a QTAIM catastrophe: a combined experimental and theoretical charge density study on the alkylidyne cluster Fe3(μ-H)(μ-COMe)(CO)10.
Farrugia LJ, Senn HM., J Phys Chem A 114(51), 2010
PMID: 21182291
Farrugia LJ, Senn HM., J Phys Chem A 114(51), 2010
PMID: 21182291
Chemical interpretation of molecular electron density distributions.
Henn J, Leusser D, Stalke D., J Comput Chem 28(14), 2007
PMID: 17631649
Henn J, Leusser D, Stalke D., J Comput Chem 28(14), 2007
PMID: 17631649
Chemical bonding in view of electron charge density and kinetic energy density descriptors.
Jacobsen H., J Comput Chem 30(7), 2009
PMID: 19090572
Jacobsen H., J Comput Chem 30(7), 2009
PMID: 19090572
Fischer, Phys. Rev. B 91(), 2015
Klimpel, Organometallics 20(), 2001
AUTHOR UNKNOWN, 0
Cremer, Croat. Chem. Acta 56(), 1984
Cremer, Angew. Chem. Int. Ed. Engl. 23(), 1984
AUTHOR UNKNOWN, Angew. Chem. 96(), 1984
Synthesis of a pentasilapropellane. Exploring the nature of a stretched silicon-silicon bond in a nonclassical molecule.
Nied D, Koppe R, Klopper W, Schnockel H, Breher F., J. Am. Chem. Soc. 132(30), 2010
PMID: 20662508
Nied D, Koppe R, Klopper W, Schnockel H, Breher F., J. Am. Chem. Soc. 132(30), 2010
PMID: 20662508
AUTHOR UNKNOWN, 0
Steiner, J. Phys. Chem. A 105(), 2001
Four- and two-electron rules for diatropic and paratropic ring currents in monocyclic pi systems.
Seiner E, Fowler PW., Chem. Commun. (Camb.) (21), 2001
PMID: 12240120
Seiner E, Fowler PW., Chem. Commun. (Camb.) (21), 2001
PMID: 12240120
Fowler, Chem. Phys. Lett. 371(), 2003
AUTHOR UNKNOWN, 0
AUTHOR UNKNOWN, 0
Ring currents in the dismutational aromatic Si6R6.
Berger RJ, Rzepa HS, Scheschkewitz D., Angew. Chem. Int. Ed. Engl. 49(51), 2010
PMID: 21082630
Berger RJ, Rzepa HS, Scheschkewitz D., Angew. Chem. Int. Ed. Engl. 49(51), 2010
PMID: 21082630
AUTHOR UNKNOWN, Angew. Chem. 122(), 2010
A stable derivative of the global minimum on the Si6H6 potential energy surface.
Abersfelder K, White AJ, Berger RJ, Rzepa HS, Scheschkewitz D., Angew. Chem. Int. Ed. Engl. 50(34), 2011
PMID: 21728221
Abersfelder K, White AJ, Berger RJ, Rzepa HS, Scheschkewitz D., Angew. Chem. Int. Ed. Engl. 50(34), 2011
PMID: 21728221
AUTHOR UNKNOWN, Angew. Chem. 123(), 2011
Dismutational and global-minimum isomers of heavier 1,4-dimetallatetrasilabenzenes of Group 14.
Jana A, Huch V, Repisky M, Berger RJ, Scheschkewitz D., Angew. Chem. Int. Ed. Engl. 53(13), 2014
PMID: 24574162
Jana A, Huch V, Repisky M, Berger RJ, Scheschkewitz D., Angew. Chem. Int. Ed. Engl. 53(13), 2014
PMID: 24574162
AUTHOR UNKNOWN, Angew. Chem. 126(), 2014
An experimental charge density study of two isomers of hexasilabenzene.
Kratzert D, Leusser D, Holstein JJ, Dittrich B, Abersfelder K, Scheschkewitz D, Stalke D., Angew. Chem. Int. Ed. Engl. 52(16), 2013
PMID: 23494889
Kratzert D, Leusser D, Holstein JJ, Dittrich B, Abersfelder K, Scheschkewitz D, Stalke D., Angew. Chem. Int. Ed. Engl. 52(16), 2013
PMID: 23494889
AUTHOR UNKNOWN, Angew. Chem. 125(), 2013
AUTHOR UNKNOWN, 0
Calculation of current densities using gauge-including atomic orbitals.
Juselius J, Sundholm D, Gauss J., J Chem Phys 121(9), 2004
PMID: 15332941
Juselius J, Sundholm D, Gauss J., J Chem Phys 121(9), 2004
PMID: 15332941
The gauge including magnetically induced current method.
Fliegl H, Taubert S, Lehtonen O, Sundholm D., Phys Chem Chem Phys 13(46), 2011
PMID: 21909556
Fliegl H, Taubert S, Lehtonen O, Sundholm D., Phys Chem Chem Phys 13(46), 2011
PMID: 21909556
AUTHOR UNKNOWN, 0
On the chemical shifts of agostic protons.
Barquera-Lozada JE, Obenhuber A, Hauf C, Scherer W., J Phys Chem A 117(20), 2013
PMID: 23600565
Barquera-Lozada JE, Obenhuber A, Hauf C, Scherer W., J Phys Chem A 117(20), 2013
PMID: 23600565
Gillespie, 2001
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Phasenabhängige Strukturchemie - Struktur-Reaktivitäts-Beziehungen und nicht-kovalente Wechselwirkungen
Blomeyer S (2017)
Bielefeld.
Blomeyer S (2017)
Bielefeld.
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