Boron-centered soft ligands based on tetrazole units and their complexes with sodium, potassium and bismuth ions
Imran M, Mix A, Neumann B, Stammler H-G, Monkowius U, Bleckenwegner P, Mitzel NW (2014)
Dalton Transactions 43(39): 14737-14748.
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Autor*in
Imran, MuhammadUniBi;
Mix, AndreasUniBi;
Neumann, BeateUniBi;
Stammler, Hans-GeorgUniBi;
Monkowius, Uwe;
Bleckenwegner, Petra;
Mitzel, Norbert W.UniBi
Abstract / Bemerkung
The syntheses of Na(Ttt(Me)) (1), K(Ttt(Me)) (2), K(Btt(Me)) (3), and Na(Btt(Ph)) (4) are reported, where (Ttt(Me))(-) and (Btt(R))(-) (R = Me, Ph) are tri- and di-substituted boron-centered soft ligands; they were produced by the reaction of NaBH4 and KBH4 with the corresponding tetrazole heterocycles: 1-methyl-5-thiotetrazole ((LH)-H-1) and 1-phenyl-5-thiotetrazole ((LH)-H-2). The syntheses of Na(Ttt(Me)) (1) and K(Ttt(Me)) (2) were carried out following Trofimenko's protocol. The anion (Ttt(Me))(-) is a typical Janus scorpionate ligand. Na(Ttt(Me)) (1) and Na(Btt(Ph)) (4) were reacted with Bi(CH3COO)(3) to observe the coordination pattern of these ligands towards bismuth ions. These reactions afforded the complexes [Bi(Ttt(Me))(2)(CH3COO)] (5), [Bi(L-2)(2)](2) (6a, 6b) and [Bi(L-2)(3)] (7). The products were characterized by NMR spectroscopy, elemental analyses and mass spectrometry. Solid state structures were determined by X-ray diffraction of single crystals of 1, 2, 3, 4, 5, 6a, 6b and 7. M(Ttt(Me)) (M = Na (1), K (2)) and K(Btt(Me)) (3) exhibit sheet-like structures. The alkali metal complexes 1-4 dissociate in solution as observed in H-1, C-13 NMR and H-1 diffusion NMR experiments. Negative mode ESI-MS data also indicate the presence of monomers. Both the sodium salts of (Ttt(Me))(-) and (Btt(Ph))(-) as well as the Bi complexes 5 and 7 were investigated by absorption and emission spectroscopy.
Erscheinungsjahr
2014
Zeitschriftentitel
Dalton Transactions
Band
43
Ausgabe
39
Seite(n)
14737-14748
ISSN
1477-9226
Page URI
https://pub.uni-bielefeld.de/record/2703326
Zitieren
Imran M, Mix A, Neumann B, et al. Boron-centered soft ligands based on tetrazole units and their complexes with sodium, potassium and bismuth ions. Dalton Transactions. 2014;43(39):14737-14748.
Imran, M., Mix, A., Neumann, B., Stammler, H. - G., Monkowius, U., Bleckenwegner, P., & Mitzel, N. W. (2014). Boron-centered soft ligands based on tetrazole units and their complexes with sodium, potassium and bismuth ions. Dalton Transactions, 43(39), 14737-14748. doi:10.1039/c4dt01931h
Imran, Muhammad, Mix, Andreas, Neumann, Beate, Stammler, Hans-Georg, Monkowius, Uwe, Bleckenwegner, Petra, and Mitzel, Norbert W. 2014. “Boron-centered soft ligands based on tetrazole units and their complexes with sodium, potassium and bismuth ions”. Dalton Transactions 43 (39): 14737-14748.
Imran, M., Mix, A., Neumann, B., Stammler, H. - G., Monkowius, U., Bleckenwegner, P., and Mitzel, N. W. (2014). Boron-centered soft ligands based on tetrazole units and their complexes with sodium, potassium and bismuth ions. Dalton Transactions 43, 14737-14748.
Imran, M., et al., 2014. Boron-centered soft ligands based on tetrazole units and their complexes with sodium, potassium and bismuth ions. Dalton Transactions, 43(39), p 14737-14748.
M. Imran, et al., “Boron-centered soft ligands based on tetrazole units and their complexes with sodium, potassium and bismuth ions”, Dalton Transactions, vol. 43, 2014, pp. 14737-14748.
Imran, M., Mix, A., Neumann, B., Stammler, H.-G., Monkowius, U., Bleckenwegner, P., Mitzel, N.W.: Boron-centered soft ligands based on tetrazole units and their complexes with sodium, potassium and bismuth ions. Dalton Transactions. 43, 14737-14748 (2014).
Imran, Muhammad, Mix, Andreas, Neumann, Beate, Stammler, Hans-Georg, Monkowius, Uwe, Bleckenwegner, Petra, and Mitzel, Norbert W. “Boron-centered soft ligands based on tetrazole units and their complexes with sodium, potassium and bismuth ions”. Dalton Transactions 43.39 (2014): 14737-14748.
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1 Zitation in Europe PMC
Daten bereitgestellt von Europe PubMed Central.
Paddlewheel 1,2,4-diazaphospholide dibismuthanes with very short bismuth-bismuth single bonds.
Zhao M, Wang L, Li P, Zhang X, Yang Y, Zheng W., Chem Commun (Camb) 51(90), 2015
PMID: 26399734
Zhao M, Wang L, Li P, Zhang X, Yang Y, Zheng W., Chem Commun (Camb) 51(90), 2015
PMID: 26399734
37 References
Daten bereitgestellt von Europe PubMed Central.
Garner, J. Chem. Soc., Chem. Commun. (), 1996
Kimblin, Chem. Commun. (), 1999
White, J. Chem. Soc., Dalton Trans. (), 2002
Sulfur-rich zinc chemistry: new tris(thioimidazolyl)hydroborate ligands and their zinc complex chemistry related to the structure and function of alcohol dehydrogenase.
Tesmer M, Shu M, Vahrenkamp H., Inorg Chem 40(16), 2001
PMID: 11466063
Tesmer M, Shu M, Vahrenkamp H., Inorg Chem 40(16), 2001
PMID: 11466063
Barriers to racemization in C3-symmetric complexes containing the hydrotris(2-mercapto-1-ethylimidazolyl)borate (Tm(Et)) ligand.
Bailey PJ, Dawson A, McCormack C, Moggach SA, Oswald ID, Parsons S, Rankin DW, Turner A., Inorg Chem 44(24), 2005
PMID: 16296844
Bailey PJ, Dawson A, McCormack C, Moggach SA, Oswald ID, Parsons S, Rankin DW, Turner A., Inorg Chem 44(24), 2005
PMID: 16296844
Janus scorpionates: supramolecular tectons for the directed assembly of hard-soft alkali metallopolymer chains.
Silva RM, Gwengo C, Lindeman SV, Smith MD, Gardinier JR., Inorg Chem 45(26), 2006
PMID: 17173459
Silva RM, Gwengo C, Lindeman SV, Smith MD, Gardinier JR., Inorg Chem 45(26), 2006
PMID: 17173459
A second-generation janus scorpionate ligand: controlling coordination modes in iron(II) complexes by steric modulation.
Silva RM, Gwengo C, Lindeman SV, Smith MD, Long GJ, Grandjean F, Gardinier JR., Inorg Chem 47(16), 2008
PMID: 18646840
Silva RM, Gwengo C, Lindeman SV, Smith MD, Long GJ, Grandjean F, Gardinier JR., Inorg Chem 47(16), 2008
PMID: 18646840
Hydridotris(thioxotriazolyl)borate (Tt), an ambidentate (N(3)/S(3)) tripodal ligand. X-ray crystal structures of sodium, bismuth(III), tin(IV), and manganese(I) complexes.
Bailey PJ, Lanfranchi M, Marchio L, Parsons S., Inorg Chem 40(19), 2001
PMID: 11531454
Bailey PJ, Lanfranchi M, Marchio L, Parsons S., Inorg Chem 40(19), 2001
PMID: 11531454
Synthesis, structure, and electrochemical properties of copper(I) complexes with S/N homoscorpionate and heteroscorpionate ligands.
Cammi R, Gennari M, Giannetto M, Lanfranchi M, Marchio L, Mori G, Paiola C, Pellinghelli MA., Inorg Chem 44(12), 2005
PMID: 15934764
Cammi R, Gennari M, Giannetto M, Lanfranchi M, Marchio L, Mori G, Paiola C, Pellinghelli MA., Inorg Chem 44(12), 2005
PMID: 15934764
Trofimenko, J. Am. Chem. Soc. 88(), 1966
Trofimenko, Chem. Rev. 93(), 1993
Trofimenko, 1999
Trofimenko, Polyhedron 23(), 2004
Pettinari, 2008
Modeling the Catalytic Site of Liver Alcohol Dehydrogenase: Synthesis and Structural Characterization of a [Bis(thioimidazolyl)(pyrazolyl)hydroborato]zinc Complex, [HB(tim(Me))(2)pz]ZnI.
Kimblin C, Hascall T, Parkin G., Inorg Chem 36(25), 1997
PMID: 11670182
Kimblin C, Hascall T, Parkin G., Inorg Chem 36(25), 1997
PMID: 11670182
Kimblin, J. Chem. Soc., Dalton Trans. (), 2000
Dyson, Dalton Trans. (), 2009
Reactivity of [Re[kappa(3)-H(mu-H)B(tim(Me))(2)](CO)(3)] (tim(Me) = 2-mercapto-1-methylimidazolyl) toward neutral substrates.
Garcia R, Domingos A, Paulo A, Santos I, Alberto R., Inorg Chem 41(9), 2002
PMID: 11978108
Garcia R, Domingos A, Paulo A, Santos I, Alberto R., Inorg Chem 41(9), 2002
PMID: 11978108
Garcia, J. Organomet. Chem. 632(), 2001
Wang, Polyhedron 24(), 2005
Novel pyridazine based scorpionate ligands in cobalt and nickel boratrane compounds.
Nuss G, Saischek G, Harum BN, Volpe M, Gatterer K, Belaj F, Mosch-Zanetti NC., Inorg Chem 50(5), 2011
PMID: 21250681
Nuss G, Saischek G, Harum BN, Volpe M, Gatterer K, Belaj F, Mosch-Zanetti NC., Inorg Chem 50(5), 2011
PMID: 21250681
Spicer, Eur. J. Inorg. Chem. (), 2009
Garner, Dalton Trans. (), 2003
Jesson, J. Am. Chem. Soc. 89(), 1967
Coinage metal complexes of a boron-substituted soft scorpionate ligand.
Dodds CA, Garner M, Reglinski J, Spicer MD., Inorg Chem 45(6), 2006
PMID: 16529498
Dodds CA, Garner M, Reglinski J, Spicer MD., Inorg Chem 45(6), 2006
PMID: 16529498
Nuss, Eur. J. Inorg. Chem. (), 2012
The versatile behaviour of a novel Janus scorpionate ligand towards sodium, potassium and bismuth(III) ions.
Imran M, Neumann B, Stammler HG, Monkowius U, Ertl M, Mitzel NW., Dalton Trans 42(44), 2013
PMID: 24071804
Imran M, Neumann B, Stammler HG, Monkowius U, Ertl M, Mitzel NW., Dalton Trans 42(44), 2013
PMID: 24071804
Borate-based ligands with two soft heterocycle/thione groups and their sodium and bismuth complexes.
Imran M, Neumann B, Stammler HG, Monkowius U, Ertl M, Mitzel NW., Dalton Trans 43(3), 2013
PMID: 24190102
Imran M, Neumann B, Stammler HG, Monkowius U, Ertl M, Mitzel NW., Dalton Trans 43(3), 2013
PMID: 24190102
Versatile ligand behavior of hydrotris(4-ethyl-3-methyl-5-thioxo-1,2,4-triazolyl)borate. Syntheses and crystal structures of Cu(I) and Bi(III) complexes.
Careri M, Elviri L, Lanfranchi M, Marchio L, Mora C, Pellinghelli MA., Inorg Chem 42(6), 2003
PMID: 12639148
Careri M, Elviri L, Lanfranchi M, Marchio L, Mora C, Pellinghelli MA., Inorg Chem 42(6), 2003
PMID: 12639148
Lanfranchi, Inorg. Chim. Acta 357(), 2004
Shu, Appl. Organomet. Chem. 19(), 2005
Bensch, Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 43(), 1987
Frank, Angew. Chem., Int. Ed. Engl. 110(), 1998
Calderazzo, J. Chem. Soc., Dalton Trans. (), 1984
Cucka, Acta Crystallogr. 15(), 1962
Simon, J. Organomet. Chem. 740(), 2013
Sheldrick, Acta Crystallogr., Sect. A: Fundam. Crystallogr. 64(), 2008
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