Giant polyoxomolybdates : syntheses, structure and stability studies : from syntheses of extended structures to novel host design, stability investigations in solution and perspectives for a future mechanistic study

Roy S (2005)
Bielefeld (Germany): Bielefeld University.

Bielefelder E-Dissertation | Englisch
 
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Autor*in
Roy, Soumyajit
Betreuer*in
Müller, Achim
Abstract / Bemerkung
In this dissertation investigation of one of the existing ring-shaped polyoxomolybdates led to the formation of extended structures and alluded to their potential host functionalities. After realizing such potentials in ring-shaped as well as in spherical giant polyoxomolybdates, and studying the structure of water inside the spherical capsules, this dissertation investigated the stability of some selected spherical polyoxomolybdates in aqueous solution. From this study sites vulnerable to "attack" by degrading agents and hence responsible for their decomposition were proposed and also the role of cations in stabilizing these clusters emerged. The dissertation concludes with a perspective for some open questions regarding the generation of the giant polyoxomolybdates from an ionic soup.
Stichworte
Polyoxomolybdate; Kristallwachstum; Wirt-Gast-Beziehung; Polyoxomolybdates; Extended structures; Host-guest chemistry; Stability studies
Jahr
2005
Page URI
https://pub.uni-bielefeld.de/record/2305249

Zitieren

Roy S. Giant polyoxomolybdates : syntheses, structure and stability studies : from syntheses of extended structures to novel host design, stability investigations in solution and perspectives for a future mechanistic study. Bielefeld (Germany): Bielefeld University; 2005.
Roy, S. (2005). Giant polyoxomolybdates : syntheses, structure and stability studies : from syntheses of extended structures to novel host design, stability investigations in solution and perspectives for a future mechanistic study. Bielefeld (Germany): Bielefeld University.
Roy, S. (2005). Giant polyoxomolybdates : syntheses, structure and stability studies : from syntheses of extended structures to novel host design, stability investigations in solution and perspectives for a future mechanistic study. Bielefeld (Germany): Bielefeld University.
Roy, S., 2005. Giant polyoxomolybdates : syntheses, structure and stability studies : from syntheses of extended structures to novel host design, stability investigations in solution and perspectives for a future mechanistic study, Bielefeld (Germany): Bielefeld University.
S. Roy, Giant polyoxomolybdates : syntheses, structure and stability studies : from syntheses of extended structures to novel host design, stability investigations in solution and perspectives for a future mechanistic study, Bielefeld (Germany): Bielefeld University, 2005.
Roy, S.: Giant polyoxomolybdates : syntheses, structure and stability studies : from syntheses of extended structures to novel host design, stability investigations in solution and perspectives for a future mechanistic study. Bielefeld University, Bielefeld (Germany) (2005).
Roy, Soumyajit. Giant polyoxomolybdates : syntheses, structure and stability studies : from syntheses of extended structures to novel host design, stability investigations in solution and perspectives for a future mechanistic study. Bielefeld (Germany): Bielefeld University, 2005.
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2019-09-06T08:57:48Z
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