A Neutral Silicon/Phosphorus Frustrated Lewis Pair
Waerder B, Pieper M, Körte LA, Kinder T, Mix A, Neumann B, Stammler H-G, Mitzel NW (2015)
Angewandte Chemie International Edition 54(45): 13416-13419.
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Abstract / Bemerkung
Frustrated Lewis pairs (FLPs) have a great potential for activation of small molecules. Most known FLP systems are based on boron or aluminum atoms as acid functions, few on zinc, and only two on boron-isoelectronic silicenium cation systems. The first FLP system based on a neutral silane, (C2F5)(3)SiCH2P(tBu)(2) (1), was prepared from (C2F5)(3)SiCl with C2F5 groups of very high electronegativity and LiCH2P(tBu)(2). 1 is capable of cleaving hydrogen, and adds CO2 and SO2. Hydrogen splitting was confirmed by H/D scrambling reactions. The structures of 1, its CO2 and SO2 adducts, and a decomposition product with CO2 were elucidated by X-ray diffraction.
Stichworte
silicon;
phosphorus;
hydrogen splitting;
carbon dioxide;
frustrated Lewis pairs
Erscheinungsjahr
2015
Zeitschriftentitel
Angewandte Chemie International Edition
Band
54
Ausgabe
45
Seite(n)
13416-13419
ISSN
1433-7851
Page URI
https://pub.uni-bielefeld.de/record/2788784
Zitieren
Waerder B, Pieper M, Körte LA, et al. A Neutral Silicon/Phosphorus Frustrated Lewis Pair. Angewandte Chemie International Edition. 2015;54(45):13416-13419.
Waerder, B., Pieper, M., Körte, L. A., Kinder, T., Mix, A., Neumann, B., Stammler, H. - G., et al. (2015). A Neutral Silicon/Phosphorus Frustrated Lewis Pair. Angewandte Chemie International Edition, 54(45), 13416-13419. doi:10.1002/anie.201504171
Waerder, Benedikt, Pieper, Martin, Körte, Leif Arne, Kinder, Timo, Mix, Andreas, Neumann, Beate, Stammler, Hans-Georg, and Mitzel, Norbert W. 2015. “A Neutral Silicon/Phosphorus Frustrated Lewis Pair”. Angewandte Chemie International Edition 54 (45): 13416-13419.
Waerder, B., Pieper, M., Körte, L. A., Kinder, T., Mix, A., Neumann, B., Stammler, H. - G., and Mitzel, N. W. (2015). A Neutral Silicon/Phosphorus Frustrated Lewis Pair. Angewandte Chemie International Edition 54, 13416-13419.
Waerder, B., et al., 2015. A Neutral Silicon/Phosphorus Frustrated Lewis Pair. Angewandte Chemie International Edition, 54(45), p 13416-13419.
B. Waerder, et al., “A Neutral Silicon/Phosphorus Frustrated Lewis Pair”, Angewandte Chemie International Edition, vol. 54, 2015, pp. 13416-13419.
Waerder, B., Pieper, M., Körte, L.A., Kinder, T., Mix, A., Neumann, B., Stammler, H.-G., Mitzel, N.W.: A Neutral Silicon/Phosphorus Frustrated Lewis Pair. Angewandte Chemie International Edition. 54, 13416-13419 (2015).
Waerder, Benedikt, Pieper, Martin, Körte, Leif Arne, Kinder, Timo, Mix, Andreas, Neumann, Beate, Stammler, Hans-Georg, and Mitzel, Norbert W. “A Neutral Silicon/Phosphorus Frustrated Lewis Pair”. Angewandte Chemie International Edition 54.45 (2015): 13416-13419.
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Teil dieser Dissertation
Geminale frustrierte Lewis-Paare mit Elementen der IV. und V. Hauptgruppe
Kinder T (2019)
Bielefeld: Universität Bielefeld.
Kinder T (2019)
Bielefeld: Universität Bielefeld.
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