Pentacoordinate silicon(IV): cationic, anionic and neutral complexes derived from the reaction of NHC -> SiCl4 with highly Lewis acidic (C2F5)(2)SiH2

Boettcher T, Steinhauer S, Neumann B, Stammler H-G, Roeschenthaler G-V, Hoge B (2014)
Chemical Communications 50(47): 6204-6206.

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DOI
Autor*in
Boettcher, T.; Steinhauer, SimonUniBi; Neumann, BeateUniBi; Stammler, Hans-GeorgUniBi; Roeschenthaler, G. -V.; Hoge, BertholdUniBi
Einrichtung
Fakultät für Chemie > Anorganische Chemie und Strukturchemie
Abstract / Bemerkung
Addition of NHC -> SiCl4 to the highly Lewis acidic bis(pentafluoroethyl) silane ((C2F5)(2)SiH2) afforded the salt [(NHC)(2)SiCl2H][(C2F5)(2)SiCl3] with pentacoordinate silicon in the cation and the anion. The anion represents the first example of a chlorosilicate structurally characterized in the solid state. In this reaction, the long sought pentacoordinate NHC-adduct of silicochloroform was identified as an intermediate and its crystal structure is presented.
Erscheinungsjahr
2014
Zeitschriftentitel
Chemical Communications
Band
50
Ausgabe
47
Seite(n)
6204-6206
ISSN
1359-7345
eISSN
1364-548X
Page URI
https://pub.uni-bielefeld.de/record/2684379

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Boettcher T, Steinhauer S, Neumann B, Stammler H-G, Roeschenthaler G-V, Hoge B. Pentacoordinate silicon(IV): cationic, anionic and neutral complexes derived from the reaction of NHC -> SiCl4 with highly Lewis acidic (C2F5)(2)SiH2. Chemical Communications. 2014;50(47):6204-6206.
Boettcher, T., Steinhauer, S., Neumann, B., Stammler, H. - G., Roeschenthaler, G. - V., & Hoge, B. (2014). Pentacoordinate silicon(IV): cationic, anionic and neutral complexes derived from the reaction of NHC -> SiCl4 with highly Lewis acidic (C2F5)(2)SiH2. Chemical Communications, 50(47), 6204-6206. doi:10.1039/c4cc02583k
Boettcher, T., Steinhauer, Simon, Neumann, Beate, Stammler, Hans-Georg, Roeschenthaler, G. -V., and Hoge, Berthold. 2014. “Pentacoordinate silicon(IV): cationic, anionic and neutral complexes derived from the reaction of NHC -> SiCl4 with highly Lewis acidic (C2F5)(2)SiH2”. Chemical Communications 50 (47): 6204-6206.
Boettcher, T., Steinhauer, S., Neumann, B., Stammler, H. - G., Roeschenthaler, G. - V., and Hoge, B. (2014). Pentacoordinate silicon(IV): cationic, anionic and neutral complexes derived from the reaction of NHC -> SiCl4 with highly Lewis acidic (C2F5)(2)SiH2. Chemical Communications 50, 6204-6206.
Boettcher, T., et al., 2014. Pentacoordinate silicon(IV): cationic, anionic and neutral complexes derived from the reaction of NHC -> SiCl4 with highly Lewis acidic (C2F5)(2)SiH2. Chemical Communications, 50(47), p 6204-6206.
T. Boettcher, et al., “Pentacoordinate silicon(IV): cationic, anionic and neutral complexes derived from the reaction of NHC -> SiCl4 with highly Lewis acidic (C2F5)(2)SiH2”, Chemical Communications, vol. 50, 2014, pp. 6204-6206.
Boettcher, T., Steinhauer, S., Neumann, B., Stammler, H.-G., Roeschenthaler, G.-V., Hoge, B.: Pentacoordinate silicon(IV): cationic, anionic and neutral complexes derived from the reaction of NHC -> SiCl4 with highly Lewis acidic (C2F5)(2)SiH2. Chemical Communications. 50, 6204-6206 (2014).
Boettcher, T., Steinhauer, Simon, Neumann, Beate, Stammler, Hans-Georg, Roeschenthaler, G. -V., and Hoge, Berthold. “Pentacoordinate silicon(IV): cationic, anionic and neutral complexes derived from the reaction of NHC -> SiCl4 with highly Lewis acidic (C2F5)(2)SiH2”. Chemical Communications 50.47 (2014): 6204-6206.

5 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

The Dynamic Equilibrium of Hexakis(pentafluoroethyl)distannane Adducts [XSn(C2 F5 )3 {Sn(C2 F5 )3 }]- (X=Cl, Br, I, Sn(C2 F5 )3 ).
Wiesemann M, Klösener J, Neumann B, Stammler HG, Hoge B., Chemistry 24(17), 2018
PMID: 29240270
Pentafluoroethylated Compounds of Silicon, Germanium and Tin.
Wiesemann M, Hoge B., Chemistry 24(62), 2018
PMID: 29722451
The classification and representation of main group element compounds that feature three-center four-electron interactions.
Green ML, Parkin G., Dalton Trans 45(47), 2016
PMID: 27845802
NHC→SiCl4 : an ambivalent carbene-transfer reagent.
Böttcher T, Steinhauer S, Lewis-Alleyne LC, Neumann B, Stammler HG, Bassil BS, Röschenthaler GV, Hoge B., Chemistry 21(2), 2015
PMID: 25363673
Synthesis of chlorosilicates.
Steinhauer S, Böttcher T, Schwarze N, Neumann B, Stammler HG, Hoge B., Angew Chem Int Ed Engl 53(48), 2014
PMID: 25256121

21 References

Daten bereitgestellt von Europe PubMed Central.


Chuit, Chem. Rev. 93(), 1993
Comparison of Phosphorus and Silicon: Hypervalency, Stereochemistry, and Reactivity.
Holmes RR., Chem. Rev. 96(3), 1996
PMID: 11848776

Levason, Coord. Chem. Rev. 255(), 2011

Campbell-Ferguson, J. Chem. Soc. A (), 1966

Fleischer, Chem. Ber. 129(), 1996

Boudjouk, J. Chem. Soc., Dalton Trans. (), 1998

Fester, Eur. J. Inorg. Chem. (), 2008
Octahedral HSiCl3 and HSiCl2Me adducts with pyridines.
Fester GW, Wagler J, Brendler E, Bohme U, Gerlach D, Kroke E., J. Am. Chem. Soc. 131(19), 2009
PMID: 19391595

Fester, Chem. – Eur. J. 14(), 2008
Lewis base mediated dismutation of trichlorosilane.
Singh AP, Ghadwal RS, Roesky HW, Holstein JJ, Dittrich B, Demers JP, Chevelkov V, Lange A., Chem. Commun. (Camb.) 48(61), 2012
PMID: 22735667

Kuhn, Chem. Ber. 128(), 1995

Xiong, Z. Naturforsch., B: Chem. Sci. 68(), 2013

Himmel, Angew. Chem., Int. Ed. 53(), 2014

Ghadwal, Organometallics 28(), 2009

Filippou, Chem. – Eur. J. 16(), 2010

Filippou, Angew. Chem., Int. Ed. 52(), 2013

Böttcher, Chem. Sci. 4(), 2013
Synthesis and characterization of new cationic hexacoordinate silanes.
Kim BK, Choi SB, Kloos SD, Boudjouk P., Inorg Chem 39(4), 2000
PMID: 11272567

Wartenberg, Z. Anorg. Allg. Chem. 273(), 1953

Ault, Inorg. Chem. 18(), 1979

Beattie, J. Chem. Soc. A (), 1969
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