Olefin Metathesis Reaction in Water and in Air Improved by Supramolecular Additives

Tomasek J, Seßler M, Gröger H, Schatz J (2015)
Molecules 20(10): 19130-19141.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
A range of water-immiscible commercially available Grubbs-type precatalysts can be used in ring-closing olefin metathesis reaction in high yields. The synthetic transformation is possible in pure water under ambient conditions. Sulfocalixarenes can help to boost the reactivity of the metathesis reaction by catalyst activation, improved mass transfer, and solubility of reactants in the aqueous reaction media. Additionally, the use of supramolecular additives allows lower catalyst loadings, but still high activity in pure water under aerobic conditions.
Erscheinungsjahr
Zeitschriftentitel
Molecules
Band
20
Ausgabe
10
Seite(n)
19130-19141
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Tomasek J, Seßler M, Gröger H, Schatz J. Olefin Metathesis Reaction in Water and in Air Improved by Supramolecular Additives. Molecules. 2015;20(10):19130-19141.
Tomasek, J., Seßler, M., Gröger, H., & Schatz, J. (2015). Olefin Metathesis Reaction in Water and in Air Improved by Supramolecular Additives. Molecules, 20(10), 19130-19141. doi:10.3390/molecules201019130
Tomasek, J., Seßler, M., Gröger, H., and Schatz, J. (2015). Olefin Metathesis Reaction in Water and in Air Improved by Supramolecular Additives. Molecules 20, 19130-19141.
Tomasek, J., et al., 2015. Olefin Metathesis Reaction in Water and in Air Improved by Supramolecular Additives. Molecules, 20(10), p 19130-19141.
J. Tomasek, et al., “Olefin Metathesis Reaction in Water and in Air Improved by Supramolecular Additives”, Molecules, vol. 20, 2015, pp. 19130-19141.
Tomasek, J., Seßler, M., Gröger, H., Schatz, J.: Olefin Metathesis Reaction in Water and in Air Improved by Supramolecular Additives. Molecules. 20, 19130-19141 (2015).
Tomasek, Jasmine, Seßler, Miriam, Gröger, Harald, and Schatz, Jürgen. “Olefin Metathesis Reaction in Water and in Air Improved by Supramolecular Additives”. Molecules 20.10 (2015): 19130-19141.

3 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Ammonium-tagged ruthenium-based catalysts for olefin metathesis in aqueous media under ultrasound and microwave irradiation.
Gułajski Ł, Tracz A, Urbaniak K, Czarnocki SJ, Bieniek M, Olszewski TK., Beilstein J Org Chem 15(), 2019
PMID: 30745991
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Vougioukalakis GC., Molecules 21(12), 2016
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