Characterization of polybutadiene-poly(ethyleneoxide) aggregates in aqueous solution: A light-scattering and small-angle neutron-scattering study
Fuetterer T, Nordskog A, Hellweg T, Findenegg GH, Foerster S, Dewhurst CD (2004)
Physical Review E 70(4): 41408.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
Download
Es wurden keine Dateien hochgeladen. Nur Publikationsnachweis!
Autor*in
Fuetterer, T;
Nordskog, A;
Hellweg, ThomasUniBi 
;
Findenegg, GH;
Foerster, S;
Dewhurst, CD
;
Findenegg, GH;
Foerster, S;
Dewhurst, CDAbstract / Bemerkung
For diblockcopolymers of polybutadiene-poly(ethyleneoxide) (PB-PEO) type, water is a selective solvent. In dependence of the length of both blocks and the block length ratio, these polymers form a multitude of self-assembled structures in solution. In the present work scattering methods are used to investigate the water-soluble polymer PB125-PEO155. It is found to form long rodlike micelles, which are characterized with respect to the aggregate length L, the cross sectional radius R-CS, the radial scattering length density profile sigma(r), and the radial aggregation number N-rad. Model-independent as well as model-based approaches are used for the scattering data analysis. From dynamic light scattering (DLS) and static light scattering (SLS) experiments the weight averaged length L-w of these stiff elongated aggregates is determined to L-w=350 nm. Small angle neutron scattering (SANS) reveals a cross sectional radius of R-CS = 17 nm and in combination with results from the SLS the radial aggregation number is found to be N-rad=70.
Erscheinungsjahr
2004
Zeitschriftentitel
Physical Review E
Band
70
Ausgabe
4
Art.-Nr.
41408
ISSN
1539-3755
eISSN
1550-2376
Page URI
https://pub.uni-bielefeld.de/record/2000165
Zitieren
Fuetterer T, Nordskog A, Hellweg T, Findenegg GH, Foerster S, Dewhurst CD. Characterization of polybutadiene-poly(ethyleneoxide) aggregates in aqueous solution: A light-scattering and small-angle neutron-scattering study. Physical Review E. 2004;70(4): 41408.
Fuetterer, T., Nordskog, A., Hellweg, T., Findenegg, G. H., Foerster, S., & Dewhurst, C. D. (2004). Characterization of polybutadiene-poly(ethyleneoxide) aggregates in aqueous solution: A light-scattering and small-angle neutron-scattering study. Physical Review E, 70(4), 41408. https://doi.org/10.1103/PhysRevE.70.041408
Fuetterer, T, Nordskog, A, Hellweg, Thomas, Findenegg, GH, Foerster, S, and Dewhurst, CD. 2004. “Characterization of polybutadiene-poly(ethyleneoxide) aggregates in aqueous solution: A light-scattering and small-angle neutron-scattering study”. Physical Review E 70 (4): 41408.
Fuetterer, T., Nordskog, A., Hellweg, T., Findenegg, G. H., Foerster, S., and Dewhurst, C. D. (2004). Characterization of polybutadiene-poly(ethyleneoxide) aggregates in aqueous solution: A light-scattering and small-angle neutron-scattering study. Physical Review E 70:41408.
Fuetterer, T., et al., 2004. Characterization of polybutadiene-poly(ethyleneoxide) aggregates in aqueous solution: A light-scattering and small-angle neutron-scattering study. Physical Review E, 70(4): 41408.
T. Fuetterer, et al., “Characterization of polybutadiene-poly(ethyleneoxide) aggregates in aqueous solution: A light-scattering and small-angle neutron-scattering study”, Physical Review E, vol. 70, 2004, : 41408.
Fuetterer, T., Nordskog, A., Hellweg, T., Findenegg, G.H., Foerster, S., Dewhurst, C.D.: Characterization of polybutadiene-poly(ethyleneoxide) aggregates in aqueous solution: A light-scattering and small-angle neutron-scattering study. Physical Review E. 70, : 41408 (2004).
Fuetterer, T, Nordskog, A, Hellweg, Thomas, Findenegg, GH, Foerster, S, and Dewhurst, CD. “Characterization of polybutadiene-poly(ethyleneoxide) aggregates in aqueous solution: A light-scattering and small-angle neutron-scattering study”. Physical Review E 70.4 (2004): 41408.
64 References
Daten bereitgestellt von Europe PubMed Central.
AUTHOR UNKNOWN, ber bunsenges phys chem 101(), 1997
AUTHOR UNKNOWN, acta phys austriaca 47(), 1977
AUTHOR UNKNOWN, ber bunsenges phys chem 100(), 1996
AUTHOR UNKNOWN, 1982
AUTHOR UNKNOWN, 1986
AUTHOR UNKNOWN, j phys chem b 103(), 1999
AUTHOR UNKNOWN, 1993
AUTHOR UNKNOWN, 1976
AUTHOR UNKNOWN, 1977
AUTHOR UNKNOWN, makromol chem macromol symp 18(), 1988
Synthesis and Photonic Bandgap Characterization of Polymer Inverse Opals
Míguez, Advanced Materials 13(6), 2001
Míguez, Advanced Materials 13(6), 2001
Polymer-Based Photonic Crystals
Edrington, Advanced Materials 13(6), 2001
Edrington, Advanced Materials 13(6), 2001
Influence of temperature and oil-to-surfactant ratio on micellar growth in aqueous solutions of C12E5 with decane
Menge, Colloids and Surfaces A Physicochemical and Engineering Aspects 163(1), 2000
Menge, Colloids and Surfaces A Physicochemical and Engineering Aspects 163(1), 2000
The dynamics in dodecane/C10E5/water microemulsions determined by time resolved scattering techniques
Hellweg, Physica A Statistical and Theoretical Physics 264(3-4), 1999
Hellweg, Physica A Statistical and Theoretical Physics 264(3-4), 1999
Analysis of small-angle scattering data from colloids and polymer solutions: modeling and least-squares fitting
Pedersen, Advances in Colloid and Interface Science 70(), 1997
Pedersen, Advances in Colloid and Interface Science 70(), 1997
Cryogenic Transmission Electron Microscopy (Cryo-TEM) of Micelles and Vesicles Formed in Water by Poly(ethylene oxide)-Based Block Copolymers
Won, The Journal of Physical Chemistry B 106(13), 2002
Won, The Journal of Physical Chemistry B 106(13), 2002
A Small-Angle Neutron Scattering Study of Spherical and Wormlike Micelles Formed by Poly(oxyethylene)-Based Diblock Copolymers
Hamley, Langmuir 17(20), 2001
Hamley, Langmuir 17(20), 2001
Controlled Synthesis of Coordination Block Copolymers with β-Dicarbonyl Ligating Segments
Schlaad, Macromolecules 34(22), 2001
Schlaad, Macromolecules 34(22), 2001
Synthesis of α,ω-Heterobifunctional Poly(ethylene glycol)s by Metal-Free Anionic Ring-Opening Polymerization
Schlaad, Macromolecules 34(13), 2001
Schlaad, Macromolecules 34(13), 2001
Lyotropic Phase Morphologies of Amphiphilic Block Copolymers
Förster, Macromolecules 34(13), 2001
Förster, Macromolecules 34(13), 2001
Scattering Functions of Semiflexible Polymers with and without Excluded Volume Effects
Pedersen, Macromolecules 29(23), 1996
Pedersen, Macromolecules 29(23), 1996
Small-Angle X-ray Contrast-Variation Study of Micelles Formed by Poly(styrene)−Poly(ethylene oxide) Block Copolymers in Aqueous Solution
Hickl, Macromolecules 29(11), 1996
Hickl, Macromolecules 29(11), 1996
Diblock Copolymers of Ethylene Oxide and 1,2-Butylene Oxide in Aqueous Solution. Effect of E-Block-Length Distribution on Self-Association Properties
Yu, The Journal of Physical Chemistry B 101(22), 1997
Yu, The Journal of Physical Chemistry B 101(22), 1997
Temperature Dependences of the Critical Micelle Concentrations of Diblock Oxyethylene/Oxybutylene Copolymers. A Case of Athermal Micellization
Kelarakis, Macromolecules 31(3), 1998
Kelarakis, Macromolecules 31(3), 1998
Effects of Block Lengths on the Association Numbers and Micellar Sizes of BnEmBn Type Triblock Copolymer Micelles in Aqueous Solution
Liu, Macromolecules 30(24), 1997
Liu, Macromolecules 30(24), 1997
Lyotropic Mesophases of Poly(ethylene oxide)-b-poly(butadiene) Diblock Copolymers and Their Cross-Linking To Generate Ordered Gels
Hentze, Macromolecules 32(18), 1999
Hentze, Macromolecules 32(18), 1999
Self-Assembly of Mixed Amphiphilic Triblock Copolymers in Aqueous Solution
Liu, Langmuir 15(9), 1999
Liu, Langmuir 15(9), 1999
Synthesis of PB−PEO and PI−PEO Block Copolymers with Alkyllithium Initiators and the Phosphazene Base t-BuP4
Förster, Macromolecules 32(8), 1999
Förster, Macromolecules 32(8), 1999
Micellization of Model Macromolecular Surfactants as Studied by Static Light Scattering
Schädler, The Journal of Physical Chemistry B 104(21), 2000
Schädler, The Journal of Physical Chemistry B 104(21), 2000
Segment Distribution of the Micellar Brushes of Poly(ethylene oxide) via Small-Angle Neutron Scattering
Won, The Journal of Physical Chemistry B 104(30), 2000
Won, The Journal of Physical Chemistry B 104(30), 2000
Relationship between Pluronic Block Copolymer Structure, Critical Micellization Concentration and Partitioning Coefficients of Low Molecular Mass Solutes
Kozlov, Macromolecules 33(9), 2000
Kozlov, Macromolecules 33(9), 2000
Dynamic light scattering by aqueous solutions of rodlike fd-virus particles
Graf, The Journal of Chemical Physics 95(9), 1991
Graf, The Journal of Chemical Physics 95(9), 1991
The pair-distribution function and light-scattered intensities for charged rod-like macromolecules in solution
Schneider, The Journal of Chemical Physics 87(5), 1987
Schneider, The Journal of Chemical Physics 87(5), 1987
Wang, Journal of Physics Condensed Matter 11(50), 1999
Palberg, Journal of Physics Condensed Matter 11(28), 1999
Experimental investigation of the structure of nonionic microemulsions and their relation to the bending elasticity of the amphiphilic film.
Gradzielski M, Langevin D, Farago B., Phys Rev E Stat Phys Plasmas Fluids Relat Interdiscip Topics 53(4), 1996
PMID: 9964703
Gradzielski M, Langevin D, Farago B., Phys Rev E Stat Phys Plasmas Fluids Relat Interdiscip Topics 53(4), 1996
PMID: 9964703
Photonic band gap phenomenon and optical properties of artificial opals
Bogomolov, Physical Review E 55(6), 1997
Bogomolov, Physical Review E 55(6), 1997
Analytical treatment of the resolution function for small-angle scattering
Pedersen, Journal of Applied Crystallography 23(4), 1990
Pedersen, Journal of Applied Crystallography 23(4), 1990
Determination of particle-size distribution functions from small-angle scattering data by means of the indirect transformation method
Glatter, Journal of Applied Crystallography 13(1), 1980
Glatter, Journal of Applied Crystallography 13(1), 1980
Colloidal crystals made of poly( N -isopropylacrylamide) microgel particles
Hellweg, Colloid & Polymer Science 278(10), 2000
Hellweg, Colloid & Polymer Science 278(10), 2000
Association Properties of Triblock Copolymers of Ethylene Oxide and 1,2-Butylene Oxide in Aqueous Solution. Effect of Hydrophilic Block Length
Yu, Langmuir 18(20), 2002
Yu, Langmuir 18(20), 2002
A constrained regularization method for inverting data represented by linear algebraic or integral equations
Provencher, Computer Physics Communications 27(3), 1982
Provencher, Computer Physics Communications 27(3), 1982
CONTIN: A general purpose constrained regularization program for inverting noisy linear algebraic and integral equations
Provencher, Computer Physics Communications 27(3), 1982
Provencher, Computer Physics Communications 27(3), 1982
Structural Transition of Oil-Swollen Cylindrical Micelles of C12E5 in Water Studied by SANS
Menge, The Journal of Physical Chemistry B 107(6), 2003
Menge, The Journal of Physical Chemistry B 107(6), 2003
Effect of chain length on the micellization and gelation of block copoly(oxyethylene/oxybutylene/oxyethylene) EmBnEm
NICHOLAS, Polymer 34(1), 1993
NICHOLAS, Polymer 34(1), 1993
Time-Correlation Functions and Transport Coefficients in Statistical Mechanics
Zwanzig, Annual Review of Physical Chemistry 16(1), 1965
Zwanzig, Annual Review of Physical Chemistry 16(1), 1965
Structural changes of poly(butadiene)-poly(ethyleneoxide) diblock-copolymer micelles induced by a cationic surfactant: scattering and cryogenic transmission electron microscopy studies.
Nordskog A, Egger H, Findenegg GH, Hellweg T, Schlaad H, Von Berlepsch H, Bottcher C., Phys Rev E Stat Nonlin Soft Matter Phys 68(1 Pt 1), 2003
PMID: 12935142
Nordskog A, Egger H, Findenegg GH, Hellweg T, Schlaad H, Von Berlepsch H, Bottcher C., Phys Rev E Stat Nonlin Soft Matter Phys 68(1 Pt 1), 2003
PMID: 12935142
Spectrum of Light Scattered from Optically Anisotropic Macromolecules
Pecora, The Journal of Chemical Physics 49(3), 1968
Pecora, The Journal of Chemical Physics 49(3), 1968
Formation of mixed micelles of PB40PEO62 and the anionic surfactant SDS in aqueous solutions
Nordskog, Physical Chemistry Chemical Physics 6(12), 2004
Nordskog, Physical Chemistry Chemical Physics 6(12), 2004
Depletion interactions and fractionated crystallization for polydisperse emulsion purification
BIBETTE, Journal of Colloid and Interface Science 147(2), 1991
BIBETTE, Journal of Colloid and Interface Science 147(2), 1991
Internal dynamics of linear and superhelical DNA as studied by photon correlation spectroscopy.
Seils J, Dorfmuller T., Biopolymers 31(7), 1991
PMID: 1912340
Seils J, Dorfmuller T., Biopolymers 31(7), 1991
PMID: 1912340
Rotational Diffusion Constant of a Cylindrical Particle
Broersma, The Journal of Chemical Physics 32(6), 1960
Broersma, The Journal of Chemical Physics 32(6), 1960
Viscous Force Constant for a Closed Cylinder
Broersma, The Journal of Chemical Physics 32(6), 1960
Broersma, The Journal of Chemical Physics 32(6), 1960
Thermodynamic and Conformational Properties of Polystyrene. I. Light-Scattering Studies on Dilute Solutions of Linear Polystyrenes
Berry, The Journal of Chemical Physics 44(12), 1966
Berry, The Journal of Chemical Physics 44(12), 1966
Micelle shape and size
Tanford, The Journal of Physical Chemistry 76(21), 1972
Tanford, The Journal of Physical Chemistry 76(21), 1972
Fluorescence Studies on the Properties of a Pluronic F68 Micelle
Nakashima, Langmuir 10(3), 1994
Nakashima, Langmuir 10(3), 1994
Quasi-elastic light scattering by semiflexible chains
Schmidt, Macromolecules 17(4), 1984
Schmidt, Macromolecules 17(4), 1984
Absolute Rayleigh ratios of four solvents at 488 nm
Bender, Macromolecules 19(1), 1986
Bender, Macromolecules 19(1), 1986
Poly(styrene-ethylene oxide) block copolymer micelle formation in water: a fluorescence probe study
Wilhelm, Macromolecules 24(5), 1991
Wilhelm, Macromolecules 24(5), 1991
Investigations on the solution architecture of carboxylated tamarind seed polysaccharide by static and dynamic light scattering
Lang, Macromolecules 26(15), 1993
Lang, Macromolecules 26(15), 1993
Phase Diagrams and Aggregation Behavior of Poly(oxyethylene)-Poly(oxypropylene)-Poly(oxyethylene) Triblock Copolymers in Aqueous Solutions
Wanka, Macromolecules 27(15), 1994
Wanka, Macromolecules 27(15), 1994
Flexibility of F-actin in aqueous solution: a study on filaments of different average lengths
Droegemeier, Macromolecules 27(1), 1994
Droegemeier, Macromolecules 27(1), 1994
Light Scattering of Stiff Chain Polymers
Koyama, Journal of the Physical Society of Japan 34(4), 1973
Koyama, Journal of the Physical Society of Japan 34(4), 1973
Analysis of the conformation of worm-like chains by small-angle scattering: Monte-Carlo simulations in comparison to analytical theory
Pötschke, Macromolecular Theory and Simulations 9(6), 2000
Pötschke, Macromolecular Theory and Simulations 9(6), 2000
Export
Markieren/ Markierung löschen
Markierte Publikationen
Web of Science
Dieser Datensatz im Web of Science®Quellen
PMID: 15600409
PubMed | Europe PMC
Suchen in
Google Scholar