Functional Characterization of a Supramolecular Affinity Switch at the Single Molecule Level
Walhorn V, Schröder T, Mattay J, Anselmetti D (In Press)
Nanoscale 3(11): 4859-4865.
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Einrichtung
Centrum für Biotechnologie > Institut für Biophysik und Nanowissenschaften
Fakultät für Chemie > Industrielle Organische Chemie und Biotechnologie
Centrum für Biotechnologie > Institut für Biochemie und Biotechnik
Centrum für Biotechnologie > Arbeitsgruppe D. Anselmetti
Fakultät für Physik > AG Biophysik und angewandte Nanowissenschaften
Fakultät für Chemie > Industrielle Organische Chemie und Biotechnologie
Centrum für Biotechnologie > Institut für Biochemie und Biotechnik
Centrum für Biotechnologie > Arbeitsgruppe D. Anselmetti
Fakultät für Physik > AG Biophysik und angewandte Nanowissenschaften
Abstract / Bemerkung
Surface-immobilized and switchable resorcin[4]arene receptor molecules were quantitatively investigated with atomic force microscopy (AFM) and AFM-single molecule force spectroscopy (AFM-SMFS). The upper rim of the supramolecular receptor cavities was modified with two photodimerizable anthracene moieties. The molecular constitution can be externally switched and controlled by exposure to ultraviolet (UV) light and heat. The topography as well as the complexation affinity against small ammonium guest ions of the two isomers were investigated at the single molecule level. Our results demonstrate the feasibility to externally control the supramolecular receptor's affinity and simultaneously quantify and associate these binding properties with the structural change of the resorcin[4]arenes structure on the basis of the measured molecule corrugation height.
Erscheinungsjahr
2011
Zeitschriftentitel
Nanoscale
Band
3
Ausgabe
11
Seite(n)
4859-4865
ISSN
2040-3364
eISSN
2040-3372
Page URI
https://pub.uni-bielefeld.de/record/2315153
Zitieren
Walhorn V, Schröder T, Mattay J, Anselmetti D. Functional Characterization of a Supramolecular Affinity Switch at the Single Molecule Level. Nanoscale. In Press;3(11):4859-4865.
Walhorn, V., Schröder, T., Mattay, J., & Anselmetti, D. (In Press). Functional Characterization of a Supramolecular Affinity Switch at the Single Molecule Level. Nanoscale, 3(11), 4859-4865. https://doi.org/10.1039/C1NR10912J
Walhorn, Volker, Schröder, Tobias, Mattay, Jochen, and Anselmetti, Dario. In Press. “Functional Characterization of a Supramolecular Affinity Switch at the Single Molecule Level”. Nanoscale 3 (11): 4859-4865.
Walhorn, V., Schröder, T., Mattay, J., and Anselmetti, D. (In Press). Functional Characterization of a Supramolecular Affinity Switch at the Single Molecule Level. Nanoscale 3, 4859-4865.
Walhorn, V., et al., In Press. Functional Characterization of a Supramolecular Affinity Switch at the Single Molecule Level. Nanoscale, 3(11), p 4859-4865.
V. Walhorn, et al., “Functional Characterization of a Supramolecular Affinity Switch at the Single Molecule Level”, Nanoscale, vol. 3, In Press, pp. 4859-4865.
Walhorn, V., Schröder, T., Mattay, J., Anselmetti, D.: Functional Characterization of a Supramolecular Affinity Switch at the Single Molecule Level. Nanoscale. 3, 4859-4865 (In Press).
Walhorn, Volker, Schröder, Tobias, Mattay, Jochen, and Anselmetti, Dario. “Functional Characterization of a Supramolecular Affinity Switch at the Single Molecule Level”. Nanoscale 3.11 (In Press): 4859-4865.
Daten bereitgestellt von European Bioinformatics Institute (EBI)
5 Zitationen in Europe PMC
Daten bereitgestellt von Europe PubMed Central.
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