Preparation of Freestanding Conjugated Microporous Polymer Nanomembranes for Gas Separation

Lindemann P, Tsotsalas M, Shishatskiy S, Abetz V, Krolla-Sidenstein P, Azucena C, Monnereau L, Beyer A, Gölzhäuser A, Mugnaini V, Gliemann H, et al. (2014)
Chemistry of Materials 26(24): 7189-7193.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
Download
Es wurden keine Dateien hochgeladen. Nur Publikationsnachweis!
Autor*in
Lindemann, Peter; Tsotsalas, Manuel; Shishatskiy, Sergey; Abetz, Volker; Krolla-Sidenstein, Peter; Azucena, Carlos; Monnereau, Laure; Beyer, AndréUniBi ; Gölzhäuser, ArminUniBi ; Mugnaini, Veronica; Gliemann, Hartmut; Braese, Stefan
Alle
Abstract / Bemerkung
Conjugated microporous polymers (CMPs) have attracted much interest due to their intrinsic porosity, outstanding stability, and high variability. However, the processing of these materials for membrane application has been limited due to their insoluble nature when synthesized as bulk material. Here we report the synthesis of freestanding CMP-nanomembranes via layer-by-layer growth of a click based conjugated microporous polymer on a sacrificial substrate. After dissolution of the substrate the CMP-nanomembrane can be transferred to porous substrates and continuously cover holes of up to 50 mu m diameter. The CMP-nanomembranes appear defect-free as inferred from high selectivity values obtained from gas permeation experiments and from electrochemical investigation in the presence of ferrocene. The presented synthesis method represents a versatile strategy to incorporate CMP materials in functional devices for membrane separation, catalysis, or organic electronics.
Erscheinungsjahr
2014
Zeitschriftentitel
Chemistry of Materials
Band
26
Ausgabe
24
Seite(n)
7189-7193
ISSN
0897-4756
eISSN
1520-5002
Page URI
https://pub.uni-bielefeld.de/record/2719072

Zitieren

Lindemann P, Tsotsalas M, Shishatskiy S, et al. Preparation of Freestanding Conjugated Microporous Polymer Nanomembranes for Gas Separation. Chemistry of Materials. 2014;26(24):7189-7193.
Lindemann, P., Tsotsalas, M., Shishatskiy, S., Abetz, V., Krolla-Sidenstein, P., Azucena, C., Monnereau, L., et al. (2014). Preparation of Freestanding Conjugated Microporous Polymer Nanomembranes for Gas Separation. Chemistry of Materials, 26(24), 7189-7193. doi:10.1021/cm503924h
Lindemann, P., Tsotsalas, M., Shishatskiy, S., Abetz, V., Krolla-Sidenstein, P., Azucena, C., Monnereau, L., Beyer, A., Gölzhäuser, A., Mugnaini, V., et al. (2014). Preparation of Freestanding Conjugated Microporous Polymer Nanomembranes for Gas Separation. Chemistry of Materials 26, 7189-7193.
Lindemann, P., et al., 2014. Preparation of Freestanding Conjugated Microporous Polymer Nanomembranes for Gas Separation. Chemistry of Materials, 26(24), p 7189-7193.
P. Lindemann, et al., “Preparation of Freestanding Conjugated Microporous Polymer Nanomembranes for Gas Separation”, Chemistry of Materials, vol. 26, 2014, pp. 7189-7193.
Lindemann, P., Tsotsalas, M., Shishatskiy, S., Abetz, V., Krolla-Sidenstein, P., Azucena, C., Monnereau, L., Beyer, A., Gölzhäuser, A., Mugnaini, V., Gliemann, H., Braese, S., Woell, C.: Preparation of Freestanding Conjugated Microporous Polymer Nanomembranes for Gas Separation. Chemistry of Materials. 26, 7189-7193 (2014).
Lindemann, Peter, Tsotsalas, Manuel, Shishatskiy, Sergey, Abetz, Volker, Krolla-Sidenstein, Peter, Azucena, Carlos, Monnereau, Laure, Beyer, André, Gölzhäuser, Armin, Mugnaini, Veronica, Gliemann, Hartmut, Braese, Stefan, and Woell, Christof. “Preparation of Freestanding Conjugated Microporous Polymer Nanomembranes for Gas Separation”. Chemistry of Materials 26.24 (2014): 7189-7193.