Silanetriols in the gas phase: single molecules vs. hydrogen-bonded dimers

Spirk S, Berger R, Reuter C, Pietschnig R, Mitzel NW (2012)
Dalton Transactions 41(13): 3630-3632.

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Abstract / Bemerkung
The first gas phase structure of a silanetriol, tert-butylsilanetriol [tBuSi(OH)(3)], determined by gas electron diffraction (GED), is reported. Quantum chemical calculations have been performed to elucidate potential intermolecular interactions between silanetriol molecules in the gas phase. The results are set into contrast to solid state structures of tBuSi(OH)(3) and related compounds.
Erscheinungsjahr
Zeitschriftentitel
Dalton Transactions
Band
41
Ausgabe
13
Seite(n)
3630-3632
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Spirk S, Berger R, Reuter C, Pietschnig R, Mitzel NW. Silanetriols in the gas phase: single molecules vs. hydrogen-bonded dimers. Dalton Transactions. 2012;41(13):3630-3632.
Spirk, S., Berger, R., Reuter, C., Pietschnig, R., & Mitzel, N. W. (2012). Silanetriols in the gas phase: single molecules vs. hydrogen-bonded dimers. Dalton Transactions, 41(13), 3630-3632. doi:10.1039/c1dt11740h
Spirk, S., Berger, R., Reuter, C., Pietschnig, R., and Mitzel, N. W. (2012). Silanetriols in the gas phase: single molecules vs. hydrogen-bonded dimers. Dalton Transactions 41, 3630-3632.
Spirk, S., et al., 2012. Silanetriols in the gas phase: single molecules vs. hydrogen-bonded dimers. Dalton Transactions, 41(13), p 3630-3632.
S. Spirk, et al., “Silanetriols in the gas phase: single molecules vs. hydrogen-bonded dimers”, Dalton Transactions, vol. 41, 2012, pp. 3630-3632.
Spirk, S., Berger, R., Reuter, C., Pietschnig, R., Mitzel, N.W.: Silanetriols in the gas phase: single molecules vs. hydrogen-bonded dimers. Dalton Transactions. 41, 3630-3632 (2012).
Spirk, Stefan, Berger, Raphael, Reuter, Christian, Pietschnig, Rudolf, and Mitzel, Norbert W. “Silanetriols in the gas phase: single molecules vs. hydrogen-bonded dimers”. Dalton Transactions 41.13 (2012): 3630-3632.

2 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Silanol-based surfactants: synthetic access and properties of an innovative class of environmentally benign detergents.
Hurkes N, Ehmann HM, List M, Spirk S, Bussiek M, Belaj F, Pietschnig R., Chemistry 20(30), 2014
PMID: 24986309
Silanetriols as Powerful Starting Materials for Selective Condensation to Bulky POSS Cages.
Hurkes N, Bruhn C, Belaj F, Pietschnig R., Organometallics 33(24), 2014
PMID: 25550679

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