The (CpSi+)-Si-star cation as a stoichiometric source of silicon

Leszczynska K, Abersfelder K, Majumdar M, Neumann B, Stammler H-G, Rzepa HS, Jutzi P, Scheschkewitz D (2012)
Chemical Communications 48(63): 7820-7822.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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DOI
Autor*in
Leszczynska, Kinga; Abersfelder, Kai; Majumdar, Moumita; Neumann, BeateUniBi; Stammler, Hans-GeorgUniBi; Rzepa, Henry S.; Jutzi, PeterUniBi; Scheschkewitz, David
Einrichtung
Fakultät für Chemie > Anorganische Chemie und Strukturchemie
Abstract / Bemerkung
The (CpSi+)-Si-star cation acts as a stoichiometric source of silicon in the reaction with the disilenide Tip(2)Si=Si(Tip)Li (Tip = 2,4,6-(Pr3C6H2)-Pr-i) affording known neutral unsaturated silicon clusters. It thereby provides a conceptually different approach to this novel class of compounds. The proposed mechanism involves a Cp-star-substituted cyclotrisilene in which Cp star- acts as a leaving group upon single electron reduction or in a nucleophilic substitution step.
Erscheinungsjahr
2012
Zeitschriftentitel
Chemical Communications
Band
48
Ausgabe
63
Seite(n)
7820-7822
ISSN
1359-7345
eISSN
1364-548X
Page URI
https://pub.uni-bielefeld.de/record/2518088

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Leszczynska K, Abersfelder K, Majumdar M, et al. The (CpSi+)-Si-star cation as a stoichiometric source of silicon. Chemical Communications. 2012;48(63):7820-7822.
Leszczynska, K., Abersfelder, K., Majumdar, M., Neumann, B., Stammler, H. - G., Rzepa, H. S., Jutzi, P., et al. (2012). The (CpSi+)-Si-star cation as a stoichiometric source of silicon. Chemical Communications, 48(63), 7820-7822. doi:10.1039/c2cc33911k
Leszczynska, Kinga, Abersfelder, Kai, Majumdar, Moumita, Neumann, Beate, Stammler, Hans-Georg, Rzepa, Henry S., Jutzi, Peter, and Scheschkewitz, David. 2012. “The (CpSi+)-Si-star cation as a stoichiometric source of silicon”. Chemical Communications 48 (63): 7820-7822.
Leszczynska, K., Abersfelder, K., Majumdar, M., Neumann, B., Stammler, H. - G., Rzepa, H. S., Jutzi, P., and Scheschkewitz, D. (2012). The (CpSi+)-Si-star cation as a stoichiometric source of silicon. Chemical Communications 48, 7820-7822.
Leszczynska, K., et al., 2012. The (CpSi+)-Si-star cation as a stoichiometric source of silicon. Chemical Communications, 48(63), p 7820-7822.
K. Leszczynska, et al., “The (CpSi+)-Si-star cation as a stoichiometric source of silicon”, Chemical Communications, vol. 48, 2012, pp. 7820-7822.
Leszczynska, K., Abersfelder, K., Majumdar, M., Neumann, B., Stammler, H.-G., Rzepa, H.S., Jutzi, P., Scheschkewitz, D.: The (CpSi+)-Si-star cation as a stoichiometric source of silicon. Chemical Communications. 48, 7820-7822 (2012).
Leszczynska, Kinga, Abersfelder, Kai, Majumdar, Moumita, Neumann, Beate, Stammler, Hans-Georg, Rzepa, Henry S., Jutzi, Peter, and Scheschkewitz, David. “The (CpSi+)-Si-star cation as a stoichiometric source of silicon”. Chemical Communications 48.63 (2012): 7820-7822.

6 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Atomically Precise Expansion of Unsaturated Silicon Clusters.
Leszczyńska KI, Huch V, Präsang C, Schwabedissen J, Berger RJF, Scheschkewitz D., Angew Chem Int Ed Engl 58(15), 2019
PMID: 30633856
Functional Disilenes in Synthesis.
Rammo A, Scheschkewitz D., Chemistry 24(27), 2018
PMID: 29193341
(Multi-)Metallic Cluster Growth.
Weinert B, Mitzinger S, Dehnen S., Chemistry 24(34), 2018
PMID: 29466607
Stable unsaturated silicon clusters (siliconoids).
Heider Y, Scheschkewitz D., Dalton Trans 47(21), 2018
PMID: 29676421
Reactivity in the periphery of functionalised multiple bonds of heavier group 14 elements.
Präsang C, Scheschkewitz D., Chem Soc Rev 45(4), 2016
PMID: 26503807
The pentamethylcyclopentadienylsilicon(II) cation: synthesis, characterization, and reactivity.
Jutzi P., Chemistry 20(30), 2014
PMID: 24986115

28 References

Daten bereitgestellt von Europe PubMed Central.

Deposition dynamics of hydrogenated silicon clusters on a crystalline silicon substrate under typical plasma conditions.
Ning N, Vach H., J Phys Chem A 114(9), 2010
PMID: 20088485

Shcherbyna, Thin Solid Films 518(), 2010

Matsumoto, J. Chem. Soc., Chem. Commun. (), 1988

Matsumoto, Angew. Chem. 104(), 1992

Wiberg, Angew. Chem. 105(), 1993

Sekiguchi, J. Am. Chem. Soc. 115(), 1993
Tetrasilatetrahedranide: a silicon cage anion.
Ichinohe M, Toyoshima M, Kinjo R, Sekiguchi A., J. Am. Chem. Soc. 125(44), 2003
PMID: 14583007

Meyer-Wegner, Organometallics 28(), 2009
Real-space observation of local anisotropic correlation between buckled dimers on Si(100) induced by a bidentate adsorbed molecule.
Hossain MZ, Mukai K, Yamashita Y, Kawai H, Yoshinobu J., Chem. Commun. (Camb.) 47(37), 2011
PMID: 21833437

Sevov, Organometallics 25(), 2006

Scharfe, Angew. Chem. 123(), 2011
Metalloid group 14 cluster compounds: an introduction and perspectives to this novel group of cluster compounds.
Schnepf A., Chem Soc Rev 36(5), 2006
PMID: 17471399
A stable bicyclic compound with two Si=Si double bonds.
Iwamoto T, Tamura M, Kabuto C, Kira M., Science 290(5491), 2000
PMID: 11039928

Scheschkewitz, Angew. Chem. 117(), 2005

Fischer, Angew. Chem. 117(), 2005
Synthesis of a pentasilapropellane. Exploring the nature of a stretched silicon-silicon bond in a nonclassical molecule.
Nied D, Koppe R, Klopper W, Schnockel H, Breher F., J. Am. Chem. Soc. 132(30), 2010
PMID: 20662508

Abersfelder, Angew. Chem. 123(), 2011
A tricyclic aromatic isomer of hexasilabenzene.
Abersfelder K, White AJ, Rzepa HS, Scheschkewitz D., Science 327(5965), 2010
PMID: 20110501

Berger, Angew. Chem. 122(), 2010

Jutzi, J. Chem. Soc., Dalton Trans. (), 2000

Purath, J. Am. Chem. Soc. 122(), 2000
The (Me5C5)Si+ cation: a stable derivative of HSi+.
Jutzi P, Mix A, Rummel B, Schoeller WW, Neumann B, Stammler HG., Science 305(5685), 2004
PMID: 15232074

Scheschkewitz, Angew. Chem. 116(), 2004

Weidenbruch, Angew. Chem. 109(), 1997
Reversible base coordination to a disilene.
Leszczynska K, Abersfelder K, Mix A, Neumann B, Stammler HG, Cowley MJ, Jutzi P, Scheschkewitz D., Angew. Chem. Int. Ed. Engl. 51(27), 2012
PMID: 22639373
Structure, strain, and degenerate rearrangement of tricyclo[2.1.0.0 1,3]pentasilane and related molecules.
Takeuchi K, Uemura D, Inagaki S., J Phys Chem A 109(38), 2005
PMID: 16834263
Long-range corrected hybrid density functionals with damped atom-atom dispersion corrections.
Chai JD, Head-Gordon M., Phys Chem Chem Phys 10(44), 2008
PMID: 18989472
SPECTRa: the deposition and validation of primary chemistry research data in digital repositories.
Downing J, Murray-Rust P, Tonge AP, Morgan P, Rzepa HS, Cotterill F, Day N, Harvey MJ., J Chem Inf Model 48(8), 2008
PMID: 18661966
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