Rare-Earth-Metal Dialkynyl Dimethyl Aluminates
Nieland A, Mix A, Neumann B, Stammler H-G, Mitzel NW (2013)
Chemistry 19(25): 8268-8275.
Zeitschriftenaufsatz
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Abstract / Bemerkung
A new class of rare-earth-metal alkynyl complexes has been prepared. The reactions of the tris(tetramethylaluminate)s of lanthanum, praseodymium, samarium, yttrium, holmium, and thulium, [Ln(AlMe4)3], with phenylacetylene afforded compounds [Ln{(-CCPh)2AlMe2}3] (Ln=La (1), Pr (2), Sm (3), Y (4), Ho (5), Tm (6)). All of these compounds have been characterized by NMR spectroscopy, X-ray crystallography, and by elemental analysis. NMR spectroscopic studies of the series of para- magnetic compounds [Ln(AlMe4)3] and [Ln{(-CCPh)2AlMe2}3] have also been performed.
Stichworte
lanthanides;
binding modes;
alkynes;
aluminum;
NMR spectroscopy
Erscheinungsjahr
2013
Zeitschriftentitel
Chemistry
Band
19
Ausgabe
25
Seite(n)
8268-8275
ISSN
0947-6539
Page URI
https://pub.uni-bielefeld.de/record/2612911
Zitieren
Nieland A, Mix A, Neumann B, Stammler H-G, Mitzel NW. Rare-Earth-Metal Dialkynyl Dimethyl Aluminates. Chemistry. 2013;19(25):8268-8275.
Nieland, A., Mix, A., Neumann, B., Stammler, H. - G., & Mitzel, N. W. (2013). Rare-Earth-Metal Dialkynyl Dimethyl Aluminates. Chemistry, 19(25), 8268-8275. doi:10.1002/chem.201300465
Nieland, Anja, Mix, Andreas, Neumann, Beate, Stammler, Hans-Georg, and Mitzel, Norbert W. 2013. “Rare-Earth-Metal Dialkynyl Dimethyl Aluminates”. Chemistry 19 (25): 8268-8275.
Nieland, A., Mix, A., Neumann, B., Stammler, H. - G., and Mitzel, N. W. (2013). Rare-Earth-Metal Dialkynyl Dimethyl Aluminates. Chemistry 19, 8268-8275.
Nieland, A., et al., 2013. Rare-Earth-Metal Dialkynyl Dimethyl Aluminates. Chemistry, 19(25), p 8268-8275.
A. Nieland, et al., “Rare-Earth-Metal Dialkynyl Dimethyl Aluminates”, Chemistry, vol. 19, 2013, pp. 8268-8275.
Nieland, A., Mix, A., Neumann, B., Stammler, H.-G., Mitzel, N.W.: Rare-Earth-Metal Dialkynyl Dimethyl Aluminates. Chemistry. 19, 8268-8275 (2013).
Nieland, Anja, Mix, Andreas, Neumann, Beate, Stammler, Hans-Georg, and Mitzel, Norbert W. “Rare-Earth-Metal Dialkynyl Dimethyl Aluminates”. Chemistry 19.25 (2013): 8268-8275.
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Daten bereitgestellt von Europe PubMed Central.
68 References
Daten bereitgestellt von Europe PubMed Central.
Tsutsui, J. Am. Chem. Soc. 96(), 1974
AUTHOR UNKNOWN, 0
Jung, Tetrahedron Lett. 36(), 1995
Lindbäck, Eur. J. Org. Chem. 2010(), 2010
Design, synthesis, and anti-HIV activity of 4'-modified carbocyclic nucleoside phosphonate reverse transcriptase inhibitors.
Boojamra CG, Parrish JP, Sperandio D, Gao Y, Petrakovsky OV, Lee SK, Markevitch DY, Vela JE, Laflamme G, Chen JM, Ray AS, Barron AC, Sparacino ML, Desai MC, Kim CU, Cihlar T, Mackman RL., Bioorg. Med. Chem. 17(4), 2008
PMID: 19179082
Boojamra CG, Parrish JP, Sperandio D, Gao Y, Petrakovsky OV, Lee SK, Markevitch DY, Vela JE, Laflamme G, Chen JM, Ray AS, Barron AC, Sparacino ML, Desai MC, Kim CU, Cihlar T, Mackman RL., Bioorg. Med. Chem. 17(4), 2008
PMID: 19179082
Internalization of a C17α-alkynylestradiol-porphyrin conjugate into estrogen receptor positive MCF-7 breast cancer cells.
Sadler S, Persons KS, Jones GB, Ray R., Bioorg. Med. Chem. Lett. 21(15), 2011
PMID: 21704522
Sadler S, Persons KS, Jones GB, Ray R., Bioorg. Med. Chem. Lett. 21(15), 2011
PMID: 21704522
AUTHOR UNKNOWN, 0
Shen, J. Organomet. Chem. 391(), 1990
Duchateau, J. Am. Chem. Soc. 115(), 1993
Straub, J. Am. Chem. Soc. 117(), 1995
Novel Z-selective head-to-head dimerization of terminal alkynes catalyzed by lanthanide half-metallocene complexes.
Nishiura M, Hou Z, Wakatsuki Y, Yamaki T, Miyamoto T., J. Am. Chem. Soc. 125(5), 2003
PMID: 12553817
Nishiura M, Hou Z, Wakatsuki Y, Yamaki T, Miyamoto T., J. Am. Chem. Soc. 125(5), 2003
PMID: 12553817
Tazelaar, Organometallics 23(), 2004
Rare-earth silylamide-catalyzed selective dimerization of terminal alkynes and subsequent hydrophosphination in one pot.
Komeyama K, Kawabata T, Takehira K, Takaki K., J. Org. Chem. 70(18), 2005
PMID: 16122246
Komeyama K, Kawabata T, Takehira K, Takaki K., J. Org. Chem. 70(18), 2005
PMID: 16122246
Ge, Organometallics 28(), 2009
Heeres, Organometallics 10(), 1991
AUTHOR UNKNOWN, 0
Deacon, J. Organomet. Chem. 146(), 1978
Dinuclear alkynyllanthanoid(II) dications with pentaphenylcyclopentadienyl or tri-tert-butyldiphosphacyclopentadienyl counter ions.
Forsyth CM, Deacon GB, Field LD, Jones C, Junk PC, Kay DL, Masters AF, Richards AF., Chem. Commun. (Camb.) (9), 2006
PMID: 16491190
Forsyth CM, Deacon GB, Field LD, Jones C, Junk PC, Kay DL, Masters AF, Richards AF., Chem. Commun. (Camb.) (9), 2006
PMID: 16491190
Steric modulation of coordination number and reactivity in the synthesis of lanthanoid(III) formamidinates.
Cole ML, Deacon GB, Forsyth CM, Junk PC, Konstas K, Wang J., Chemistry 13(29), 2007
PMID: 17768759
Cole ML, Deacon GB, Forsyth CM, Junk PC, Konstas K, Wang J., Chemistry 13(29), 2007
PMID: 17768759
Boncella, J. Chem. Soc. Chem. Commun. (), 1984
AUTHOR UNKNOWN, 0
Reactions of yttrium and scandium atoms with acetylene: a matrix isolation infrared spectroscopic and theoretical study.
Teng YL, Xu Q., J Phys Chem A 114(34), 2010
PMID: 20695467
Teng YL, Xu Q., J Phys Chem A 114(34), 2010
PMID: 20695467
Reactions of Th and U atoms with C2H2: infrared spectra and relativistic calculations of the metallacyclopropene, actinide insertion, and ethynyl products.
Andrews L, Kushto GP, Marsden CJ., Chemistry 12(32), 2006
PMID: 16933343
Andrews L, Kushto GP, Marsden CJ., Chemistry 12(32), 2006
PMID: 16933343
Den, Organometallics 6(), 1987
AUTHOR UNKNOWN, 0
Saliu, Organometallics 29(), 2010
Liu, Organometallics 28(), 2009
Cameron, Organometallics 23(), 2004
Ge, Organometallics 26(), 2007
Quiroga, Organometallics 27(), 2008
Evans, Organometallics 12(), 1993
Nolan, J. Am. Chem. Soc. 111(), 1989
Pi-conjugated aromatic enynes as a single-emitting component for white electroluminescence.
Liu Y, Nishiura M, Wang Y, Hou Z., J. Am. Chem. Soc. 128(17), 2006
PMID: 16637599
Liu Y, Nishiura M, Wang Y, Hou Z., J. Am. Chem. Soc. 128(17), 2006
PMID: 16637599
AUTHOR UNKNOWN, 0
Manipulation of reaction pathways in redox transmetallation-ligand exchange syntheses of lanthanoid(II)/(III) aryloxide complexes.
Deacon GB, Fallon GD, Forsyth CM, Harris SC, Junk PC, Skelton BW, White AH., Dalton Trans (6), 2005
PMID: 16437175
Deacon GB, Fallon GD, Forsyth CM, Harris SC, Junk PC, Skelton BW, White AH., Dalton Trans (6), 2005
PMID: 16437175
Evans, Organometallics 9(), 1990
Thomson, J. Organomet. Chem. 696(), 2011
Lin, Organometallics 19(), 2000
AUTHOR UNKNOWN, 0
Intramolecular metal-fluorocarbon coordination, C-F bond activation and lanthanoid-fluoride clusters with tethered polyfluorophenylamide ligands.
Deacon GB, Forsyth CM, Junk PC, Wang J., Chemistry 15(13), 2009
PMID: 19222064
Deacon GB, Forsyth CM, Junk PC, Wang J., Chemistry 15(13), 2009
PMID: 19222064
Ren, Polyhedron 15(), 1996
AUTHOR UNKNOWN, 0
Neutral ligand induced methane elimination from rare-earth metal tetramethylaluminates up to the six-coordinate carbide state.
Venugopal A, Kamps I, Bojer D, Berger RJ, Mix A, Willner A, Neumann B, Stammler HG, Mitzel NW., Dalton Trans (29), 2009
PMID: 20449090
Venugopal A, Kamps I, Bojer D, Berger RJ, Mix A, Willner A, Neumann B, Stammler HG, Mitzel NW., Dalton Trans (29), 2009
PMID: 20449090
Bojer, Angew. Chem. 122(), 2010
Cationic rare-earth-metal methyl complexes: a new preparative access exemplified for Y and Pr.
Nieland A, Mix A, Neumann B, Stammler HG, Mitzel NW., Dalton Trans 39(29), 2010
PMID: 20442946
Nieland A, Mix A, Neumann B, Stammler HG, Mitzel NW., Dalton Trans 39(29), 2010
PMID: 20442946
Substituent size effects in lewis base induced reductions in organolanthanide chemistry.
Bojer D, Neumann B, Stammler HG, Mitzel NW., Chemistry 17(22), 2011
PMID: 21503981
Bojer D, Neumann B, Stammler HG, Mitzel NW., Chemistry 17(22), 2011
PMID: 21503981
AUTHOR UNKNOWN, 0
Homoleptic rare-earth metal(III) tetramethylaluminates: structural chemistry, reactivity, and performance in isoprene polymerization.
Zimmermann M, Froystein NA, Fischbach A, Sirsch P, Dietrich HM, Tornroos KW, Herdtweck E, Anwander R., Chemistry 13(31), 2007
PMID: 17654457
Zimmermann M, Froystein NA, Fischbach A, Sirsch P, Dietrich HM, Tornroos KW, Herdtweck E, Anwander R., Chemistry 13(31), 2007
PMID: 17654457
Fischbach, Angew. Chem. 116(), 2004
Stereospecific polymerization of isoprene with molecular and MCM-48-grafted lanthanide(III) tetraalkylaluminates.
Fischbach A, Klimpel MG, Widenmeyer M, Herdtweck E, Scherer W, Anwander R., Angew. Chem. Int. Ed. Engl. 43(17), 2004
PMID: 15108131
Fischbach A, Klimpel MG, Widenmeyer M, Herdtweck E, Scherer W, Anwander R., Angew. Chem. Int. Ed. Engl. 43(17), 2004
PMID: 15108131
Zimmermann, Organometallics 25(), 2006
Homoleptic rare-earth metal complexes containing Ln-C σ-bonds.
Zimmermann M, Anwander R., Chem. Rev. 110(10), 2010
PMID: 20879714
Zimmermann M, Anwander R., Chem. Rev. 110(10), 2010
PMID: 20879714
Cationic methyl complexes of the rare-earth metals: an experimental and computational study on synthesis, structure, and reactivity.
Kramer MU, Robert D, Arndt S, Zeimentz PM, Spaniol TP, Yahia A, Maron L, Eisenstein O, Okuda J., Inorg Chem 47(20), 2008
PMID: 18816050
Kramer MU, Robert D, Arndt S, Zeimentz PM, Spaniol TP, Yahia A, Maron L, Eisenstein O, Okuda J., Inorg Chem 47(20), 2008
PMID: 18816050
Arndt, Angew. Chem. 115(), 2003
Homogeneous ethylene-polymerization catalysts based on alkyl cations of the rare-earth metals: are dicationic mono(alkyl) complexes the active species?
Arndt S, Spaniol TP, Okuda J., Angew. Chem. Int. Ed. Engl. 42(41), 2003
PMID: 14595637
Arndt S, Spaniol TP, Okuda J., Angew. Chem. Int. Ed. Engl. 42(41), 2003
PMID: 14595637
Holleman, 2007
Almenningen, J. Organomet. Chem. 155(), 1978
AUTHOR UNKNOWN, 0
AUTHOR UNKNOWN, 0
Evans, J. Chem. Soc. Chem. Commun. (), 1975
NMR structure determination of protein-ligand complexes by lanthanide labeling.
Pintacuda G, John M, Su XC, Otting G., Acc. Chem. Res. 40(3), 2007
PMID: 17370992
Pintacuda G, John M, Su XC, Otting G., Acc. Chem. Res. 40(3), 2007
PMID: 17370992
AUTHOR UNKNOWN, 1986
Quantitative determination of mononucleotide conformations in solution using lanthanide ion shift and broadenine NMR probes.
Barry CD, North AC, Glasel JA, Williams RJ, Xavier AV., Nature 232(5308), 1971
PMID: 4937076
Barry CD, North AC, Glasel JA, Williams RJ, Xavier AV., Nature 232(5308), 1971
PMID: 4937076
Magnetic susceptibility tensor anisotropies for a lanthanide ion series in a fixed protein matrix.
Bertini I, Janik MB, Lee YM, Luchinat C, Rosato A., J. Am. Chem. Soc. 123(18), 2001
PMID: 11457182
Bertini I, Janik MB, Lee YM, Luchinat C, Rosato A., J. Am. Chem. Soc. 123(18), 2001
PMID: 11457182
AUTHOR UNKNOWN, 1998
Synthesis and stability of homoleptic metal(III) tetramethylaluminates.
Occhipinti G, Meermann C, Dietrich HM, Litlabo R, Auras F, Tornroos KW, Maichle-Mossmer C, Jensen VR, Anwander R., J. Am. Chem. Soc. 133(16), 2011
PMID: 21466201
Occhipinti G, Meermann C, Dietrich HM, Litlabo R, Auras F, Tornroos KW, Maichle-Mossmer C, Jensen VR, Anwander R., J. Am. Chem. Soc. 133(16), 2011
PMID: 21466201
A short history of SHELX.
Sheldrick GM., Acta Crystallogr., A, Found. Crystallogr. 64(Pt 1), 2007
PMID: 18156677
Sheldrick GM., Acta Crystallogr., A, Found. Crystallogr. 64(Pt 1), 2007
PMID: 18156677
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