A Unique Fluoride Nanocontainer: Porous Molecular Capsules Can Accommodate an Unusually High Number of "Rather Labile" Fluoride Anions
Garai S, Rubcic M, Bögge H, Haupt ETK, Gouzerh P, Müller A (2015)
Angewandte Chemie International Edition 54(20): 5879-5882.
Zeitschriftenaufsatz
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Autor*in
Garai, Somenath;
Rubcic, Mirta;
Bögge, HartmutUniBi;
Haupt, Erhard T. K.;
Gouzerh, Pierre;
Müller, AchimUniBi 
Einrichtung
Abstract / Bemerkung
The present work refers to the challenging issue of fluoride anion recognition/binding in water by taking advantage of the unique possibilities offered by the porous molecular nanocontainers of the {Mo-132} Keplerate type allowing the study of a variety of new phenomena. Reaction of the highly reactive carbonate-type capsule with aqueous HF results in the release of carbon dioxide and integration of an unprecedentedly large number of fluoride anions-partly as coordinated ligands at both the pentagonal units and the linkers, partly as a disordered water/fluoride assembly inside the cavity. The internal assembly and some of the fluoride ligands are easily released, which provides interesting options for future studies regarding coordination chemistry and catalysis under confined conditions.
Stichworte
fluorides;
polyoxometalates;
porous capsules;
water dimers;
receptors
Erscheinungsjahr
2015
Zeitschriftentitel
Angewandte Chemie International Edition
Band
54
Ausgabe
20
Seite(n)
5879-5882
ISSN
1433-7851
Page URI
https://pub.uni-bielefeld.de/record/2758197
Zitieren
Garai S, Rubcic M, Bögge H, Haupt ETK, Gouzerh P, Müller A. A Unique Fluoride Nanocontainer: Porous Molecular Capsules Can Accommodate an Unusually High Number of "Rather Labile" Fluoride Anions. Angewandte Chemie International Edition. 2015;54(20):5879-5882.
Garai, S., Rubcic, M., Bögge, H., Haupt, E. T. K., Gouzerh, P., & Müller, A. (2015). A Unique Fluoride Nanocontainer: Porous Molecular Capsules Can Accommodate an Unusually High Number of "Rather Labile" Fluoride Anions. Angewandte Chemie International Edition, 54(20), 5879-5882. doi:10.1002/anie.201411814
Garai, Somenath, Rubcic, Mirta, Bögge, Hartmut, Haupt, Erhard T. K., Gouzerh, Pierre, and Müller, Achim. 2015. “A Unique Fluoride Nanocontainer: Porous Molecular Capsules Can Accommodate an Unusually High Number of "Rather Labile" Fluoride Anions”. Angewandte Chemie International Edition 54 (20): 5879-5882.
Garai, S., Rubcic, M., Bögge, H., Haupt, E. T. K., Gouzerh, P., and Müller, A. (2015). A Unique Fluoride Nanocontainer: Porous Molecular Capsules Can Accommodate an Unusually High Number of "Rather Labile" Fluoride Anions. Angewandte Chemie International Edition 54, 5879-5882.
Garai, S., et al., 2015. A Unique Fluoride Nanocontainer: Porous Molecular Capsules Can Accommodate an Unusually High Number of "Rather Labile" Fluoride Anions. Angewandte Chemie International Edition, 54(20), p 5879-5882.
S. Garai, et al., “A Unique Fluoride Nanocontainer: Porous Molecular Capsules Can Accommodate an Unusually High Number of "Rather Labile" Fluoride Anions”, Angewandte Chemie International Edition, vol. 54, 2015, pp. 5879-5882.
Garai, S., Rubcic, M., Bögge, H., Haupt, E.T.K., Gouzerh, P., Müller, A.: A Unique Fluoride Nanocontainer: Porous Molecular Capsules Can Accommodate an Unusually High Number of "Rather Labile" Fluoride Anions. Angewandte Chemie International Edition. 54, 5879-5882 (2015).
Garai, Somenath, Rubcic, Mirta, Bögge, Hartmut, Haupt, Erhard T. K., Gouzerh, Pierre, and Müller, Achim. “A Unique Fluoride Nanocontainer: Porous Molecular Capsules Can Accommodate an Unusually High Number of "Rather Labile" Fluoride Anions”. Angewandte Chemie International Edition 54.20 (2015): 5879-5882.
Daten bereitgestellt von European Bioinformatics Institute (EBI)
2 Zitationen in Europe PMC
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