Bis(tetrafluorophenyl)borane
Winkelhaus D, Neumann B, Stammler H-G, Mitzel NW (2012)
Dalton Transactions 41(28): 8609-8614.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
Download
Es wurden keine Dateien hochgeladen. Nur Publikationsnachweis!
Autor*in
Abstract / Bemerkung
The reaction of the Grignard reagent (p-C6F4H) MgBr with Me2SnCl2 afforded the p-C6F4H transfer reagent Me2Sn(p-C6F4H)(2) (1). Subsequent reaction of 1 with BCl3 led to the chloroborane (p-C6F4H)(2)BCl (2), which was converted to the borane [(p-C6F4H)(2)BH](2) (3) by treatment with the hydride source Me2SiHCl. By reaction of tetrafluoropyridine with i-PrMgCl followed by the in situ reaction with Me2SnCl2, the stannane Me2Sn(C5F4N)(2) (4) could be obtained. However, this did not react with BCl3. The resulting products were characterized by elemental analyses and NMR spectroscopy. Single crystal X-ray diffraction experiments were performed for compounds 1, 2 and 4. The crystal structure of the literature known compound Me2Sn(C6F5)(2) (5) was determined and compared with structures of 1 and 4.
Erscheinungsjahr
2012
Zeitschriftentitel
Dalton Transactions
Band
41
Ausgabe
28
Seite(n)
8609-8614
ISSN
1477-9226
eISSN
1477-9234
Page URI
https://pub.uni-bielefeld.de/record/2518132
Zitieren
Winkelhaus D, Neumann B, Stammler H-G, Mitzel NW. Bis(tetrafluorophenyl)borane. Dalton Transactions. 2012;41(28):8609-8614.
Winkelhaus, D., Neumann, B., Stammler, H. - G., & Mitzel, N. W. (2012). Bis(tetrafluorophenyl)borane. Dalton Transactions, 41(28), 8609-8614. doi:10.1039/c2dt30924f
Winkelhaus, Daniel, Neumann, Beate, Stammler, Hans-Georg, and Mitzel, Norbert W. 2012. “Bis(tetrafluorophenyl)borane”. Dalton Transactions 41 (28): 8609-8614.
Winkelhaus, D., Neumann, B., Stammler, H. - G., and Mitzel, N. W. (2012). Bis(tetrafluorophenyl)borane. Dalton Transactions 41, 8609-8614.
Winkelhaus, D., et al., 2012. Bis(tetrafluorophenyl)borane. Dalton Transactions, 41(28), p 8609-8614.
D. Winkelhaus, et al., “Bis(tetrafluorophenyl)borane”, Dalton Transactions, vol. 41, 2012, pp. 8609-8614.
Winkelhaus, D., Neumann, B., Stammler, H.-G., Mitzel, N.W.: Bis(tetrafluorophenyl)borane. Dalton Transactions. 41, 8609-8614 (2012).
Winkelhaus, Daniel, Neumann, Beate, Stammler, Hans-Georg, and Mitzel, Norbert W. “Bis(tetrafluorophenyl)borane”. Dalton Transactions 41.28 (2012): 8609-8614.
Daten bereitgestellt von European Bioinformatics Institute (EBI)
2 Zitationen in Europe PMC
Daten bereitgestellt von Europe PubMed Central.
Tris(perfluorotolyl)borane-A Boron Lewis Superacid.
Körte LA, Schwabedissen J, Soffner M, Blomeyer S, Reuter CG, Vishnevskiy YV, Neumann B, Stammler HG, Mitzel NW., Angew Chem Int Ed Engl 56(29), 2017
PMID: 28524451
Körte LA, Schwabedissen J, Soffner M, Blomeyer S, Reuter CG, Vishnevskiy YV, Neumann B, Stammler HG, Mitzel NW., Angew Chem Int Ed Engl 56(29), 2017
PMID: 28524451
A highly cis-selective and enantioselective metal-free hydrogenation of 2,3-disubstituted quinoxalines.
Zhang Z, Du H., Angew Chem Int Ed Engl 54(2), 2015
PMID: 25393413
Zhang Z, Du H., Angew Chem Int Ed Engl 54(2), 2015
PMID: 25393413
33 References
Daten bereitgestellt von Europe PubMed Central.
Massey, Proc. Chem. Soc. (), 1963
Massey, J. Organomet. Chem. 2(), 1964
Cocatalysts for metal-catalyzed olefin polymerization: activators, activation processes, and structure-activity relationships.
Chen EY, Marks TJ., Chem. Rev. 100(4), 2000
PMID: 11749269
Chen EY, Marks TJ., Chem. Rev. 100(4), 2000
PMID: 11749269
Yang, J. Am. Chem. Soc. 113(), 1991
Yang, J. Am. Chem. Soc. 116(), 1994
Reversible, metal-free hydrogen activation.
Welch GC, San Juan RR, Masuda JD, Stephan DW., Science 314(5802), 2006
PMID: 17110572
Welch GC, San Juan RR, Masuda JD, Stephan DW., Science 314(5802), 2006
PMID: 17110572
Activation of dihydrogen by non-metal systems.
Stephan DW., Chem. Commun. (Camb.) 46(45), 2010
PMID: 20967357
Stephan DW., Chem. Commun. (Camb.) 46(45), 2010
PMID: 20967357
Stephan, Angew. Chem. 122(), 2009
"Frustrated Lewis pairs": a concept for new reactivity and catalysis.
Stephan DW., Org. Biomol. Chem. 6(9), 2008
PMID: 18421382
Stephan DW., Org. Biomol. Chem. 6(9), 2008
PMID: 18421382
Facile heterolytic cleavage of dihydrogen by phosphines and boranes.
Welch GC, Stephan DW., J. Am. Chem. Soc. 129(7), 2007
PMID: 17260994
Welch GC, Stephan DW., J. Am. Chem. Soc. 129(7), 2007
PMID: 17260994
Spies, Chem. Commun. (), 2007
Tandem frustrated Lewis pair/tris(pentafluorophenyl)borane-catalyzed deoxygenative hydrosilylation of carbon dioxide.
Berkefeld A, Piers WE, Parvez M., J. Am. Chem. Soc. 132(31), 2010
PMID: 20681691
Berkefeld A, Piers WE, Parvez M., J. Am. Chem. Soc. 132(31), 2010
PMID: 20681691
Mömming, Angew. Chem. 121(), 2009
Ménard, Angew. Chem. 123(), 2011
Neu, Chem. Sci. 2(), 2011
Neu, Angew. Chem. 121(), 2009
Spies, Angew. Chem. 120(), 2008
Sumerin, Angew. Chem. 120(), 2008
Sumerin, J. Organomet. Chem. 694(), 2009
Chase, Chem. Commun. (), 2008
Parks, Organometallics 17(), 1998
Parks, Angew. Chem. 107(), 1995
Parks, Angew. Chem., Int. Ed. Engl. 34(), 1995
Welch, Dalton Trans. (), 2007
Reversible, metal-free, heterolytic activation of H2 at room temperature.
Ullrich M, Lough AJ, Stephan DW., J. Am. Chem. Soc. 131(1), 2009
PMID: 19061321
Ullrich M, Lough AJ, Stephan DW., J. Am. Chem. Soc. 131(1), 2009
PMID: 19061321
Ullrich, Organometallics 29(), 2010
Chambers, J. Chem. Soc. (), 1964
Piers, Acta Crystallogr., Sect. C: Cryst. Struct. Commun. C51(), 1995
Fraenk, J. Fluorine Chem. 112(), 2001
Soderquist, J. Org. Chem. 45(), 1980
Hoge, J. Fluorine Chem. 128(), 2007
Laev, Tetrahedron Lett. 38(), 1997
Sheldrick, Acta Crystallogr., Sect. A: Fundam. Crystallogr. A64(), 2008
Export
Markieren/ Markierung löschen
Markierte Publikationen
Web of Science
Dieser Datensatz im Web of Science®Quellen
PMID: 22674228
PubMed | Europe PMC
Suchen in