Iron(III)-porphyrin Complex FeTSPP: A Versatile Water-soluble Catalyst for Oxidations in Organic Syntheses, Biorenewables Degradation and Environmental Applications

Böhm P, Gröger H (2015)
ChemCatChem 7(1): 22-28.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Abstract / Bemerkung
The metal complex FeTSPP (5,10,15,20-tetrakis-(4-sulfonato-phenyl)-porphyrin-iron(III) chloride; also denoted as FeTPPS), which consists of an iron(III) center ion (an environmentally advantageous metal) and a highly water-soluble heme ligand, represents an exciting and already broadly applied catalyst in the area of "green" oxidation reactions in aqueous media. This commercially available iron catalyst shows a high oxidation potential for many substrates. Further advantages are its high stability and ability not to aggregate in aqueous solution. This Minireview gives an overview of the structural properties of FeTSPP in aqueous solution and selected applications as an oxidation catalyst for organic syntheses, biorenewable degradations, and environmental applications.
Stichworte
porphyrins; oxidations; iron; homogeneous catalysis; supported catalysis
Erscheinungsjahr
2015
Zeitschriftentitel
ChemCatChem
Band
7
Ausgabe
1
Seite(n)
22-28
ISSN
1867-3880
Page URI
https://pub.uni-bielefeld.de/record/2719049

Zitieren

Böhm P, Gröger H. Iron(III)-porphyrin Complex FeTSPP: A Versatile Water-soluble Catalyst for Oxidations in Organic Syntheses, Biorenewables Degradation and Environmental Applications. ChemCatChem. 2015;7(1):22-28.
Böhm, P., & Gröger, H. (2015). Iron(III)-porphyrin Complex FeTSPP: A Versatile Water-soluble Catalyst for Oxidations in Organic Syntheses, Biorenewables Degradation and Environmental Applications. ChemCatChem, 7(1), 22-28. doi:10.1002/cctc.201402331
Böhm, P., and Gröger, H. (2015). Iron(III)-porphyrin Complex FeTSPP: A Versatile Water-soluble Catalyst for Oxidations in Organic Syntheses, Biorenewables Degradation and Environmental Applications. ChemCatChem 7, 22-28.
Böhm, P., & Gröger, H., 2015. Iron(III)-porphyrin Complex FeTSPP: A Versatile Water-soluble Catalyst for Oxidations in Organic Syntheses, Biorenewables Degradation and Environmental Applications. ChemCatChem, 7(1), p 22-28.
P. Böhm and H. Gröger, “Iron(III)-porphyrin Complex FeTSPP: A Versatile Water-soluble Catalyst for Oxidations in Organic Syntheses, Biorenewables Degradation and Environmental Applications”, ChemCatChem, vol. 7, 2015, pp. 22-28.
Böhm, P., Gröger, H.: Iron(III)-porphyrin Complex FeTSPP: A Versatile Water-soluble Catalyst for Oxidations in Organic Syntheses, Biorenewables Degradation and Environmental Applications. ChemCatChem. 7, 22-28 (2015).
Böhm, Philipp, and Gröger, Harald. “Iron(III)-porphyrin Complex FeTSPP: A Versatile Water-soluble Catalyst for Oxidations in Organic Syntheses, Biorenewables Degradation and Environmental Applications”. ChemCatChem 7.1 (2015): 22-28.