Hydroxy Functionalization of Non-Activated C-H and C=C Bonds: New Perspectives for the Synthesis of Alcohols through Biocatalytic Processes

Gröger H (2014)
Angewandte Chemie. International edition 53(12): 3067-3069.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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DOI
Autor*in
Gröger, HaraldUniBi
Einrichtung
Fakultät für Chemie > Industrielle Organische Chemie und Biotechnologie
Abstract / Bemerkung
New perspectives through enzymes: Recent breakthroughs have been achieved in the selective hydroxy functionalization of non-activated C-H and C=C bonds. Enzymes turned out to be suitable catalysts for the ω-hydroxylation of (substituted) alkanes and regioselective hydroxylation of aromatic hydrocarbons with atmospheric oxygen as the oxidant, and the asymmetric addition of water to non-activated alkenes.
Erscheinungsjahr
2014
Zeitschriftentitel
Angewandte Chemie. International edition
Band
53
Ausgabe
12
Seite(n)
3067-3069
ISSN
1433-7851
Page URI
https://pub.uni-bielefeld.de/record/2672840

Zitieren

Gröger H. Hydroxy Functionalization of Non-Activated C-H and C=C Bonds: New Perspectives for the Synthesis of Alcohols through Biocatalytic Processes. Angewandte Chemie. International edition. 2014;53(12):3067-3069.
Gröger, H. (2014). Hydroxy Functionalization of Non-Activated C-H and C=C Bonds: New Perspectives for the Synthesis of Alcohols through Biocatalytic Processes. Angewandte Chemie. International edition, 53(12), 3067-3069. doi:10.1002/anie.201308556
Gröger, Harald. 2014. “Hydroxy Functionalization of Non-Activated C-H and C=C Bonds: New Perspectives for the Synthesis of Alcohols through Biocatalytic Processes”. Angewandte Chemie. International edition 53 (12): 3067-3069.
Gröger, H. (2014). Hydroxy Functionalization of Non-Activated C-H and C=C Bonds: New Perspectives for the Synthesis of Alcohols through Biocatalytic Processes. Angewandte Chemie. International edition 53, 3067-3069.
Gröger, H., 2014. Hydroxy Functionalization of Non-Activated C-H and C=C Bonds: New Perspectives for the Synthesis of Alcohols through Biocatalytic Processes. Angewandte Chemie. International edition, 53(12), p 3067-3069.
H. Gröger, “Hydroxy Functionalization of Non-Activated C-H and C=C Bonds: New Perspectives for the Synthesis of Alcohols through Biocatalytic Processes”, Angewandte Chemie. International edition, vol. 53, 2014, pp. 3067-3069.
Gröger, H.: Hydroxy Functionalization of Non-Activated C-H and C=C Bonds: New Perspectives for the Synthesis of Alcohols through Biocatalytic Processes. Angewandte Chemie. International edition. 53, 3067-3069 (2014).
Gröger, Harald. “Hydroxy Functionalization of Non-Activated C-H and C=C Bonds: New Perspectives for the Synthesis of Alcohols through Biocatalytic Processes”. Angewandte Chemie. International edition 53.12 (2014): 3067-3069.

10 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Evolving the Promiscuity of Elizabethkingia meningoseptica Oleate Hydratase for the Regio- and Stereoselective Hydration of Oleic Acid Derivatives.
Engleder M, Strohmeier GA, Weber H, Steinkellner G, Leitner E, Müller M, Mink D, Schürmann M, Schürmann M, Gruber K, Pichler H., Angew Chem Int Ed Engl 58(22), 2019
PMID: 30848865
Biocatalytic production of adiponitrile and related aliphatic linear α,ω-dinitriles.
Betke T, Maier M, Gruber-Wölfler H, Gröger H., Nat Commun 9(1), 2018
PMID: 30504854
A redox-neutral catechol synthesis.
Wu Q, Yan D, Chen Y, Wang T, Xiong F, Wei W, Lu Y, Sun WY, Li JJ, Zhao J., Nat Commun 8(), 2017
PMID: 28128196
Rhodium Complexes Promoting C-O Bond Formation in Reactions with Oxygen: The Role of Superoxo Species.
Vilella-Arribas L, García-Melchor M, Balcells D, Balcells D, Lledós A, López JA, Sancho S, Villarroya BE, Del Río MP, Ciriano MA, Tejel C., Chemistry 23(22), 2017
PMID: 28130799
Enantioselective synthesis of 1,2,3,4-tetrahydroquinoline-4-ols and 2,3-dihydroquinolin-4(1H)-ones via a sequential asymmetric hydroxylation/diastereoselective oxidation process using Rhodococcus equi ZMU-LK19.
Li K, Wang J, Wu K, Zheng D, Zhou X, Han W, Wan N, Cui B, Chen Y., Org Biomol Chem 15(17), 2017
PMID: 28177033
The medicinal chemist's toolbox for late stage functionalization of drug-like molecules.
Cernak T, Dykstra KD, Tyagarajan S, Vachal P, Krska SW., Chem Soc Rev 45(3), 2016
PMID: 26507237
Stereochemistry of enzymatic water addition to C=C bonds.
Chen BS, Otten LG, Hanefeld U., Biotechnol Adv 33(5), 2015
PMID: 25640045
Stability engineering of the Geobacillus stearothermophilus alcohol dehydrogenase and application for the synthesis of a polyamide 12 precursor.
Kirmair L, Seiler DL, Skerra A., Appl Microbiol Biotechnol 99(24), 2015
PMID: 26329849
Unactivated C(sp(3))-H hydroxylation through palladium catalysis with H2O as the oxygen source.
Hu J, Lan T, Sun Y, Chen H, Yao J, Rao Y., Chem Commun (Camb) 51(80), 2015
PMID: 26307027
Unusually broad substrate profile of self-sufficient cytochrome P450 monooxygenase CYP116B4 from Labrenzia aggregata.
Yin YC, Yu HL, Luan ZJ, Li RJ, Ouyang PF, Liu J, Xu JH., Chembiochem 15(16), 2014
PMID: 25236924

18 References

Daten bereitgestellt von Europe PubMed Central.


AUTHOR UNKNOWN, 2012

Liese, 2006
Engineering the third wave of biocatalysis.
Bornscheuer UT, Huisman GW, Kazlauskas RJ, Lutz S, Moore JC, Robins K., Nature 485(7397), 2012
PMID: 22575958

Constable, Green Chem. 9(), 2007
Outer membrane protein AlkL boosts biocatalytic oxyfunctionalization of hydrophobic substrates in Escherichia coli.
Julsing MK, Schrewe M, Cornelissen S, Hermann I, Schmid A, Buhler B., Appl. Environ. Microbiol. 78(16), 2012
PMID: 22685130

Schrewe, Adv. Synth. Catal. 355(), 2013

Dennig, Angew. Chem. 125(), 2013
Regioselective o-hydroxylation of monosubstituted benzenes by P450 BM3.
Dennig A, Lulsdorf N, Liu H, Schwaneberg U., Angew. Chem. Int. Ed. Engl. 52(32), 2013
PMID: 23818430

Wuensch, Angew. Chem. 125(), 2013
Asymmetric enzymatic hydration of hydroxystyrene derivatives.
Wuensch C, Gross J, Steinkellner G, Gruber K, Glueck SM, Faber K., Angew. Chem. Int. Ed. Engl. 52(8), 2013
PMID: 23335002

Asano, 2012

Schiffer, 2000

AUTHOR UNKNOWN, 0

Shoji, Angew. Chem. 125(), 2013
Highly selective hydroxylation of benzene to phenol by wild-type cytochrome P450BM3 assisted by decoy molecules.
Shoji O, Kunimatsu T, Kawakami N, Watanabe Y., Angew. Chem. Int. Ed. Engl. 52(26), 2013
PMID: 23649984

Hintermann, Top. Organomet. Chem. 31(), 2010
Formal asymmetric hydration of non-activated alkenes in aqueous medium through a "chemoenzymatic catalytic system".
Schnapperelle I, Hummel W, Groger H., Chemistry 18(4), 2011
PMID: 22213251
The selective addition of water to C=C bonds; enzymes are the best chemists.
Jin J, Hanefeld U., Chem. Commun. (Camb.) 47(9), 2011
PMID: 21243161
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