Syntheses and reductions of C-dimesitylboryl-1,2-dicarba-closo-dodecaboranes
Kahlert J, Böhling L, Brockhinke A, Stammler H-G, Neumann B, Rendina LM, Low PJ, Weber L, Fox MA (2015)
Journal of the Chemical Society. Dalton Transactions 44(21): 9766-9781.
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Autor*in
Kahlert, JanUniBi;
Böhling, LenaUniBi;
Brockhinke, AndreasUniBi;
Stammler, Hans-GeorgUniBi;
Neumann, BeateUniBi;
Rendina, Louis M.;
Low, Paul J.;
Weber, LotharUniBi;
Fox, Mark A.
Einrichtung
Abstract / Bemerkung
Two C-dimesitylboryl-1,2-dicarba-closo-dodecaboranes, 1-(BMes(2))-2-R-1,2-C2B10H10 (1, R = H, 2, R = Ph), were synthesised by lithiation of 1,2-dicarba-closo-dodecaborane and 1-phenyl-1,2-dicarba-closo-dodecaborane, respectively, with n-butyllithium and subsequent reaction with fluorodimesitylborane. These novel compounds were structurally characterised by X-ray crystallography. Compounds 1 and 2 are hydrolysed on prolonged exposure to air to give mesitylene and boronic acids 1-(B(OH)(2))-2-R-1,2-C2B10H10 (3, R = H, 4, R = Ph respectively). Addition of fluoride anions to 1 and 2 resulted in boryl-carborane bond cleavage to give dimesitylborinic acid HOBMes(2). UV absorption bands at 318-333 nm were observed for 1 and 2 corresponding to local pi-pi*-transitions within the dimesitylboryl groups while visible emissions at 541-664 nm with Stokes shifts of 11 920-16 170 cm(-1) were attributed to intra-molecular charge transfer transitions between the mesityl and cluster groups. Compound 2 was shown by cyclic voltammetry to form a stable dianion on reduction. NMR spectra for the dianion [2](2-) were recorded from solutions generated by reductions of 2 with alkali metals and compared with NMR spectra from reductions of 1,2-diphenyl-ortho-carborane 5. On the basis of observed and computed B-11 NMR shifts, these nido-dianions contain bowl-shaped cluster geometries. The carborane is viewed as the electron-acceptor and the mesityl group is the electron-donor in C-dimesitylboryl-1,2-dicarba-closo-dodecaboranes.
Erscheinungsjahr
2015
Zeitschriftentitel
Journal of the Chemical Society. Dalton Transactions
Band
44
Ausgabe
21
Seite(n)
9766-9781
ISSN
1477-9226
Page URI
https://pub.uni-bielefeld.de/record/2758180
Zitieren
Kahlert J, Böhling L, Brockhinke A, et al. Syntheses and reductions of C-dimesitylboryl-1,2-dicarba-closo-dodecaboranes. Journal of the Chemical Society. Dalton Transactions. 2015;44(21):9766-9781.
Kahlert, J., Böhling, L., Brockhinke, A., Stammler, H. - G., Neumann, B., Rendina, L. M., Low, P. J., et al. (2015). Syntheses and reductions of C-dimesitylboryl-1,2-dicarba-closo-dodecaboranes. Journal of the Chemical Society. Dalton Transactions, 44(21), 9766-9781. doi:10.1039/c5dt00758e
Kahlert, Jan, Böhling, Lena, Brockhinke, Andreas, Stammler, Hans-Georg, Neumann, Beate, Rendina, Louis M., Low, Paul J., Weber, Lothar, and Fox, Mark A. 2015. “Syntheses and reductions of C-dimesitylboryl-1,2-dicarba-closo-dodecaboranes”. Journal of the Chemical Society. Dalton Transactions 44 (21): 9766-9781.
Kahlert, J., Böhling, L., Brockhinke, A., Stammler, H. - G., Neumann, B., Rendina, L. M., Low, P. J., Weber, L., and Fox, M. A. (2015). Syntheses and reductions of C-dimesitylboryl-1,2-dicarba-closo-dodecaboranes. Journal of the Chemical Society. Dalton Transactions 44, 9766-9781.
Kahlert, J., et al., 2015. Syntheses and reductions of C-dimesitylboryl-1,2-dicarba-closo-dodecaboranes. Journal of the Chemical Society. Dalton Transactions, 44(21), p 9766-9781.
J. Kahlert, et al., “Syntheses and reductions of C-dimesitylboryl-1,2-dicarba-closo-dodecaboranes”, Journal of the Chemical Society. Dalton Transactions, vol. 44, 2015, pp. 9766-9781.
Kahlert, J., Böhling, L., Brockhinke, A., Stammler, H.-G., Neumann, B., Rendina, L.M., Low, P.J., Weber, L., Fox, M.A.: Syntheses and reductions of C-dimesitylboryl-1,2-dicarba-closo-dodecaboranes. Journal of the Chemical Society. Dalton Transactions. 44, 9766-9781 (2015).
Kahlert, Jan, Böhling, Lena, Brockhinke, Andreas, Stammler, Hans-Georg, Neumann, Beate, Rendina, Louis M., Low, Paul J., Weber, Lothar, and Fox, Mark A. “Syntheses and reductions of C-dimesitylboryl-1,2-dicarba-closo-dodecaboranes”. Journal of the Chemical Society. Dalton Transactions 44.21 (2015): 9766-9781.
Daten bereitgestellt von European Bioinformatics Institute (EBI)
6 Zitationen in Europe PMC
Daten bereitgestellt von Europe PubMed Central.
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Naito H, Nishino K, Morisaki Y, Tanaka K, Chujo Y., Angew Chem Int Ed Engl 56(1), 2017
PMID: 27911472
Naito H, Nishino K, Morisaki Y, Tanaka K, Chujo Y., Angew Chem Int Ed Engl 56(1), 2017
PMID: 27911472
A Carborane-Containing Fluorophore as a Stain of Cellular Lipid Droplets.
Wu A, Kolanowski JL, Boumelhem BB, Yang K, Lee R, Kaur A, Fraser ST, New EJ, Rendina LM., Chem Asian J 12(14), 2017
PMID: 28640518
Wu A, Kolanowski JL, Boumelhem BB, Yang K, Lee R, Kaur A, Fraser ST, New EJ, Rendina LM., Chem Asian J 12(14), 2017
PMID: 28640518
Luminescence Color Tuning from Blue to Near Infrared of Stable Luminescent Solid Materials Based on Bis-o-Carborane-Substituted Oligoacenes.
Naito H, Nishino K, Morisaki Y, Tanaka K, Chujo Y., Chem Asian J 12(16), 2017
PMID: 28649772
Naito H, Nishino K, Morisaki Y, Tanaka K, Chujo Y., Chem Asian J 12(16), 2017
PMID: 28649772
Enhancement of Aggregation-Induced Emission by Introducing Multiple o-Carborane Substitutions into Triphenylamine.
Nishino K, Uemura K, Gon M, Tanaka K, Chujo Y., Molecules 22(11), 2017
PMID: 29156590
Nishino K, Uemura K, Gon M, Tanaka K, Chujo Y., Molecules 22(11), 2017
PMID: 29156590
Luminescent Metal Complexes Featuring Photophysically Innocent Boron Cluster Ligands.
Kirlikovali KO, Axtell JC, Gonzalez A, Phung AC, Khan SI, Spokoyny AM., Chem Sci 7(8), 2016
PMID: 28191302
Kirlikovali KO, Axtell JC, Gonzalez A, Phung AC, Khan SI, Spokoyny AM., Chem Sci 7(8), 2016
PMID: 28191302
Blue-shifted emission and enhanced quantum efficiency viaπ-bridge elongation in carbazole-carborane dyads.
Wang Z, Jiang P, Wang T, Moxey GJ, Cifuentes MP, Zhang C, Humphrey MG., Phys Chem Chem Phys 18(23), 2016
PMID: 27225829
Wang Z, Jiang P, Wang T, Moxey GJ, Cifuentes MP, Zhang C, Humphrey MG., Phys Chem Chem Phys 18(23), 2016
PMID: 27225829
196 References
Daten bereitgestellt von Europe PubMed Central.
Entwistle, Angew. Chem. 114(), 2002
Entwistle, Chem. Mater. 16(), 2004
Yamaguchi, Pure Appl. Chem. 78(), 2006
Jäkle, Coord. Chem. Rev. 250(), 2006
Schulz, Chem. Ber. 122(), 1989
Glogowski, J. Organomet. Chem. 218(), 1981
Noda, J. Am. Chem. Soc. 120(), 1998
Kinoshita, Synth. Met. 121(), 2001
Three-coordinate organoboron compounds BAr2R (Ar = mesityl, R = 7-azaindolyl- or 2,2'-dipyridylamino-functionalized aryl or thienyl) for electroluminescent devices and supramolecular assembly.
Jia WL, Bai DR, McCormick T, Liu QD, Motala M, Wang RY, Seward C, Tao Y, Wang S., Chemistry 10(4), 2004
PMID: 14978826
Jia WL, Bai DR, McCormick T, Liu QD, Motala M, Wang RY, Seward C, Tao Y, Wang S., Chemistry 10(4), 2004
PMID: 14978826
Jia, Chem. Mater. 17(), 2005
Mazzeo, Adv. Mater. 17(), 2005
Noda, Adv. Mater. 11(), 1999
Noda, J. Lumin. 87–89(), 2000
Shirota, J. Am. Chem. Soc. 122(), 2000
Wong, Aust. J. Chem. 60(), 2007
Zhou, Adv. Funct. Mater. 18(), 2008
Ho;, J. Organomet. Chem. 730(), 2013
Synthesis and spectroscopic properties of platinum(II) terpyridine complexes having an arylborane charge transfer unit.
Sakuda E, Funahashi A, Kitamura N., Inorg Chem 45(26), 2006
PMID: 17173422
Sakuda E, Funahashi A, Kitamura N., Inorg Chem 45(26), 2006
PMID: 17173422
A heteronuclear bidentate Lewis acid as a phosphorescent fluoride sensor.
Melaimi M, Gabbai FP., J. Am. Chem. Soc. 127(27), 2005
PMID: 15998060
Melaimi M, Gabbai FP., J. Am. Chem. Soc. 127(27), 2005
PMID: 15998060
Cationic boranes for the complexation of fluoride ions in water below the 4 ppm maximum contaminant level.
Kim Y, Gabbai FP., J. Am. Chem. Soc. 131(9), 2009
PMID: 19256571
Kim Y, Gabbai FP., J. Am. Chem. Soc. 131(9), 2009
PMID: 19256571
Ambient-temperature metal-to-ligand charge-transfer phosphorescence facilitated by triarylboron: Bnpa and its metal complexes.
Zhao SB, McCormick T, Wang S., Inorg Chem 46(26), 2007
PMID: 18052060
Zhao SB, McCormick T, Wang S., Inorg Chem 46(26), 2007
PMID: 18052060
Donor-and-acceptor substituted truxenes as multifunctional fluorescent probes.
Yuan MS, Liu ZQ, Fang Q., J. Org. Chem. 72(21), 2007
PMID: 17880237
Yuan MS, Liu ZQ, Fang Q., J. Org. Chem. 72(21), 2007
PMID: 17880237
Liu, Angew. Chem. 118(), 2006
Charge-transfer emission involving three-coordinate organoboron: V-shape versus U-shape and impact of the spacer on dual emission and fluorescent sensing.
Bai DR, Liu XY, Wang S., Chemistry 13(20), 2007
PMID: 17508365
Bai DR, Liu XY, Wang S., Chemistry 13(20), 2007
PMID: 17508365
Fluoride ion complexation by a cationic borane in aqueous solution.
Lee MH, Agou T, Kobayashi J, Kawashima T, Gabbai FP., Chem. Commun. (Camb.) (11), 2007
PMID: 17347716
Lee MH, Agou T, Kobayashi J, Kawashima T, Gabbai FP., Chem. Commun. (Camb.) (11), 2007
PMID: 17347716
Hybrid Lewis acid/hydrogen-bond donor receptor for fluoride.
Hudnall TW, Melaimi M, Gabbai FP., Org. Lett. 8(13), 2006
PMID: 16774247
Hudnall TW, Melaimi M, Gabbai FP., Org. Lett. 8(13), 2006
PMID: 16774247
A boron-containing carbazole dimer: synthesis, photophysical properties and sensing properties.
Shi HP, Dai JX, Xu L, Shi LW, Fang L, Shuang SM, Dong C., Org. Biomol. Chem. 10(19), 2012
PMID: 22526353
Shi HP, Dai JX, Xu L, Shi LW, Fang L, Shuang SM, Dong C., Org. Biomol. Chem. 10(19), 2012
PMID: 22526353
Fluoride ion capture from water with a cationic borane.
Chiu CW, Gabbai FP., J. Am. Chem. Soc. 128(44), 2006
PMID: 17076485
Chiu CW, Gabbai FP., J. Am. Chem. Soc. 128(44), 2006
PMID: 17076485
Colorimetric fluoride ion sensing by boron-containing pi-electron systems.
Yamaguchi S, Akiyama S, Tamao K., J. Am. Chem. Soc. 123(46), 2001
PMID: 11707112
Yamaguchi S, Akiyama S, Tamao K., J. Am. Chem. Soc. 123(46), 2001
PMID: 11707112
Dibenzoborole-containing pi-electron systems: remarkable fluorescence change based on the "on/off" control of the p(pi)-pi* conjugation.
Yamaguchi S, Shirasaka T, Akiyama S, Tamao K., J. Am. Chem. Soc. 124(30), 2002
PMID: 12137533
Yamaguchi S, Shirasaka T, Akiyama S, Tamao K., J. Am. Chem. Soc. 124(30), 2002
PMID: 12137533
Kubo, Angew. Chem. 115(), 2003
A bidentate borane as colorimetric fluoride ion sensor.
Sole S, Gabbai FP., Chem. Commun. (Camb.) (11), 2004
PMID: 15154038
Sole S, Gabbai FP., Chem. Commun. (Camb.) (11), 2004
PMID: 15154038
Ammonium boranes for the selective complexation of cyanide or fluoride ions in water.
Hudnall TW, Gabbai FP., J. Am. Chem. Soc. 129(39), 2007
PMID: 17845043
Hudnall TW, Gabbai FP., J. Am. Chem. Soc. 129(39), 2007
PMID: 17845043
A family of main-chain polymeric Lewis acids: synthesis and fluorescent sensing properties of boron-modified polythiophenes.
Sundararaman A, Victor M, Varughese R, Jakle F., J. Am. Chem. Soc. 127(40), 2005
PMID: 16201769
Sundararaman A, Victor M, Varughese R, Jakle F., J. Am. Chem. Soc. 127(40), 2005
PMID: 16201769
Luminescent triarylborane-functionalized polystyrene: synthesis, photophysical characterization, and anion-binding studies.
Parab K, Venkatasubbaiah K, Jakle F., J. Am. Chem. Soc. 128(39), 2006
PMID: 17002382
Parab K, Venkatasubbaiah K, Jakle F., J. Am. Chem. Soc. 128(39), 2006
PMID: 17002382
Synthesis, one- and two-photon photophysical and excited-state properties, and sensing application of a new phosphorescent dinuclear cationic iridium(III) complex.
Xu WJ, Liu SJ, Zhao X, Zhao N, Liu ZQ, Xu H, Liang H, Zhao Q, Yu XQ, Huang W., Chemistry 19(2), 2012
PMID: 23229190
Xu WJ, Liu SJ, Zhao X, Zhao N, Liu ZQ, Xu H, Liang H, Zhao Q, Yu XQ, Huang W., Chemistry 19(2), 2012
PMID: 23229190
D-π-A triarylboron compounds with tunable push-pull character achieved by modification of both the donor and acceptor moieties.
Zhang Z, Edkins RM, Nitsch J, Fucke K, Eichhorn A, Steffen A, Wang Y, Marder TB., Chemistry 21(1), 2014
PMID: 25413782
Zhang Z, Edkins RM, Nitsch J, Fucke K, Eichhorn A, Steffen A, Wang Y, Marder TB., Chemistry 21(1), 2014
PMID: 25413782
Diazaborolyl-boryl push-pull systems with ethynylene-arylene bridges as 'turn-on' fluoride sensors.
Weber L, Eickhoff D, Kahlert J, Bohling L, Brockhinke A, Stammler HG, Neumann B, Fox MA., Dalton Trans 41(34), 2012
PMID: 22810804
Weber L, Eickhoff D, Kahlert J, Bohling L, Brockhinke A, Stammler HG, Neumann B, Fox MA., Dalton Trans 41(34), 2012
PMID: 22810804
Zhao, Organometallics 27(), 2008
Turn-on fluorescence sensing of cyanide ions in aqueous solution at parts-per-billion concentrations.
Kim Y, Huh HS, Lee MH, Lenov IL, Zhao H, Gabbai FP., Chemistry 17(7), 2011
PMID: 21294176
Kim Y, Huh HS, Lee MH, Lenov IL, Zhao H, Gabbai FP., Chemistry 17(7), 2011
PMID: 21294176
Triarylboranes with a 2-dimesitylboryl-2'-(N,N-dimethylamino)biphenyl core unit: structure-property correlations and sensing abilities to discriminate between F(-) and CN(-) ions.
Wang C, Jia J, Zhang WN, Zhang HY, Zhao CH., Chemistry 20(50), 2014
PMID: 25336407
Wang C, Jia J, Zhang WN, Zhang HY, Zhao CH., Chemistry 20(50), 2014
PMID: 25336407
Jia, Tetrahedron 70(), 2014
Bresner, New J. Chem. 34(), 2010
Grimes, 2011
Dash, New J. Chem. 35(), 2011
Sivaev, Eur. J. Inorg. Chem. (), 2009
Boron in drug discovery: carboranes as unique pharmacophores in biologically active compounds.
Issa F, Kassiou M, Rendina LM., Chem. Rev. 111(9), 2011
PMID: 21718011
Issa F, Kassiou M, Rendina LM., Chem. Rev. 111(9), 2011
PMID: 21718011
Carbaboranes as pharmacophores: properties, synthesis, and application strategies.
Scholz M, Hey-Hawkins E., Chem. Rev. 111(11), 2011
PMID: 21780840
Scholz M, Hey-Hawkins E., Chem. Rev. 111(11), 2011
PMID: 21780840
Valliant, Coord. Chem. Rev. 232(), 2002
Kalinin, Russ. Chem. Bull. 57(), 2008
Bregadze, Chem. Rev. 92(), 1992
The bioinorganic and medicinal chemistry of carboranes: from new drug discovery to molecular imaging and therapy.
Armstrong AF, Valliant JF., Dalton Trans (38), 2007
PMID: 17893811
Armstrong AF, Valliant JF., Dalton Trans (38), 2007
PMID: 17893811
Leites, Chem. Rev. 92(), 1992
Wedge, Coord. Chem. Rev. 240(), 2003
Methods to produce B-C, B-P, B-N and B-S bonds in boron clusters.
Olid D, Nunez R, Vinas C, Teixidor F., Chem Soc Rev 42(8), 2013
PMID: 23318646
Olid D, Nunez R, Vinas C, Teixidor F., Chem Soc Rev 42(8), 2013
PMID: 23318646
Viñas, 2012
Boron-enriched star-shaped molecule via cycloaddition reaction.
Prasanna Dash B, Satapathy R, Maguire JA, Hosmane NS., Chem. Commun. (Camb.) (22), 2009
PMID: 19587935
Prasanna Dash B, Satapathy R, Maguire JA, Hosmane NS., Chem. Commun. (Camb.) (22), 2009
PMID: 19587935
Kabachii, Int. J. Polym. Mater. 14(), 1990
Hideaki, Chem. Mater. 15(), 2003
Poly[di(2-thiophenyl)carborane]s: conducting polymers with high electrochemical and thermal resistance.
Hao E, Fabre B, Fronczek FR, Vicente MG., Chem. Commun. (Camb.) (42), 2007
PMID: 17957295
Hao E, Fabre B, Fronczek FR, Vicente MG., Chem. Commun. (Camb.) (42), 2007
PMID: 17957295
Hao, Chem. Mater. 19(), 2007
Fox, J. Mater. Chem. 12(), 2002
Synthesis and hydrogen sorption properties of carborane based metal-organic framework materials.
Farha OK, Spokoyny AM, Mulfort KL, Hawthorne MF, Mirkin CA, Hupp JT., J. Am. Chem. Soc. 129(42), 2007
PMID: 17900124
Farha OK, Spokoyny AM, Mulfort KL, Hawthorne MF, Mirkin CA, Hupp JT., J. Am. Chem. Soc. 129(42), 2007
PMID: 17900124
Llop, J. Organomet. Chem. 657(), 2002
Strikingly long C...C distances in 1,2-disubstituted ortho-carboranes and their dianions.
Oliva JM, Allan NL, Schleyer PV, Vinas C, Teixidor F., J. Am. Chem. Soc. 127(39), 2005
PMID: 16190717
Oliva JM, Allan NL, Schleyer PV, Vinas C, Teixidor F., J. Am. Chem. Soc. 127(39), 2005
PMID: 16190717
Brown, J. Chem. Soc., Chem. Commun. (), 1987
Exo-pi-bonding to an ortho-carborane hypercarbon atom: systematic icosahedral cage distortions reflected in the structures of the fluoro-, hydroxy- and amino-carboranes, 1-X-2-Ph-1,2-C2B10H10 (X=F, OH or NH2) and related anions.
Boyd LA, Clegg W, Copley RC, Davidson MG, Fox MA, Hibbert TG, Howard JA, Mackinnon A, Peace RJ, Wade K., Dalton Trans (17), 2004
PMID: 15514767
Boyd LA, Clegg W, Copley RC, Davidson MG, Fox MA, Hibbert TG, Howard JA, Mackinnon A, Peace RJ, Wade K., Dalton Trans (17), 2004
PMID: 15514767
Getman, J. Am. Chem. Soc. 112(), 1990
Getman, Inorg. Chem. 31(), 1992
Svidlov, Inorg. Chem. Commun. 43(), 2014
Marshall, Polym. Chem. 5(), 2014
Marshall, J. Mater. Chem. C 2(), 2014
Fajardo, Inorg. Chim. Acta 422(), 2014
Wrackmeyer, Eur. J. Inorg. Chem. (), 2014
Qiu, Tetrahedron Lett. 56(), 2015
Carborane functionalization of the aromatic network in chemically-synthesized graphene.
Kahlert JU, Rawal A, Hook JM, Rendina LM, Choucair M., Chem. Commun. (Camb.) 50(77), 2014
PMID: 25116510
Kahlert JU, Rawal A, Hook JM, Rendina LM, Choucair M., Chem. Commun. (Camb.) 50(77), 2014
PMID: 25116510
El-Zaria, Angew. Chem., Int. Ed. 53(), 2014
Junold, Eur. J. Inorg. Chem. (), 2014
Self-assembly of a family of suprametallomacrocycles: revisiting an o-carborane bisterpyridyl building block.
Ludlow Iii JM, Tominaga M, Chujo Y, Schultz A, Lu X, Xie T, Guo K, Moorefield CN, Wesdemiotis C, Newkome GR., Dalton Trans 43(25), 2014
PMID: 24832526
Ludlow Iii JM, Tominaga M, Chujo Y, Schultz A, Lu X, Xie T, Guo K, Moorefield CN, Wesdemiotis C, Newkome GR., Dalton Trans 43(25), 2014
PMID: 24832526
Carbaborane-based alkynylphosphanes and phospholes.
Kreienbrink A, Sarosi MB, Kuhnert R, Wonneberger P, Arkhypchuk AI, Lonnecke P, Ott S, Hey-Hawkins E., Chem. Commun. (Camb.) 51(5), 2014
PMID: 25411728
Kreienbrink A, Sarosi MB, Kuhnert R, Wonneberger P, Arkhypchuk AI, Lonnecke P, Ott S, Hey-Hawkins E., Chem. Commun. (Camb.) 51(5), 2014
PMID: 25411728
Palladium-catalyzed regioselective intramolecular coupling of o-carborane with aromatics via direct cage B-H activation.
Quan Y, Xie Z., J. Am. Chem. Soc. 137(10), 2015
PMID: 25747772
Quan Y, Xie Z., J. Am. Chem. Soc. 137(10), 2015
PMID: 25747772
Syntheses and structural characterization of o-carboranylamides with direct cage-amide bond.
Nie Y, Wang Y, Miao J, Bian D, Zhang Z, Cui Y, Sun G., Dalton Trans 43(13), 2014
PMID: 24468795
Nie Y, Wang Y, Miao J, Bian D, Zhang Z, Cui Y, Sun G., Dalton Trans 43(13), 2014
PMID: 24468795
Bregadze, Russ. Chem. Bull. 63(), 2014
Palladium catalyzed selective mono-arylation of o-carboranes via B-H activation.
Cao K, Huang Y, Yang J, Wu J., Chem. Commun. (Camb.) 51(33), 2015
PMID: 25821158
Cao K, Huang Y, Yang J, Wu J., Chem. Commun. (Camb.) 51(33), 2015
PMID: 25821158
Photophysical properties of carborane-containing derivatives of 5,10,15,20-tetra(p-aminophenyl)porphyrin.
Paschenko VZ, Evstigneeva RP, Gorokhov VV, Luzgina VN, Tusov VB, Rubin AB., J. Photochem. Photobiol. B, Biol. 54(2-3), 2000
PMID: 10836547
Paschenko VZ, Evstigneeva RP, Gorokhov VV, Luzgina VN, Tusov VB, Rubin AB., J. Photochem. Photobiol. B, Biol. 54(2-3), 2000
PMID: 10836547
Luzgina, Russ. J. Org. Chem. 43(), 2007
Enhanced π-conjugation and emission via icosahedral carboranes: synthetic and spectroscopic investigation.
Dash BP, Satapathy R, Gaillard ER, Norton KM, Maguire JA, Chug N, Hosmane NS., Inorg Chem 50(12), 2011
PMID: 21612206
Dash BP, Satapathy R, Gaillard ER, Norton KM, Maguire JA, Chug N, Hosmane NS., Inorg Chem 50(12), 2011
PMID: 21612206
Synthesis and characterization of new fluorescent styrene-containing carborane derivatives: the singular quenching role of a phenyl substituent.
Ferrer-Ugalde A, Juarez-Perez EJ, Teixidor F, Vinas C, Sillanpaa R, Perez-Inestrosa E, Nunez R., Chemistry 18(2), 2011
PMID: 22147538
Ferrer-Ugalde A, Juarez-Perez EJ, Teixidor F, Vinas C, Sillanpaa R, Perez-Inestrosa E, Nunez R., Chemistry 18(2), 2011
PMID: 22147538
Carborane enhanced two-photon absorption of tribranched fluorophores for fluorescence microscopy imaging.
Zhu L, Lv W, Liu S, Yan H, Zhao Q, Huang W., Chem. Commun. (Camb.) 49(90), 2013
PMID: 24096285
Zhu L, Lv W, Liu S, Yan H, Zhao Q, Huang W., Chem. Commun. (Camb.) 49(90), 2013
PMID: 24096285
Fluorescence of new o-carborane compounds with different fluorophores: can it be tuned?
Ferrer-Ugalde A, Gonzalez-Campo A, Vinas C, Rodriguez-Romero J, Santillan R, Farfan N, Sillanpaa R, Sousa-Pedrares A, Nunez R, Teixidor F., Chemistry 20(32), 2014
PMID: 24976049
Ferrer-Ugalde A, Gonzalez-Campo A, Vinas C, Rodriguez-Romero J, Santillan R, Farfan N, Sillanpaa R, Sousa-Pedrares A, Nunez R, Teixidor F., Chemistry 20(32), 2014
PMID: 24976049
BODIPY functionalized o-carborane dyads for low-energy photosensitization.
Jin GF, Cho YJ, Wee KR, Hong SA, Suh IH, Son HJ, Lee JD, Han WS, Cho DW, Kang SO., Dalton Trans 44(6), 2015
PMID: 25482506
Jin GF, Cho YJ, Wee KR, Hong SA, Suh IH, Son HJ, Lee JD, Han WS, Cho DW, Kang SO., Dalton Trans 44(6), 2015
PMID: 25482506
Kokado, Macromolecules 42(), 2009
Kokado, Macromolecules 42(), 2009
Kokado, Macromolecules 43(), 2010
Kokado, Polym. J. 42(), 2010
Kokado, Tetrahedron Lett. 52(), 2011
A luminescent coordination polymer based on bisterpyridyl ligand containing o-carborane: two tunable emission modes.
Kokado K, Chujo Y., Dalton Trans 40(9), 2011
PMID: 21258739
Kokado K, Chujo Y., Dalton Trans 40(9), 2011
PMID: 21258739
Multicolor tuning of aggregation-induced emission through substituent variation of diphenyl-o-carborane.
Kokado K, Chujo Y., J. Org. Chem. 76(1), 2010
PMID: 21158383
Kokado K, Chujo Y., J. Org. Chem. 76(1), 2010
PMID: 21158383
Tominaga, Asian J. Org. Chem. 3(), 2014
Tominaga, New J. Chem. 38(), 2014
Wee, Angew. Chem. 124(), 2012
Carborane dyads for photoinduced electron transfer: photophysical studies on carbazole and phenyl-o-carborane molecular assemblies.
Kwon S, Wee KR, Cho YJ, Kang SO., Chemistry 20(20), 2014
PMID: 24805274
Kwon S, Wee KR, Cho YJ, Kang SO., Chemistry 20(20), 2014
PMID: 24805274
Inagi, Electrochemistry 81(), 2013
Eo, Polymer 54(), 2013
Through-space charge transfer and emission color tuning of di-o-carborane substituted benzene.
Bae HJ, Kim H, Lee KM, Kim T, Lee YS, Do Y, Lee MH., Dalton Trans 43(13), 2014
PMID: 24158622
Bae HJ, Kim H, Lee KM, Kim T, Lee YS, Do Y, Lee MH., Dalton Trans 43(13), 2014
PMID: 24158622
Naito, Angew. Chem. 127(), 2015
Davis, ACS Macro Lett. 1(), 2012
Carborane-containing poly(fluorene): response to solvent vapors and amines.
Peterson JJ, Davis AR, Werre M, Coughlin EB, Carter KR., ACS Appl Mater Interfaces 3(6), 2011
PMID: 21591744
Peterson JJ, Davis AR, Werre M, Coughlin EB, Carter KR., ACS Appl Mater Interfaces 3(6), 2011
PMID: 21591744
Peterson, Macromolecules 42(), 2009
Luminescence properties of C-diazaborolyl-ortho-carboranes as donor-acceptor systems.
Weber L, Kahlert J, Brockhinke R, Bohling L, Brockhinke A, Stammler HG, Neumann B, Harder RA, Fox MA., Chemistry 18(27), 2012
PMID: 22623079
Weber L, Kahlert J, Brockhinke R, Bohling L, Brockhinke A, Stammler HG, Neumann B, Harder RA, Fox MA., Chemistry 18(27), 2012
PMID: 22623079
Electrochemical and spectroelectrochemical studies of C-benzodiazaborolyl-ortho-carboranes.
Weber L, Kahlert J, Bohling L, Brockhinke A, Stammler HG, Neumann B, Harder RA, Low PJ, Fox MA., Dalton Trans 42(6), 2013
PMID: 23202486
Weber L, Kahlert J, Bohling L, Brockhinke A, Stammler HG, Neumann B, Harder RA, Low PJ, Fox MA., Dalton Trans 42(6), 2013
PMID: 23202486
C,C'-bis(benzodiazaborolyl)dicarba-closo-dodecaboranes: synthesis, structures, photophysics and electrochemistry.
Weber L, Kahlert J, Brockhinke R, Bohling L, Halama J, Brockhinke A, Stammler HG, Neumann B, Nervi C, Harder RA, Fox MA., Dalton Trans 42(30), 2013
PMID: 23793134
Weber L, Kahlert J, Brockhinke R, Bohling L, Halama J, Brockhinke A, Stammler HG, Neumann B, Nervi C, Harder RA, Fox MA., Dalton Trans 42(30), 2013
PMID: 23793134
Wee, Angew. Chem. 125(), 2013
Carborane-based optoelectronically active organic molecules: wide band gap host materials for blue phosphorescence.
Wee KR, Cho YJ, Jeong S, Kwon S, Lee JD, Suh IH, Kang SO., J. Am. Chem. Soc. 134(43), 2012
PMID: 23057809
Wee KR, Cho YJ, Jeong S, Kwon S, Lee JD, Suh IH, Kang SO., J. Am. Chem. Soc. 134(43), 2012
PMID: 23057809
o-Carborane-assisted Lewis acidity enhancement of triarylboranes.
Huh JO, Kim H, Lee KM, Lee YS, Do Y, Lee MH., Chem. Commun. (Camb.) 46(7), 2009
PMID: 20126739
Huh JO, Kim H, Lee KM, Lee YS, Do Y, Lee MH., Chem. Commun. (Camb.) 46(7), 2009
PMID: 20126739
Dual sensing of fluoride ions by the o-carborane-triarylborane dyad.
Song KC, Kim H, Lee KM, Lee YS, Do Y, Lee MH., Dalton Trans 42(7), 2012
PMID: 23207627
Song KC, Kim H, Lee KM, Lee YS, Do Y, Lee MH., Dalton Trans 42(7), 2012
PMID: 23207627
Synthesis, crystal structures, linear and nonlinear optical properties, and theoretical studies of (p-R-phenyl)-, (p-R-phenylethynyl)-, and (E)-[2-(p-R-phenyl)ethenyl]dimesitylboranes and related compounds.
Yuan Z, Entwistle CD, Collings JC, Albesa-Jove D, Batsanov AS, Howard JA, Taylor NJ, Kaiser HM, Kaufmann DE, Poon SY, Wong WY, Jardin C, Fathallah S, Boucekkine A, Halet JF, Marder TB., Chemistry 12(10), 2006
PMID: 16429474
Yuan Z, Entwistle CD, Collings JC, Albesa-Jove D, Batsanov AS, Howard JA, Taylor NJ, Kaiser HM, Kaufmann DE, Poon SY, Wong WY, Jardin C, Fathallah S, Boucekkine A, Halet JF, Marder TB., Chemistry 12(10), 2006
PMID: 16429474
Boone, Inorg. Chem. 4(), 1965
Voloshin, Russ. Chem. Bull. 56(), 2007
Erdyakov, Inorg. Chem. Commun. 12(), 2009
Facile and efficient synthesis of C-hydroxycarboranes and C,C'-dihydroxycarboranes.
Ohta K, Goto T, Yamazaki H, Pichierri F, Endo Y., Inorg Chem 46(10), 2007
PMID: 17429958
Ohta K, Goto T, Yamazaki H, Pichierri F, Endo Y., Inorg Chem 46(10), 2007
PMID: 17429958
Brown, J. Mater. Chem. 2(), 1992
Zi, Organometallics 21(), 2002
Zi, Organometallics 21(), 2002
Nie, Z. Anorg. Allg. Chem. 639(), 2013
Nie, J. Organomet. Chem. 747(), 2013
Brown, J. Organomet. Chem. 193(), 1980
Diverse reactivity of dialkylaluminum dimesitylboryloxides [(mu-Mes2BO)AlR2]2. Synthetic and structural study.
Anulewicz-Ostrowska R, Lulinski S, Serwatowski J, Suwinska K., Inorg Chem 39(25), 2000
PMID: 11151377
Anulewicz-Ostrowska R, Lulinski S, Serwatowski J, Suwinska K., Inorg Chem 39(25), 2000
PMID: 11151377
Brown, J. Am. Chem. Soc. 79(), 1957
Tomita, Inorg. Chem. 30(), 1991
Fox, Polyhedron 16(), 1997
Facile and mild deboronation of o-carboranes using cesium fluoride.
Yoo J, Hwang JW, Do Y., Inorg Chem 40(3), 2001
PMID: 11209620
Yoo J, Hwang JW, Do Y., Inorg Chem 40(3), 2001
PMID: 11209620
Eisch, J. Am. Chem. Soc. 112(), 1990
Chisholm, Inorg. Chim. Acta 213(), 1993
Busby, Inorg. Chem. 21(), 1982
Lewis, Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 49(), 1993
McGrath, Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 51(), 1995
Alekseyeva, Appl. Organomet. Chem. 17(), 2003
Solvatochromism and fluoride sensing of thienyl-containing benzodiazaboroles.
Schwedler S, Eickhoff D, Brockhinke R, Cherian D, Weber L, Brockhinke A., Phys Chem Chem Phys 13(20), 2011
PMID: 21475763
Schwedler S, Eickhoff D, Brockhinke R, Cherian D, Weber L, Brockhinke A., Phys Chem Chem Phys 13(20), 2011
PMID: 21475763
Lippert, Z. Naturforsch., A: Phys. Sci. 10(), 1955
Lippert, Z. Elektrochem. 61(), 1957
Mataga, Bull. Chem. Soc. Jpn. 28(), 1955
Mataga, Bull. Chem. Soc. Jpn. 29(), 1956
Synthesis and spectral properties of a hydrophobic fluorescent probe: 6-propionyl-2-(dimethylamino)naphthalene.
Weber G, Farris FJ., Biochemistry 18(14), 1979
PMID: 465454
Weber G, Farris FJ., Biochemistry 18(14), 1979
PMID: 465454
The effect of solvent polarity on the photophysical properties of 4-cyano-(4'-methylthio)diphenylacetylene: a prototypic donor-acceptor system.
Benniston AC, Harriman A, Rostron JP., Phys Chem Chem Phys 7(16), 2005
PMID: 16186908
Benniston AC, Harriman A, Rostron JP., Phys Chem Chem Phys 7(16), 2005
PMID: 16186908
Experimental and theoretical studies on organic D-π-A systems containing three-coordinate boron moieties as both π-donor and π-acceptor.
Weber L, Eickhoff D, Marder TB, Fox MA, Low PJ, Dwyer AD, Tozer DJ, Schwedler S, Brockhinke A, Stammler HG, Neumann B., Chemistry 18(5), 2011
PMID: 22213064
Weber L, Eickhoff D, Marder TB, Fox MA, Low PJ, Dwyer AD, Tozer DJ, Schwedler S, Brockhinke A, Stammler HG, Neumann B., Chemistry 18(5), 2011
PMID: 22213064
Yarosh, Elektrokhimiya 29(), 1993
Yarosh, Elektrokhimiya 30(), 1994
Harder, Tetrahedron 70(), 2014
Carborane radical anions: spectroscopic and electronic properties of a carborane radical anion with a 2n + 3 skeletal electron count.
Fox MA, Nervi C, Crivello A, Low PJ., Chem. Commun. (Camb.) (23), 2007
PMID: 17844750
Fox MA, Nervi C, Crivello A, Low PJ., Chem. Commun. (Camb.) (23), 2007
PMID: 17844750
Spectroscopic, structural, computational and (spectro)electrochemical studies of icosahedral carboranes bearing fluorinated aryl groups.
Tricas H, Colon M, Ellis D, Macgregor SA, McKay D, Rosair GM, Welch AJ, Glukhov IV, Rossi F, Laschi F, Zanello P., Dalton Trans 40(16), 2011
PMID: 21390395
Tricas H, Colon M, Ellis D, Macgregor SA, McKay D, Rosair GM, Welch AJ, Glukhov IV, Rossi F, Laschi F, Zanello P., Dalton Trans 40(16), 2011
PMID: 21390395
Fox, J. Solid State Electrochem. 13(), 2009
A three-dimensional π-electron acceptor, tri-phenyl-o-carborane, bearing a rigid conformation with end-on phenyl units.
Jin GF, Hwang JH, Lee JD, Wee KR, Suh IH, Kang SO., Chem. Commun. (Camb.) 49(82), 2013
PMID: 24002167
Jin GF, Hwang JH, Lee JD, Wee KR, Suh IH, Kang SO., Chem. Commun. (Camb.) 49(82), 2013
PMID: 24002167
Kahlert, Angew. Chem. 126(), 2014
o-Carborane as an electron-transfer mediator in electrocatalytic reduction.
Hosoi K, Inagi S, Kubo T, Fuchigami T., Chem. Commun. (Camb.) 47(30), 2011
PMID: 21720623
Hosoi K, Inagi S, Kubo T, Fuchigami T., Chem. Commun. (Camb.) 47(30), 2011
PMID: 21720623
Lebedev, Organomet. Chem. USSR 4(), 1991
Lebedev, Organomet. Chem. USSR 4(), 1991
Bukhtiarov, Dokl. Acad. Sci. USSR (), 1989
Fox, 2007
Chui, Organometallics 19(), 2000
Zi, Organometallics 20(), 2001
Zi, Chem. Commun. (), 2001
Zi, Organometallics 21(), 2002
Cheung, Organometallics 23(), 2004
Shen, Organometallics 25(), 2006
Synthesis, structure, reactivity, and thermal isomerization of boron-substituted 13-vertex cobaltacarboranes (eta5-Cp)Co(eta6-R2C2B10Me8H2) (R = H, Et).
Deng L, Chan HS, Xie Z., Inorg Chem 46(7), 2007
PMID: 17343377
Deng L, Chan HS, Xie Z., Inorg Chem 46(7), 2007
PMID: 17343377
Deng, Organometallics 24(), 2005
Venable, J. Am. Chem. Soc. 106(), 1984
Spencer, Organometallics 6(), 1987
Hosmane, Organometallics 17(), 1998
A simple entry into nido-C2B10 clusters: HCl promoted cleavage of the C-C bond in ortho-carboranyl diphosphines.
Charmant JP, Haddow MF, Mistry R, Norman NC, Orpen AG, Pringle PG., Dalton Trans (11), 2008
PMID: 18322616
Charmant JP, Haddow MF, Mistry R, Norman NC, Orpen AG, Pringle PG., Dalton Trans (11), 2008
PMID: 18322616
Bühl, J. Am. Chem. Soc. 114(), 1992
Schleyer, J. Chem. Soc., Chem. Commun. (), 1993
Deboronation and deprotonation of ortho-carborane with N-heterocyclic carbenes.
Willans CE, Kilner CA, Fox MA., Chemistry 16(35), 2010
PMID: 20680947
Willans CE, Kilner CA, Fox MA., Chemistry 16(35), 2010
PMID: 20680947
Unexpectedly facile isomerisation of [7,10-Ph2-7,10-nido-C2B10H10]2- to [7,9-Ph2-7,9-nido-C2B10H10]2-.
Zlatogorsky S, Ellis D, Rosair GM, Welch AJ., Chem. Commun. (Camb.) (21), 2007
PMID: 17520128
Zlatogorsky S, Ellis D, Rosair GM, Welch AJ., Chem. Commun. (Camb.) (21), 2007
PMID: 17520128
Supercarborane radical anions with 2n + 3 electron counts: a combined experimental and theoretical study.
Zhang J, Fu X, Lin Z, Xie Z., Inorg Chem 54(4), 2015
PMID: 25622110
Zhang J, Fu X, Lin Z, Xie Z., Inorg Chem 54(4), 2015
PMID: 25622110
Zakharkin, Bull. Acad. Sci. USSR Div. Chem. Sci. (), 1966
Zakharkin, Bull. Acad. Sci. USSR Div. Chem. Sci. (), 1967
Zakharkin, Pure Appl. Chem. 29(), 1972
Zakharkin, Bull. Acad. Sci. USSR Div. Chem. Sci. (), 1976
Pelter, 1988
Zakharkin, J. Organomet. Chem. 6(), 1966
Alekseyeva, Dalton Trans. (), 2003
de, Adv. Mater. 9(), 1997
Krejcik, J. Electroanal. Chem. 317(), 1991
A short history of SHELX.
Sheldrick GM., Acta Crystallogr., A, Found. Crystallogr. 64(Pt 1), 2007
PMID: 18156677
Sheldrick GM., Acta Crystallogr., A, Found. Crystallogr. 64(Pt 1), 2007
PMID: 18156677
Becke, J. Chem. Phys. 98(), 1993
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density.
Lee C, Yang W, Parr RG., Phys. Rev., B Condens. Matter 37(2), 1988
PMID: 9944570
Lee C, Yang W, Parr RG., Phys. Rev., B Condens. Matter 37(2), 1988
PMID: 9944570
Petersson, J. Chem. Phys. 94(), 1991
Petersson, J. Chem. Phys. 89(), 1988
Runge, Phys. Rev. Lett. 52(), 1984
cclib: a library for package-independent computational chemistry algorithms.
O'Boyle NM, Tenderholt AL, Langner KM., J Comput Chem 29(5), 2008
PMID: 17849392
O'Boyle NM, Tenderholt AL, Langner KM., J Comput Chem 29(5), 2008
PMID: 17849392
Ditchfield, Mol. Phys. 27(), 1974
Rohling, Chem. Phys. 87(), 1984
Wolinski, J. Am. Chem. Soc. 112(), 1990
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