Gas uptake and chemical aging of semisolid organic aerosol particles

Shiraiwa M, Ammann M, Koop T, Poeschl U (2011)

Zeitschriftenaufsatz | Veröffentlicht | Englisch
Es wurden keine Dateien hochgeladen. Nur Publikationsnachweis!
Shiraiwa, Manabu; Ammann, Markus; Koop, ThomasUniBi ; Poeschl, Ulrich
Abstract / Bemerkung
Organic substances can adopt an amorphous solid or semisolid state, influencing the rate of heterogeneous reactions and multiphase processes in atmospheric aerosols. Here we demonstrate how molecular diffusion in the condensed phase affects the gas uptake and chemical transformation of semisolid organic particles. Flow tube experiments show that the ozone uptake and oxidative aging of amorphous protein is kinetically limited by bulk diffusion. The reactive gas uptake exhibits a pronounced increase with relative humidity, which can be explained by a decrease of viscosity and increase of diffusivity due to hygroscopic water uptake transforming the amorphous organic matrix from a glassy to a semisolid state (moisture-induced phase transition). The reaction rate depends on the condensed phase diffusion coefficients of both the oxidant and the organic reactant molecules, which can be described by a kinetic multilayer flux model but not by the traditional resistor model approach of multiphase chemistry. The chemical lifetime of reactive compounds in atmospheric particles can increase from seconds to days as the rate of diffusion in semisolid phases can decrease by multiple orders of magnitude in response to low temperature or low relative humidity. The findings demonstrate that the occurrence and properties of amorphous semisolid phases challenge traditional views and require advanced formalisms for the description of organic particle formation and transformation in atmospheric models of aerosol effects on air quality, public health, and climate.
ozonolysis; aerosol partitioning; secondary organic; Stokes-Einstein; percolation theory; glass transition
Page URI


Shiraiwa M, Ammann M, Koop T, Poeschl U. Gas uptake and chemical aging of semisolid organic aerosol particles. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES. 2011;108(27):11003-11008.
Shiraiwa, M., Ammann, M., Koop, T., & Poeschl, U. (2011). Gas uptake and chemical aging of semisolid organic aerosol particles. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES, 108(27), 11003-11008.
Shiraiwa, Manabu, Ammann, Markus, Koop, Thomas, and Poeschl, Ulrich. 2011. “Gas uptake and chemical aging of semisolid organic aerosol particles”. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES 108 (27): 11003-11008.
Shiraiwa, M., Ammann, M., Koop, T., and Poeschl, U. (2011). Gas uptake and chemical aging of semisolid organic aerosol particles. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES 108, 11003-11008.
Shiraiwa, M., et al., 2011. Gas uptake and chemical aging of semisolid organic aerosol particles. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES, 108(27), p 11003-11008.
M. Shiraiwa, et al., “Gas uptake and chemical aging of semisolid organic aerosol particles”, PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES, vol. 108, 2011, pp. 11003-11008.
Shiraiwa, M., Ammann, M., Koop, T., Poeschl, U.: Gas uptake and chemical aging of semisolid organic aerosol particles. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES. 108, 11003-11008 (2011).
Shiraiwa, Manabu, Ammann, Markus, Koop, Thomas, and Poeschl, Ulrich. “Gas uptake and chemical aging of semisolid organic aerosol particles”. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES 108.27 (2011): 11003-11008.

68 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Highly Viscous States Affect the Browning of Atmospheric Organic Particulate Matter.
Liu P, Li YJ, Wang Y, Bateman AP, Zhang Y, Gong Z, Bertram AK, Martin ST., ACS Cent Sci 4(2), 2018
PMID: 29532020
The viscosity of atmospherically relevant organic particles.
Reid JP, Bertram AK, Topping DO, Laskin A, Martin ST, Petters MD, Pope FD, Rovelli G., Nat Commun 9(1), 2018
PMID: 29511168
Temperature effect on phase state and reactivity controls atmospheric multiphase chemistry and transport of PAHs.
Mu Q, Shiraiwa M, Octaviani M, Ma N, Ding A, Su H, Lammel G, Pöschl U, Cheng Y., Sci Adv 4(3), 2018
PMID: 29750188
Amorphous phase state diagrams and viscosity of ternary aqueous organic/organic and inorganic/organic mixtures.
Marsh A, Petters SS, Rothfuss NE, Rovelli G, Song YC, Reid JP, Petters MD., Phys Chem Chem Phys 20(22), 2018
PMID: 29796502
Influence of particle viscosity on mass transfer and heterogeneous ozonolysis kinetics in aqueous-sucrose-maleic acid aerosol.
Marshall FH, Berkemeier T, Shiraiwa M, Nandy L, Ohm PB, Dutcher CS, Reid JP., Phys Chem Chem Phys 20(22), 2018
PMID: 29808874
Kinetics, mechanisms and ionic liquids in the uptake of n-butylamine onto low molecular weight dicarboxylic acids.
Fairhurst MC, Ezell MJ, Kidd C, Lakey PS, Shiraiwa M, Finlayson-Pitts BJ., Phys Chem Chem Phys 19(6), 2017
PMID: 28133655
Diffusive confinement of free radical intermediates in the OH radical oxidation of semisolid aerosols.
Wiegel AA, Liu MJ, Hinsberg WD, Wilson KR, Houle FA., Phys Chem Chem Phys 19(9), 2017
PMID: 28218326
Air Pollution and Climate Change Effects on Allergies in the Anthropocene: Abundance, Interaction, and Modification of Allergens and Adjuvants.
Reinmuth-Selzle K, Kampf CJ, Lucas K, Lang-Yona N, Fröhlich-Nowoisky J, Shiraiwa M, Lakey PSJ, Lai S, Liu F, Kunert AT, Ziegler K, Shen F, Sgarbanti R, Weber B, Bellinghausen I, Saloga J, Weller MG, Duschl A, Schuppan D, Pöschl U., Environ Sci Technol 51(8), 2017
PMID: 28326768
Global distribution of particle phase state in atmospheric secondary organic aerosols.
Shiraiwa M, Li Y, Tsimpidi AP, Karydis VA, Berkemeier T, Pandis SN, Lelieveld J, Koop T, Pöschl U., Nat Commun 8(), 2017
PMID: 28429776
Atmospheric protein chemistry influenced by anthropogenic air pollutants: nitration and oligomerization upon exposure to ozone and nitrogen dioxide.
Liu F, Lakey PSJ, Berkemeier T, Tong H, Kunert AT, Meusel H, Cheng Y, Su H, Fröhlich-Nowoisky J, Lai S, Weller MG, Shiraiwa M, Pöschl U, Kampf CJ., Faraday Discuss 200(), 2017
PMID: 28574569
Accurate representations of the physicochemical properties of atmospheric aerosols: when are laboratory measurements of value?
Marsh A, Rovelli G, Song YC, Pereira KL, Willoughby RE, Bzdek BR, Hamilton JF, Orr-Ewing AJ, Topping DO, Reid JP., Faraday Discuss 200(), 2017
PMID: 28574570
Introductory lecture: atmospheric chemistry in the Anthropocene.
Finlayson-Pitts BJ., Faraday Discuss 200(), 2017
PMID: 28686249
Knudsen cell studies of the uptake of gaseous ammonia and amines onto C3-C7 solid dicarboxylic acids.
Fairhurst MC, Ezell MJ, Finlayson-Pitts BJ., Phys Chem Chem Phys 19(38), 2017
PMID: 28936531
An update of the Worldwide Integrated Assessment (WIA) on systemic insecticides. Part 1: new molecules, metabolism, fate, and transport.
Giorio C, Safer A, Sánchez-Bayo F, Tapparo A, Lentola A, Girolami V, van Lexmond MB, Bonmatin JM., Environ Sci Pollut Res Int (), 2017
PMID: 29105037
Complex three-dimensional self-assembly in proxies for atmospheric aerosols.
Pfrang C, Rastogi K, Cabrera-Martinez ER, Seddon AM, Dicko C, Labrador A, Plivelic TS, Cowieson N, Squires AM., Nat Commun 8(1), 2017
PMID: 29170428
Diffusion and reactivity in ultraviscous aerosol and the correlation with particle viscosity.
Marshall FH, Miles REH, Song YC, Ohm PB, Power RM, Reid JP, Dutcher CS., Chem Sci 7(2), 2016
PMID: 29910887
Direct imaging of changes in aerosol particle viscosity upon hydration and chemical aging.
Hosny NA, Fitzgerald C, Vyšniauskas A, Athanasiadis A, Berkemeier T, Uygur N, Pöschl U, Shiraiwa M, Kalberer M, Pope FD, Kuimova MK., Chem Sci 7(2), 2016
PMID: 29910892
Effect of viscosity on photodegradation rates in complex secondary organic aerosol materials.
Hinks ML, Brady MV, Lignell H, Song M, Grayson JW, Bertram AK, Lin P, Laskin A, Laskin J, Nizkorodov SA., Phys Chem Chem Phys 18(13), 2016
PMID: 26685987
Ozone uptake on glassy, semi-solid and liquid organic matter and the role of reactive oxygen intermediates in atmospheric aerosol chemistry.
Berkemeier T, Steimer SS, Krieger UK, Peter T, Pöschl U, Ammann M, Shiraiwa M., Phys Chem Chem Phys 18(18), 2016
PMID: 27095585
Fluorescence lifetime imaging of optically levitated aerosol: a technique to quantitatively map the viscosity of suspended aerosol particles.
Fitzgerald C, Hosny NA, Tong H, Seville PC, Gallimore PJ, Davidson NM, Athanasiadis A, Botchway SW, Ward AD, Kalberer M, Kuimova MK, Pope FD., Phys Chem Chem Phys 18(31), 2016
PMID: 27430158
Mixing of secondary organic aerosols versus relative humidity.
Ye Q, Robinson ES, Ding X, Ye P, Sullivan RC, Donahue NM., Proc Natl Acad Sci U S A 113(45), 2016
PMID: 27791066
Dynamic viscosity mapping of the oxidation of squalene aerosol particles.
Athanasiadis A, Fitzgerald C, Davidson NM, Giorio C, Botchway SW, Ward AD, Kalberer M, Pope FD, Kuimova MK., Phys Chem Chem Phys 18(44), 2016
PMID: 27781216
Size dependence of phase transitions in aerosol nanoparticles.
Cheng Y, Su H, Koop T, Mikhailov E, Pöschl U., Nat Commun 6(), 2015
PMID: 25586967
Oxidation of a model alkane aerosol by OH radical: the emergent nature of reactive uptake.
Houle FA, Hinsberg WD, Wilson KR., Phys Chem Chem Phys 17(6), 2015
PMID: 25578745
Heterogeneous photochemistry in the atmosphere.
George C, Ammann M, D'Anna B, Donaldson DJ, Nizkorodov SA., Chem Rev 115(10), 2015
PMID: 25775235
Variabilities and uncertainties in characterising water transport kinetics in glassy and ultraviscous aerosol.
Rickards AM, Song YC, Miles RE, Preston TC, Reid JP., Phys Chem Chem Phys 17(15), 2015
PMID: 25786190
Role of the reaction of stabilized Criegee intermediates with peroxy radicals in particle formation and growth in air.
Zhao Y, Wingen LM, Perraud V, Greaves J, Finlayson-Pitts BJ., Phys Chem Chem Phys 17(19), 2015
PMID: 25899614
Water diffusion in atmospherically relevant α-pinene secondary organic material.
Price HC, Mattsson J, Zhang Y, Bertram AK, Davies JF, Grayson JW, Martin ST, O'Sullivan D, Reid JP, Rickards AMJ, Murray BJ., Chem Sci 6(8), 2015
PMID: 28717493
Shikimic acid ozonolysis kinetics of the transition from liquid aqueous solution to highly viscous glass.
Steimer SS, Berkemeier T, Gilgen A, Krieger UK, Peter T, Shiraiwa M, Ammann M., Phys Chem Chem Phys 17(46), 2015
PMID: 26536455
Timescales of water transport in viscous aerosol: measurements on sub-micron particles and dependence on conditioning history.
Lu JW, Rickards AM, Walker JS, Knox KJ, Miles RE, Reid JP, Signorell R., Phys Chem Chem Phys 16(21), 2014
PMID: 24316593
Nitration of the birch pollen allergen Bet v 1.0101: efficiency and site-selectivity of liquid and gaseous nitrating agents.
Reinmuth-Selzle K, Ackaert C, Kampf CJ, Samonig M, Shiraiwa M, Kofler S, Yang H, Gadermaier G, Brandstetter H, Huber CG, Duschl A, Oostingh GJ, Pöschl U., J Proteome Res 13(3), 2014
PMID: 24517313
Integrating phase and composition of secondary organic aerosol from the ozonolysis of α-pinene.
Kidd C, Perraud V, Wingen LM, Finlayson-Pitts BJ., Proc Natl Acad Sci U S A 111(21), 2014
PMID: 24821796
Exploring matrix effects on photochemistry of organic aerosols.
Lignell H, Hinks ML, Nizkorodov SA., Proc Natl Acad Sci U S A 111(38), 2014
PMID: 25201953
Fluorescent lifetime imaging of atmospheric aerosols: a direct probe of aerosol viscosity.
Hosny NA, Fitzgerald C, Tong C, Kalberer M, Kuimova MK, Pope FD., Faraday Discuss 165(), 2013
PMID: 24601010
Kinetic limitations in gas-particle reactions arising from slow diffusion in secondary organic aerosol.
Zhou S, Shiraiwa M, McWhinney RD, Pöschl U, Abbatt JP., Faraday Discuss 165(), 2013
PMID: 24601014
Experimental determination of chemical diffusion within secondary organic aerosol particles.
Abramson E, Imre D, Beránek J, Wilson J, Zelenyuk A., Phys Chem Chem Phys 15(8), 2013
PMID: 23340901
Multiphase chemistry of atmospheric amines.
Qiu C, Zhang R., Phys Chem Chem Phys 15(16), 2013
PMID: 23443488
Viscosity of α-pinene secondary organic material and implications for particle growth and reactivity.
Renbaum-Wolff L, Grayson JW, Bateman AP, Kuwata M, Sellier M, Murray BJ, Shilling JE, Martin ST, Bertram AK., Proc Natl Acad Sci U S A 110(20), 2013
PMID: 23620520
Influence of organic films on the evaporation and condensation of water in aerosol.
Davies JF, Miles RE, Haddrell AE, Reid JP., Proc Natl Acad Sci U S A 110(22), 2013
PMID: 23674675
Gas-particle partitioning of atmospheric aerosols: interplay of physical state, non-ideal mixing and morphology.
Shiraiwa M, Zuend A, Bertram AK, Seinfeld JH., Phys Chem Chem Phys 15(27), 2013
PMID: 23748935
Size distribution dynamics reveal particle-phase chemistry in organic aerosol formation.
Shiraiwa M, Yee LD, Schilling KA, Loza CL, Craven JS, Zuend A, Ziemann PJ, Seinfeld JH., Proc Natl Acad Sci U S A 110(29), 2013
PMID: 23818634
Formation of nitro-PAHs from the heterogeneous reaction of ambient particle-bound PAHs with N2O5/NO3/NO2.
Zimmermann K, Jariyasopit N, Massey Simonich SL, Tao S, Atkinson R, Arey J., Environ Sci Technol 47(15), 2013
PMID: 23865889
Retrieval of the complex refractive index of aerosol droplets from optical tweezers measurements.
Miles RE, Walker JS, Burnham DR, Reid JP., Phys Chem Chem Phys 14(9), 2012
PMID: 22286506
Nonequilibrium atmospheric secondary organic aerosol formation and growth.
Perraud V, Bruns EA, Ezell MJ, Johnson SN, Yu Y, Alexander ML, Zelenyuk A, Imre D, Chang WL, Dabdub D, Pankow JF, Finlayson-Pitts BJ., Proc Natl Acad Sci U S A 109(8), 2012
PMID: 22308444
Chemistry and composition of atmospheric aerosol particles.
Kolb CE, Worsnop DR., Annu Rev Phys Chem 63(), 2012
PMID: 22404591
Comparing the mechanism of water condensation and evaporation in glassy aerosol.
Bones DL, Reid JP, Lienhard DM, Krieger UK., Proc Natl Acad Sci U S A 109(29), 2012
PMID: 22753520
Biogenic potassium salt particles as seeds for secondary organic aerosol in the Amazon.
Pöhlker C, Wiedemann KT, Sinha B, Shiraiwa M, Gunthe SS, Smith M, Su H, Artaxo P, Chen Q, Cheng Y, Elbert W, Gilles MK, Kilcoyne AL, Moffet RC, Weigand M, Martin ST, Pöschl U, Andreae MO., Science 337(6098), 2012
PMID: 22936773
Kinetics, products, and mechanisms of secondary organic aerosol formation.
Ziemann PJ, Atkinson R., Chem Soc Rev 41(19), 2012
PMID: 22940672
Phase of atmospheric secondary organic material affects its reactivity.
Kuwata M, Martin ST., Proc Natl Acad Sci U S A 109(43), 2012
PMID: 23045632
Changes in fluorescence spectra of bioaerosols exposed to ozone in a laboratory reaction chamber to simulate atmospheric aging.
Santarpia JL, Pan YL, Hill SC, Baker N, Cottrell B, McKee L, Ratnesar-Shumate S, Pinnick RG., Opt Express 20(28), 2012
PMID: 23388813
Heterogeneous oxidation kinetics of organic biomass burning aerosol surrogates by O3, NO2, N2O5, and NO3.
Knopf DA, Forrester SM, Slade JH., Phys Chem Chem Phys 13(47), 2011
PMID: 22020363

71 References

Daten bereitgestellt von Europe PubMed Central.

Atmospheric aerosols: Composition, transformation, climate and health effects
Pöschl U., 2005

Atmospheric chemistry.
Finlayson-Pitts BJ., Proc. Natl. Acad. Sci. U.S.A. 107(15), 2010
PMID: 20388910
Aerosol-cloud-precipitation interactions. Part 1. The nature and sources of cloud-active aerosols
Andreae MO, Rosenfeld D., 2008
Critical assessment of the current state of scientific knowledge, terminology, and research needs concerning the role of organic aerosols in the atmosphere, climate, and global change
Fuzzi S., 2006
Heterogeneous production of nitrous acid on soot in polluted air masses
Ammann M., 1998
Light changes the atmospheric reactivity of soot.
Monge ME, D'Anna B, Mazri L, Giroir-Fendler A, Ammann M, Donaldson DJ, George C., Proc. Natl. Acad. Sci. U.S.A. 107(15), 2010
PMID: 20080580
Rainforest aerosols as biogenic nuclei of clouds and precipitation in the Amazon.
Poschl U, Martin ST, Sinha B, Chen Q, Gunthe SS, Huffman JA, Borrmann S, Farmer DK, Garland RM, Helas G, Jimenez JL, King SM, Manzi A, Mikhailov E, Pauliquevis T, Petters MD, Prenni AJ, Roldin P, Rose D, Schneider J, Su H, Zorn SR, Artaxo P, Andreae MO., Science 329(5998), 2010
PMID: 20847268
Rapid aerosol particle growth and increase of cloud condensation nucleus activity by secondary aerosol formation and condensation: a case study for regional air pollution in northeastern China
Wiedensohler A., 2009
Radiative impact of mixing state of black carbon aerosol in Asian outflow
Shiraiwa M., 2008
The role of long-lived reactive oxygen intermediates in the reaction of ozone with aerosol particles.
Shiraiwa M, Sosedova Y, Rouviere A, Yang H, Zhang Y, Abbatt JP, Ammann M, Poschl U., Nat Chem 3(4), 2011
PMID: 21430687
Acidity enhances the formation of a persistent ozonide at aqueous ascorbate/ozone gas interfaces.
Enami S, Hoffmann MR, Colussi AJ., Proc. Natl. Acad. Sci. U.S.A. 105(21), 2008
PMID: 18487455
Surface-specific reactions on liquids
Hanson DR., 1997
Mass-transport limitation to the rate of reaction of gases in liquid droplets—Application to oxidation of SO in aqueous-solutions
Schwartz SE, Freiberg JE., 1981
Aerosol uptake described by numerical solution of the diffusion—Reaction equations in the particle
Smith GD, Woods E, Baer T, Miller RE., 2003
Kinetic model framework for aerosol and cloud surface chemistry and gas-particle interactions—Part 2: exemplary practical applications and numerical simulations
Ammann M, Pöschl U., 2007
Evolution of organic aerosols in the atmosphere.
Jimenez JL, Canagaratna MR, Donahue NM, Prevot AS, Zhang Q, Kroll JH, DeCarlo PF, Allan JD, Coe H, Ng NL, Aiken AC, Docherty KS, Ulbrich IM, Grieshop AP, Robinson AL, Duplissy J, Smith JD, Wilson KR, Lanz VA, Hueglin C, Sun YL, Tian J, Laaksonen A, Raatikainen T, Rautiainen J, Vaattovaara P, Ehn M, Kulmala M, Tomlinson JM, Collins DR, Cubison MJ, Dunlea EJ, Huffman JA, Onasch TB, Alfarra MR, Williams PI, Bower K, Kondo Y, Schneider J, Drewnick F, Borrmann S, Weimer S, Demerjian K, Salcedo D, Cottrell L, Griffin R, Takami A, Miyoshi T, Hatakeyama S, Shimono A, Sun JY, Zhang YM, Dzepina K, Kimmel JR, Sueper D, Jayne JT, Herndon SC, Trimborn AM, Williams LR, Wood EC, Middlebrook AM, Kolb CE, Baltensperger U, Worsnop DR., Science 326(5959), 2009
PMID: 20007897
Organic aerosol growth mechanisms and their climate-forcing implications.
Maria SF, Russell LM, Gilles MK, Myneni SC., Science 306(5703), 2004
PMID: 15591199
Carbon oxidation state as a metric for describing the chemistry of atmospheric organic aerosol.
Kroll JH, Donahue NM, Jimenez JL, Kessler SH, Canagaratna MR, Wilson KR, Altieri KE, Mazzoleni LR, Wozniak AS, Bluhm H, Mysak ER, Smith JD, Kolb CE, Worsnop DR., Nat Chem 3(2), 2011
PMID: 21258386
Phase Transitions of Aqueous Atmospheric Particles.
Martin ST., Chem. Rev. 100(9), 2000
PMID: 11777428
Mixing of the organic aerosol fractions: liquids as the thermodynamically stable phases
Marcolli C, Luo BP, Peter T., 2004
Black carbon or brown carbon? The nature of light-absorbing carbonaceous aerosols
Andreae MO, Gelencser A., 2006
Kinetic double-layer model of aerosol surface chemistry and gas-particle interactions (K2-SURF): degradation of polycyclic aromatic hydrocarbons exposed to O, NO, HO, OH and NO
Shiraiwa M, Garland RM, Pöschl U., 2009
Raman microspectroscopy of soot and related carbonaceous materials: spectral analysis and structural information
Sadezky A, Muckenhuber H, Grothe H, Niessner R, Pöschl U., 2005
The formation, properties and impact of secondary organic aerosol: current and emerging issues
Hallquist M., 2009
Organic aerosol and global climate modelling: a review
Kanakidou M., 2005
An absorption-model of the gas aerosol partitioning involved in the formation of secondary organic aerosol
Pankow JF., 1994
An amorphous solid state of biogenic secondary organic aerosol particles.
Virtanen A, Joutsensaari J, Koop T, Kannosto J, Yli-Pirila P, Leskinen J, Makela JM, Holopainen JK, Poschl U, Kulmala M, Worsnop DR, Laaksonen A., Nature 467(7317), 2010
PMID: 20944744
Identification of polymers as major components of atmospheric organic aerosols.
Kalberer M, Paulsen D, Sax M, Steinbacher M, Dommen J, Prevot AS, Fisseha R, Weingartner E, Frankevich V, Zenobi R, Baltensperger U., Science 303(5664), 2004
PMID: 15016998
Identifying organic aerosol sources by comparing functional group composition in chamber and atmospheric particles.
Russell LM, Bahadur R, Ziemann PJ., Proc. Natl. Acad. Sci. U.S.A. 108(9), 2011
PMID: 21317360
Amorphous and crystalline aerosol particles interacting with water vapor: conceptual framework and experimental evidence for restructuring, phase transitions and kinetic limitations
Mikhailov E, Vlasenko S, Martin ST, Koop T, Pöschl U., 2009
Do atmospheric aerosols form glasses?
Zobrist B, Marcolli C, Pedernera DA, Koop T., 2008
Inhibition of ice crystallization in highly viscous aqueous organic acid droplets
Murray BJ., 2008
Formation of glasses from liquids and biopolymers.
Angell CA., Science 267(5206), 1995
PMID: 17770101
Little evidence for dynamic divergences in ultraviscous molecular liquids
Hecksher T, Nielsen AI, Olsen NB, Dyre JC., 2008

Bird RB, Stewart WE, Lightfoot EN., 2007
The uptake of acidic gases on ice.
Huthwelker T, Ammann M, Peter T., Chem. Rev. 106(4), 2006
PMID: 16608185
Diffusion in maltose-water mixtures at temperatures close to the glass-tranition
Parker R, Ring SG., 1995
Diffusivity of ozone in Wwater
Johnson PN, Davis RA., 1996

Seinfeld JH, Pandis SN., 1998
Kinetic multi-layer model of aerosol surface and bulk chemistry (KM-SUB): the influence of interfacial transport and bulk diffusion on the oxidation of oleic acid by ozone
Shiraiwa M, Pfrang C, Pöschl U., 2010
Ultra-slow water diffusion in aqueous sucrose glasses.
Zobrist B, Soonsin V, Luo BP, Krieger UK, Marcolli C, Peter T, Koop T., Phys Chem Chem Phys 13(8), 2011
PMID: 21229162
Measurements of the timescales for the mass transfer of water in glassy aerosol at low relative humidity and ambient temperature
Tong HJ, Reid JP, Bones DL, Luo BP, Krieger UK., 2011
Thermophysical properties of aqueous and frozen states of BSA/water/Tris systems.
Hottot A, Daoussi R, Andrieu J., Int. J. Biol. Macromol. 38(3-5), 2006
PMID: 16616363
The glass transition behavior of the globular protein bovine serum albumin.
Brownsey GJ, Noel TR, Parker R, Ring SG., Biophys. J. 85(6), 2003
PMID: 14645083
Interaction of aerosol particles composed of protein and salts with water vapor: hygroscopic growth and microstructural rearrangement
Mikhailov E, Vlasenko S, Niessner R, Pöschl U., 2004
Introduction to percolation theory
Shante VKS, Kirkpatrick S., 1971
A chemical kinetic model for reactive transformations of aerosol particles
Worsnop DR, Morris JW, Shi Q, Davidovits P, Kolb CE., 2002

Coupling aerosol surface and bulk chemistry with a kinetic double layer model (K2-SUB): an exemplary study of the oxidation of oleic acid by ozone
Pfrang C, Shiraiwa M, Pöschl U., 2010
Kinetic model framework for aerosol and cloud surface chemistry and gas-particle interactions—Part 1: General equations, parameters, and terminology
Pöschl U, Rudich Y, Ammann M., 2007
An overview of current issues in the uptake of atmospheric trace gases by aerosols and clouds
Kolb CE., 2010
Analytical description of gas transport across an interface with coupled diffusion in two phases
Huthwelker T, Peter T., 1996
Absorption by simultaneous diffusion and chemical reaction into particles of various shapes and into falling drops
Danckwerts PV., 1951
General trends for bulk diffusion in ice and surface diffusion on ice
Livingston FE, Smith JA, George SM., 2002
Reactive uptake of O3 by multicomponent and multiphase mixtures containing oleic acid.
Knopf DA, Anthony LM, Bertram AK., J Phys Chem A 109(25), 2005
PMID: 16833889
The oleic acid-ozone heterogeneous reaction system: products, kinetics, secondary chemistry, and atmospheric implications of a model system—a review
Zahardis J, Petrucci GA., 2007
Coupled partitioning, dilution, and chemical aging of semivolatile organics
Donahue NM, Robinson AL, Stanier CO, Pandis SN., 2006
Rethinking organic aerosols: semivolatile emissions and photochemical aging.
Robinson AL, Donahue NM, Shrivastava MK, Weitkamp EA, Sage AM, Grieshop AP, Lane TE, Pierce JR, Pandis SN., Science 315(5816), 2007
PMID: 17332409
Computation of liquid-liquid equilibria and phase stabilities: implications for RH-dependent gas/particle partitioning of organic-inorganic aerosols
Zuend A, Marcolli C, Peter T, Seinfeld JH., 2010
Evaporation kinetics and phase of laboratory and ambient secondary organic aerosol.
Vaden TD, Imre D, Beranek J, Shrivastava M, Zelenyuk A., Proc. Natl. Acad. Sci. U.S.A. 108(6), 2011
PMID: 21262848
Intercomparison of cloud condensation nuclei and hygroscopic fraction measurements: coated soot particles investigated during the LACIS Experiment in November (LExNo)
Snider JR., 2010
Sensitivity of the global distribution of cirrus ice crystal concentration to heterogeneous freezing
Barahona D, Rodriguez J, Nenes A., 2010
Gas-particle interactions of tropospheric aerosols: kinetic and thermodynamic perspectives of multiphase chemical reactions, amorphous organic substances, and the activation of cloud condensation nuclei
Pöschl U., 2011
Heterogeneous nucleation of ice particles on glassy aerosols under cirrus conditions
Murray BJ., 2010
Analyses of mass-transfer in hemodialyzers for laminar blood-flow and homogeneous dialysate
Cooney DO, Kim SS, Davis EJ., 1974
Nitrogen dioxide multiphase chemistry: uptake kinetics on aqueous solutions containing phenolic compounds.
Ammann M, Rossler E, Strekowski R, George C., Phys Chem Chem Phys 7(12), 2005
PMID: 15962037

Markieren/ Markierung löschen
Markierte Publikationen

Open Data PUB

Web of Science

Dieser Datensatz im Web of Science®

PMID: 21690350
PubMed | Europe PMC

Suchen in

Google Scholar