Synthesis and Some Chemical Properties of a 1,2 lambda(3)sigma(3)-Thiaphosphirane
A rare example of the addition of sulfur to a phosphaalkene double bond leading to 1,2 lambda(3),sigma(3)-thiaphosphirane 4 is described. The relative accessibility of this compound has allowed the study of some of the chemical properties of the thiaphosphirane ring. The thermodynamic stability of 1,2 lambda(3),s(3)-thiaphosphiranes compared with lambda(5),sigma(3)-phosphoranes has been studied by DFT calculations.
2011
11
1762-1767
1762-1767
Wiley-Blackwell