Photoinduced cycloadditions and cyclizations. Mechanistic studies and synthetic applications
Mattay J, Albrecht E, Fagnoni M, Heidbreder A, Hintz S, Kirschberg T, Klessinger M, Mahlmann J, Schlachter I, Steenken S (1996)
JOURNAL OF INFORMATION RECORDING 23(1-2): 23-29.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
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Autor*in
Mattay, JochenUniBi;
Albrecht, E;
Fagnoni, M;
Heidbreder, A;
Hintz, S;
Kirschberg, T;
Klessinger, M;
Mahlmann, J;
Schlachter, I;
Steenken, S
Abstract / Bemerkung
Synthetic applications and mechanistic studies from three areas of photoinduced cycloadditions and cyclizations are reported: First it is shown that unsaturated silyl enol ethers preferentially cyclisize in a 6-endo mode via their photochemically generated radical cations. In the following chapter we discuss fragmentation-cyclization reactions of unsaturated alpha-cyclopropyl ketones by photoinduced electron transfer leading to polycyclic compounds. Finally a kinetic and theoretical study of [2+3] cycloadditions of nitrile ylides generated from 2H-azirines is presented.
Stichworte
cycloaddition;
cyclization;
C-C bond cleavage;
photoinduced electron transfer (PET);
radical ions;
nitrile ylides;
laser flash photolysis;
semiempirical calculations
Erscheinungsjahr
1996
Zeitschriftentitel
JOURNAL OF INFORMATION RECORDING
Band
23
Ausgabe
1-2
Seite(n)
23-29
ISSN
1025-6008
Page URI
https://pub.uni-bielefeld.de/record/2402621
Zitieren
Mattay J, Albrecht E, Fagnoni M, et al. Photoinduced cycloadditions and cyclizations. Mechanistic studies and synthetic applications. JOURNAL OF INFORMATION RECORDING. 1996;23(1-2):23-29.
Mattay, J., Albrecht, E., Fagnoni, M., Heidbreder, A., Hintz, S., Kirschberg, T., Klessinger, M., et al. (1996). Photoinduced cycloadditions and cyclizations. Mechanistic studies and synthetic applications. JOURNAL OF INFORMATION RECORDING, 23(1-2), 23-29.
Mattay, Jochen, Albrecht, E, Fagnoni, M, Heidbreder, A, Hintz, S, Kirschberg, T, Klessinger, M, Mahlmann, J, Schlachter, I, and Steenken, S. 1996. “Photoinduced cycloadditions and cyclizations. Mechanistic studies and synthetic applications”. JOURNAL OF INFORMATION RECORDING 23 (1-2): 23-29.
Mattay, J., Albrecht, E., Fagnoni, M., Heidbreder, A., Hintz, S., Kirschberg, T., Klessinger, M., Mahlmann, J., Schlachter, I., and Steenken, S. (1996). Photoinduced cycloadditions and cyclizations. Mechanistic studies and synthetic applications. JOURNAL OF INFORMATION RECORDING 23, 23-29.
Mattay, J., et al., 1996. Photoinduced cycloadditions and cyclizations. Mechanistic studies and synthetic applications. JOURNAL OF INFORMATION RECORDING, 23(1-2), p 23-29.
J. Mattay, et al., “Photoinduced cycloadditions and cyclizations. Mechanistic studies and synthetic applications”, JOURNAL OF INFORMATION RECORDING, vol. 23, 1996, pp. 23-29.
Mattay, J., Albrecht, E., Fagnoni, M., Heidbreder, A., Hintz, S., Kirschberg, T., Klessinger, M., Mahlmann, J., Schlachter, I., Steenken, S.: Photoinduced cycloadditions and cyclizations. Mechanistic studies and synthetic applications. JOURNAL OF INFORMATION RECORDING. 23, 23-29 (1996).
Mattay, Jochen, Albrecht, E, Fagnoni, M, Heidbreder, A, Hintz, S, Kirschberg, T, Klessinger, M, Mahlmann, J, Schlachter, I, and Steenken, S. “Photoinduced cycloadditions and cyclizations. Mechanistic studies and synthetic applications”. JOURNAL OF INFORMATION RECORDING 23.1-2 (1996): 23-29.
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