The Pentamethylcyclopentadienylsilicon(II) Cation: Synthesis, Characterization, and Reactivity

Jutzi P (2014)
Chemistry - A European Journal 20(30): 9192-9207.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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DOI
Autor*in
Jutzi, PeterUniBi
Einrichtung
Fakultät für Chemie > Anorganische Chemie und Strukturchemie
Abstract / Bemerkung
In the flourishing chemistry of divalent silicon, pi-complex formation between silicon and the pentamethylcyclopentadienyl (Cp*) group is one of the successful strategies for thermodynamic and/or kinetic stabilization. Here, the diverse reactivity of the [Cp*Si](+) ion is described. Its chemistry is characterized by the addition of anionic and neutral nucleophiles and by the easy hapticity change and the leaving-group character of the Cp* group. Several novel sandwich and half-sandwich pi-complexes of divalent silicon were synthesized, and a novel access to the class of cyclotrisilenes was found. A reversible adduct formation is the basis for the catalytic activity of the [Cp*Si](+) ion in the specific oligoether degradation. Homo-or heterolytic Cp*-Si bond cleavage allows the use of the cation as a source of silicon atoms in silicon cluster synthesis and in nanoparticle formation.
Stichworte
catalysis; cyclopentadienyl ligands; silicon; silicon(II) cation; pi interactions; nucleophilic addition
Erscheinungsjahr
2014
Zeitschriftentitel
Chemistry - A European Journal
Band
20
Ausgabe
30
Seite(n)
9192-9207
ISSN
0947-6539
Page URI
https://pub.uni-bielefeld.de/record/2695036

Zitieren

Jutzi P. The Pentamethylcyclopentadienylsilicon(II) Cation: Synthesis, Characterization, and Reactivity. Chemistry - A European Journal. 2014;20(30):9192-9207.
Jutzi, P. (2014). The Pentamethylcyclopentadienylsilicon(II) Cation: Synthesis, Characterization, and Reactivity. Chemistry - A European Journal, 20(30), 9192-9207. doi:10.1002/chem.201402163
Jutzi, Peter. 2014. “The Pentamethylcyclopentadienylsilicon(II) Cation: Synthesis, Characterization, and Reactivity”. Chemistry - A European Journal 20 (30): 9192-9207.
Jutzi, P. (2014). The Pentamethylcyclopentadienylsilicon(II) Cation: Synthesis, Characterization, and Reactivity. Chemistry - A European Journal 20, 9192-9207.
Jutzi, P., 2014. The Pentamethylcyclopentadienylsilicon(II) Cation: Synthesis, Characterization, and Reactivity. Chemistry - A European Journal, 20(30), p 9192-9207.
P. Jutzi, “The Pentamethylcyclopentadienylsilicon(II) Cation: Synthesis, Characterization, and Reactivity”, Chemistry - A European Journal, vol. 20, 2014, pp. 9192-9207.
Jutzi, P.: The Pentamethylcyclopentadienylsilicon(II) Cation: Synthesis, Characterization, and Reactivity. Chemistry - A European Journal. 20, 9192-9207 (2014).
Jutzi, Peter. “The Pentamethylcyclopentadienylsilicon(II) Cation: Synthesis, Characterization, and Reactivity”. Chemistry - A European Journal 20.30 (2014): 9192-9207.

4 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

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