Insertion of the P=C-Functionality in (Pentamethylcyclopentadienyl)(dicarbonyl) [1,3,3-tris(trimethylsilyl)-η1-1,2-diphosphaallyl]iron into the CH-Bond of a Methyl Group of the C5Me5 Ring: Formation of a Chelating (η1-P,η5-C5)-3-Tetramethylcyclopentadienyl-1,2-diphosphapropanido Ligand

Weber L, Kirchhoff R, Boese R (1992)
Journal of the Chemical Society, Chemical Communications (17): 1182-1184.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Autor*in
Weber, LotharUniBi; Kirchhoff, Ralf; Boese, Roland
Abstract / Bemerkung
Heating a methylcyclohexane solution of [(eta-5-C5Me5)(CO)2Fe-P(SiMe3)-P=C(SiMe3)2] 1 gives rise to the insertion of the P=C-moiety into the CH-bond of a ring methyl group forming the chelate complex {eta-5-C5Me4CH2P[CH(SiMe3)2]P(SiMe3)Fe(CO)2} 5 which is trapped by (Z-cyclooctene)Cr(CO)5 and fully characterized as its Cr(CO)5 adduct 6.
Erscheinungsjahr
1992
Zeitschriftentitel
Journal of the Chemical Society, Chemical Communications
Ausgabe
17
Seite(n)
1182-1184
ISSN
0022-4936
Page URI
https://pub.uni-bielefeld.de/record/2727035

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Weber L, Kirchhoff R, Boese R. Insertion of the P=C-Functionality in (Pentamethylcyclopentadienyl)(dicarbonyl) [1,3,3-tris(trimethylsilyl)-η1-1,2-diphosphaallyl]iron into the CH-Bond of a Methyl Group of the C5Me5 Ring: Formation of a Chelating (η1-P,η5-C5)-3-Tetramethylcyclopentadienyl-1,2-diphosphapropanido Ligand. Journal of the Chemical Society, Chemical Communications. 1992;(17):1182-1184.
Weber, L., Kirchhoff, R., & Boese, R. (1992). Insertion of the P=C-Functionality in (Pentamethylcyclopentadienyl)(dicarbonyl) [1,3,3-tris(trimethylsilyl)-η1-1,2-diphosphaallyl]iron into the CH-Bond of a Methyl Group of the C5Me5 Ring: Formation of a Chelating (η1-P,η5-C5)-3-Tetramethylcyclopentadienyl-1,2-diphosphapropanido Ligand. Journal of the Chemical Society, Chemical Communications(17), 1182-1184. doi:10.1039/c39920001182
Weber, L., Kirchhoff, R., and Boese, R. (1992). Insertion of the P=C-Functionality in (Pentamethylcyclopentadienyl)(dicarbonyl) [1,3,3-tris(trimethylsilyl)-η1-1,2-diphosphaallyl]iron into the CH-Bond of a Methyl Group of the C5Me5 Ring: Formation of a Chelating (η1-P,η5-C5)-3-Tetramethylcyclopentadienyl-1,2-diphosphapropanido Ligand. Journal of the Chemical Society, Chemical Communications, 1182-1184.
Weber, L., Kirchhoff, R., & Boese, R., 1992. Insertion of the P=C-Functionality in (Pentamethylcyclopentadienyl)(dicarbonyl) [1,3,3-tris(trimethylsilyl)-η1-1,2-diphosphaallyl]iron into the CH-Bond of a Methyl Group of the C5Me5 Ring: Formation of a Chelating (η1-P,η5-C5)-3-Tetramethylcyclopentadienyl-1,2-diphosphapropanido Ligand. Journal of the Chemical Society, Chemical Communications, (17), p 1182-1184.
L. Weber, R. Kirchhoff, and R. Boese, “Insertion of the P=C-Functionality in (Pentamethylcyclopentadienyl)(dicarbonyl) [1,3,3-tris(trimethylsilyl)-η1-1,2-diphosphaallyl]iron into the CH-Bond of a Methyl Group of the C5Me5 Ring: Formation of a Chelating (η1-P,η5-C5)-3-Tetramethylcyclopentadienyl-1,2-diphosphapropanido Ligand”, Journal of the Chemical Society, Chemical Communications, 1992, pp. 1182-1184.
Weber, L., Kirchhoff, R., Boese, R.: Insertion of the P=C-Functionality in (Pentamethylcyclopentadienyl)(dicarbonyl) [1,3,3-tris(trimethylsilyl)-η1-1,2-diphosphaallyl]iron into the CH-Bond of a Methyl Group of the C5Me5 Ring: Formation of a Chelating (η1-P,η5-C5)-3-Tetramethylcyclopentadienyl-1,2-diphosphapropanido Ligand. Journal of the Chemical Society, Chemical Communications. 1182-1184 (1992).
Weber, Lothar, Kirchhoff, Ralf, and Boese, Roland. “Insertion of the P=C-Functionality in (Pentamethylcyclopentadienyl)(dicarbonyl) [1,3,3-tris(trimethylsilyl)-η1-1,2-diphosphaallyl]iron into the CH-Bond of a Methyl Group of the C5Me5 Ring: Formation of a Chelating (η1-P,η5-C5)-3-Tetramethylcyclopentadienyl-1,2-diphosphapropanido Ligand”. Journal of the Chemical Society, Chemical Communications 17 (1992): 1182-1184.

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