Enantioselective supramolecular devices in the gas phase. Resorcin[4] arene as a model system
Fraschetti C, Letzel M, Filippi A, Speranza M, Mattay J (2012)
Beilstein Journal of Organic Chemistry 8: 539-550.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
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Autor*in
Fraschetti, Caterina;
Letzel, MatthiasUniBi;
Filippi, Antonello;
Speranza, Maurizio;
Mattay, JochenUniBi
Einrichtung
Abstract / Bemerkung
This review describes the state-of-art in the field of the gas-phase reactivity of diastereomeric complexes formed between a chiral artificial receptor and a biologically active molecule. The presented experimental approach is a ligand-displacement reaction carried out in a nano ESI-FT-ICR instrument, supported by a thermodynamic MS-study and molecular-mechanics and molecular-dynamics (MM/MD) computational techniques. The noncovalent ion-molecule complexes are ideal for the study of chiral recognition in the absence of complicating solvent and counterion effects.
Stichworte
spectrometry;
resorcin[4] arene receptor;
gas phase enantioselectivity;
diastereomeric complexes;
kinetics;
mass
Erscheinungsjahr
2012
Zeitschriftentitel
Beilstein Journal of Organic Chemistry
Band
8
Seite(n)
539-550
ISSN
1860-5397
eISSN
1860-5397
Page URI
https://pub.uni-bielefeld.de/record/2501810
Zitieren
Fraschetti C, Letzel M, Filippi A, Speranza M, Mattay J. Enantioselective supramolecular devices in the gas phase. Resorcin[4] arene as a model system. Beilstein Journal of Organic Chemistry. 2012;8:539-550.
Fraschetti, C., Letzel, M., Filippi, A., Speranza, M., & Mattay, J. (2012). Enantioselective supramolecular devices in the gas phase. Resorcin[4] arene as a model system. Beilstein Journal of Organic Chemistry, 8, 539-550. doi:10.3762/bjoc.8.62
Fraschetti, Caterina, Letzel, Matthias, Filippi, Antonello, Speranza, Maurizio, and Mattay, Jochen. 2012. “Enantioselective supramolecular devices in the gas phase. Resorcin[4] arene as a model system”. Beilstein Journal of Organic Chemistry 8: 539-550.
Fraschetti, C., Letzel, M., Filippi, A., Speranza, M., and Mattay, J. (2012). Enantioselective supramolecular devices in the gas phase. Resorcin[4] arene as a model system. Beilstein Journal of Organic Chemistry 8, 539-550.
Fraschetti, C., et al., 2012. Enantioselective supramolecular devices in the gas phase. Resorcin[4] arene as a model system. Beilstein Journal of Organic Chemistry, 8, p 539-550.
C. Fraschetti, et al., “Enantioselective supramolecular devices in the gas phase. Resorcin[4] arene as a model system”, Beilstein Journal of Organic Chemistry, vol. 8, 2012, pp. 539-550.
Fraschetti, C., Letzel, M., Filippi, A., Speranza, M., Mattay, J.: Enantioselective supramolecular devices in the gas phase. Resorcin[4] arene as a model system. Beilstein Journal of Organic Chemistry. 8, 539-550 (2012).
Fraschetti, Caterina, Letzel, Matthias, Filippi, Antonello, Speranza, Maurizio, and Mattay, Jochen. “Enantioselective supramolecular devices in the gas phase. Resorcin[4] arene as a model system”. Beilstein Journal of Organic Chemistry 8 (2012): 539-550.
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