The (CpSi+)-Si-star cation as a stoichiometric source of silicon

Leszczynska K, Abersfelder K, Majumdar M, Neumann B, Stammler H-G, Rzepa HS, Jutzi P, Scheschkewitz D (2012)
Chemical Communications 48(63): 7820-7822.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
The (CpSi+)-Si-star cation acts as a stoichiometric source of silicon in the reaction with the disilenide Tip(2)Si=Si(Tip)Li (Tip = 2,4,6-(Pr3C6H2)-Pr-i) affording known neutral unsaturated silicon clusters. It thereby provides a conceptually different approach to this novel class of compounds. The proposed mechanism involves a Cp-star-substituted cyclotrisilene in which Cp star- acts as a leaving group upon single electron reduction or in a nucleophilic substitution step.
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Zeitschriftentitel
Chemical Communications
Band
48
Ausgabe
63
Seite(n)
7820-7822
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Leszczynska K, Abersfelder K, Majumdar M, et al. The (CpSi+)-Si-star cation as a stoichiometric source of silicon. Chemical Communications. 2012;48(63):7820-7822.
Leszczynska, K., Abersfelder, K., Majumdar, M., Neumann, B., Stammler, H. - G., Rzepa, H. S., Jutzi, P., et al. (2012). The (CpSi+)-Si-star cation as a stoichiometric source of silicon. Chemical Communications, 48(63), 7820-7822. doi:10.1039/c2cc33911k
Leszczynska, K., Abersfelder, K., Majumdar, M., Neumann, B., Stammler, H. - G., Rzepa, H. S., Jutzi, P., and Scheschkewitz, D. (2012). The (CpSi+)-Si-star cation as a stoichiometric source of silicon. Chemical Communications 48, 7820-7822.
Leszczynska, K., et al., 2012. The (CpSi+)-Si-star cation as a stoichiometric source of silicon. Chemical Communications, 48(63), p 7820-7822.
K. Leszczynska, et al., “The (CpSi+)-Si-star cation as a stoichiometric source of silicon”, Chemical Communications, vol. 48, 2012, pp. 7820-7822.
Leszczynska, K., Abersfelder, K., Majumdar, M., Neumann, B., Stammler, H.-G., Rzepa, H.S., Jutzi, P., Scheschkewitz, D.: The (CpSi+)-Si-star cation as a stoichiometric source of silicon. Chemical Communications. 48, 7820-7822 (2012).
Leszczynska, Kinga, Abersfelder, Kai, Majumdar, Moumita, Neumann, Beate, Stammler, Hans-Georg, Rzepa, Henry S., Jutzi, Peter, and Scheschkewitz, David. “The (CpSi+)-Si-star cation as a stoichiometric source of silicon”. Chemical Communications 48.63 (2012): 7820-7822.

5 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Functional Disilenes in Synthesis.
Rammo A, Scheschkewitz D., Chemistry 24(27), 2018
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(Multi-)Metallic Cluster Growth.
Weinert B, Mitzinger S, Dehnen S., Chemistry 24(34), 2018
PMID: 29466607
Stable unsaturated silicon clusters (siliconoids).
Heider Y, Scheschkewitz D., Dalton Trans 47(21), 2018
PMID: 29676421

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