Nanorod-coated PNIPAM microgels: Thermoresponsive optical properties

Karg M, Pastoriza-Santos I, Perez-Juste J, Hellweg T, Liz-Marzan LM (2007)
Small 3(7): 1222-1229.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
Es wurden keine Dateien hochgeladen. Nur Publikationsnachweis!
Karg, Matthias; Pastoriza-Santos, Isabel; Perez-Juste, Jorge; Hellweg, ThomasUniBi ; Liz-Marzan, Luis M.
Abstract / Bemerkung
Nanoparticles and in particular gold nanorods have interesting optical properties arising from two well-differentiated plasmon modes. The frequency of such modes can be altered by their chemical environment and coupling with neighboring rods. This study investigates new composite materials made of gold nanorods adsorbed on thermoresponsive poly (N-isopropylacrylamide) (PNIPAM) microgels. It is shown that the thermally induced collapse of the polymer network inside the particles leads to a red shift of the longitudinal plasmon band of the gold rods, which is found to be fully reversible.
gold; nanoparticles; nanorods; plasmon resonance; microgels
Page URI


Karg M, Pastoriza-Santos I, Perez-Juste J, Hellweg T, Liz-Marzan LM. Nanorod-coated PNIPAM microgels: Thermoresponsive optical properties. Small. 2007;3(7):1222-1229.
Karg, M., Pastoriza-Santos, I., Perez-Juste, J., Hellweg, T., & Liz-Marzan, L. M. (2007). Nanorod-coated PNIPAM microgels: Thermoresponsive optical properties. Small, 3(7), 1222-1229.
Karg, Matthias, Pastoriza-Santos, Isabel, Perez-Juste, Jorge, Hellweg, Thomas, and Liz-Marzan, Luis M. 2007. “Nanorod-coated PNIPAM microgels: Thermoresponsive optical properties”. Small 3 (7): 1222-1229.
Karg, M., Pastoriza-Santos, I., Perez-Juste, J., Hellweg, T., and Liz-Marzan, L. M. (2007). Nanorod-coated PNIPAM microgels: Thermoresponsive optical properties. Small 3, 1222-1229.
Karg, M., et al., 2007. Nanorod-coated PNIPAM microgels: Thermoresponsive optical properties. Small, 3(7), p 1222-1229.
M. Karg, et al., “Nanorod-coated PNIPAM microgels: Thermoresponsive optical properties”, Small, vol. 3, 2007, pp. 1222-1229.
Karg, M., Pastoriza-Santos, I., Perez-Juste, J., Hellweg, T., Liz-Marzan, L.M.: Nanorod-coated PNIPAM microgels: Thermoresponsive optical properties. Small. 3, 1222-1229 (2007).
Karg, Matthias, Pastoriza-Santos, Isabel, Perez-Juste, Jorge, Hellweg, Thomas, and Liz-Marzan, Luis M. “Nanorod-coated PNIPAM microgels: Thermoresponsive optical properties”. Small 3.7 (2007): 1222-1229.

51 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Modular soft robotic microdevices for dexterous biomanipulation.
Özkale B, Parreira R, Bekdemir A, Pancaldi L, Özelçi E, Amadio C, Kaynak M, Stellacci F, Mooney DJ, Sakar MS., Lab Chip 19(5), 2019
PMID: 30714604
Relationship between rheology and structure of interpenetrating, deforming and compressing microgels.
Conley GM, Zhang C, Aebischer P, Harden JL, Scheffold F., Nat Commun 10(1), 2019
PMID: 31164639
Thermoresponsive Bentonite for Water-Based Drilling Fluids.
Dong W, Pu X, Ren Y, Zhai Y, Gao F, Xie W., Materials (Basel) 12(13), 2019
PMID: 31262077
Plasmonic and colloidal stability behaviours of Au-acrylic core-shell nanoparticles with thin pH-responsive shells.
Wu S, Zhu M, Lian Q, Lu D, Spencer B, Adlam DJ, Hoyland JA, Volk K, Karg M, Saunders BR., Nanoscale 10(39), 2018
PMID: 30259044
Thermo-Sensitive Nanomaterials: Recent Advance in Synthesis and Biomedical Applications.
Sánchez-Moreno P, de Vicente J, Nardecchia S, Marchal JA, Boulaiz H., Nanomaterials (Basel) 8(11), 2018
PMID: 30428608
How gold nanoparticles can be used to probe the structural changes of a pH-responsive hydrogel.
Schmidt MM, Wu S, Cui Z, Nguyen NT, Faulkner M, Saunders BR., Phys Chem Chem Phys 19(7), 2017
PMID: 28138660
On/off-switchable LSPR nano-immunoassay for troponin-T.
Ashaduzzaman M, Deshpande SR, Murugan NA, Mishra YK, Turner AP, Tiwari A., Sci Rep 7(), 2017
PMID: 28382946
Robust raspberry-like metallo-dielectric nanoclusters of critical sizes as SERS substrates.
Le Beulze A, Gomez-Graña S, Gehan H, Mornet S, Ravaine S, Correa-Duarte M, Guerrini L, Alvarez-Puebla RA, Duguet E, Pertreux E, Crut A, Maioli P, Vallée F, Del Fatti N, Ersen O, Treguer-Delapierre M., Nanoscale 9(17), 2017
PMID: 28426077
Tuning the Size of Thermoresponsive Poly(N-Isopropyl Acrylamide) Grafted Silica Microgels.
Nun N, Hinrichs S, Schroer MA, Sheyfer D, Grübel G, Fischer B., Gels 3(3), 2017
PMID: 30920530
Jamming and overpacking fuzzy microgels: Deformation, interpenetration, and compression.
Conley GM, Aebischer P, Nöjd S, Schurtenberger P, Scheffold F., Sci Adv 3(10), 2017
PMID: 29062888
Light-induced actuating nanotransducers.
Ding T, Valev VK, Salmon AR, Forman CJ, Smoukov SK, Scherman OA, Frenkel D, Baumberg JJ., Proc Natl Acad Sci U S A 113(20), 2016
PMID: 27140648
Multi-responsive hybrid particles: thermo-, pH-, photo-, and magneto-responsive magnetic hydrogel cores with gold nanorod optical triggers.
Rittikulsittichai S, Kolhatkar AG, Sarangi S, Vorontsova MA, Vekilov PG, Brazdeikis A, Randall Lee T., Nanoscale 8(23), 2016
PMID: 27227963
Polymer-assisted self-assembly of gold nanoparticle monolayers and their dynamical switching.
Ding T, Rudrum AW, Herrmann LO, Turek V, Baumberg JJ., Nanoscale 8(35), 2016
PMID: 27546585
Photosensitive microgels containing azobenzene surfactants of different charges.
Schimka S, Lomadze N, Rabe M, Kopyshev A, Lehmann M, von Klitzing R, Rumyantsev AM, Kramarenko EY, Santer S., Phys Chem Chem Phys 19(1), 2016
PMID: 27722591
Core-shell-shell and hollow double-shell microgels with advanced temperature responsiveness.
Dubbert J, Nothdurft K, Karg M, Richtering W., Macromol Rapid Commun 36(2), 2015
PMID: 25354836
Microspherical hydrogel particles based on silica nanoparticle-webbed polymer networks.
Takafuji M, Alam MA, Goto H, Ihara H., J Colloid Interface Sci 455(), 2015
PMID: 26051029
A Surface-Enhanced Raman Scattering Sensor Integrated with Battery-Controlled Fluidic Device for Capture and Detection of Trace Small Molecules.
Zhou Q, Meng G, Zheng P, Cushing S, Wu N, Huang Q, Zhu C, Zhang Z, Wang Z., Sci Rep 5(), 2015
PMID: 26238799
Tunable Optical Nanoantennas Incorporating Bowtie Nanoantenna Arrays with Stimuli-Responsive Polymer.
Wang Q, Liu L, Wang Y, Liu P, Jiang H, Xu Z, Ma Z, Oren S, Chow EK, Lu M, Dong L., Sci Rep 5(), 2015
PMID: 26681478
Laser heating tunability by off-resonant irradiation of gold nanoparticles.
Hormeño S, Gregorio-Godoy P, Pérez-Juste J, Liz-Marzán LM, Juárez BH, Arias-Gonzalez JR., Small 10(2), 2014
PMID: 24106098
Anisotropic gold nanoparticles: synthesis, properties, applications, and toxicity.
Li N, Zhao P, Astruc D., Angew Chem Int Ed Engl 53(7), 2014
PMID: 24421264
Thermo-responsiveness and tunable optical properties of asymmetric polystyrene/PNIPAM-gold composite particles.
Zhang M, Rabiah NI, Ngo TH, Otanicar TP, Phelan PE, Swaminathan R, Dai LL., J Colloid Interface Sci 425(), 2014
PMID: 24776658
Thermally sensitive reversible microgels formed by poly(N-Isopropylacrylamide) charged chains: a Hofmeister effect study.
López-León T, Ortega-Vinuesa JL, Bastos-González D, Elaissari A., J Colloid Interface Sci 426(), 2014
PMID: 24863797
Thermoresponsive fluorescence of a graphene-polymer composite based on a local surface plasmon resonance effect.
Huang Y, Lin W, Chen K, Zhang W, Chen X, Zhang MQ., Phys Chem Chem Phys 16(23), 2014
PMID: 24806411
Interaction of gold nanoparticles with thermoresponsive microgels: influence of the cross-linker density on optical properties.
Gawlitza K, Turner ST, Polzer F, Wellert S, Karg M, Mulvaney P, von Klitzing R., Phys Chem Chem Phys 15(37), 2013
PMID: 23942792
Quadruple-responsive nanocomposite based on dextran-PMAA-PNIPAM, iron oxide nanoparticles, and gold nanorods.
Feng W, Lv W, Qi J, Zhang G, Zhang F, Fan X., Macromol Rapid Commun 33(2), 2012
PMID: 22102518
Synthesis of silver nanoparticle necklaces without explicit addition of reducing or templating agents.
Hanisch M, Mačković M, Taccardi N, Spiecker E, Klupp Taylor RN., Chem Commun (Camb) 48(36), 2012
PMID: 22437651
Facile and efficient fabrication of photoresponsive microgels via thiol-Michael addition.
Zhang HJ, Xin Y, Yan Q, Zhou LL, Peng L, Yuan JY., Macromol Rapid Commun 33(22), 2012
PMID: 22907724
Versatile phase transfer of gold nanoparticles from aqueous media to different organic media.
Karg M, Schelero N, Oppel C, Gradzielski M, Hellweg T, von Klitzing R., Chemistry 17(16), 2011
PMID: 21433128
Triggering the volume phase transition of core-shell Au nanorod-microgel nanocomposites with light.
Rodríguez-Fernández J, Fedoruk M, Hrelescu C, Lutich AA, Feldmann J., Nanotechnology 22(24), 2011
PMID: 21543835
Directed assembly of gold nanorods using aligned electrospun polymer nanofibers for highly efficient SERS substrates.
Lee CH, Tian L, Abbas A, Kattumenu R, Singamaneni S., Nanotechnology 22(27), 2011
PMID: 21613732
Brushlike interactions between thermoresponsive microgel particles.
Scheffold F, Díaz-Leyva P, Reufer M, Ben Braham N, Lynch I, Harden JL., Phys Rev Lett 104(12), 2010
PMID: 20366570
Growing Au/Ag nanoparticles within microgel colloids for improved surface-enhanced Raman scattering detection.
Contreras-Cáceres R, Pastoriza-Santos I, Alvarez-Puebla RA, Pérez-Juste J, Fernández-Barbero A, Liz-Marzán LM., Chemistry 16(31), 2010
PMID: 20645358
Remotely triggerable drug delivery systems.
Timko BP, Dvir T, Kohane DS., Adv Mater 22(44), 2010
PMID: 20818618
Photoluminescent smart hydrogels with reversible and linear thermoresponses.
Jiang Y, Yang X, Ma C, Wang C, Li H, Dong F, Zhai X, Yu K, Lin Q, Yang B., Small 6(23), 2010
PMID: 21069754
Design and fabrication of colloidal polymer nanocomposites.
Wang T, Keddie JL., Adv Colloid Interface Sci 147-148(), 2009
PMID: 18757049
Au@pNIPAM colloids as molecular traps for surface-enhanced, spectroscopic, ultra-sensitive analysis.
Alvarez-Puebla RA, Contreras-Cáceres R, Pastoriza-Santos I, Pérez-Juste J, Liz-Marzán LM., Angew Chem Int Ed Engl 48(1), 2009
PMID: 19039813
Poly(ethylene glycol)-modified gold nanorods as a photothermal nanodevice for hyperthermia.
Niidome T, Akiyama Y, Yamagata M, Kawano T, Mori T, Niidome Y, Katayama Y., J Biomater Sci Polym Ed 20(9), 2009
PMID: 19520008
Temperature-sensitive poly(N-isopropyl-acrylamide) microgel particles: a light scattering study.
Reufer M, Díaz-Leyva P, Lynch I, Scheffold F., Eur Phys J E Soft Matter 28(2), 2009
PMID: 19031089
Gold nanorods: from synthesis and properties to biological and biomedical applications.
Huang X, Neretina S, El-Sayed MA., Adv Mater 21(48), 2009
PMID: 25378252
Dual-stimuli responsive PNiPAM microgel achieved via layer-by-layer assembly: magnetic and thermoresponsive.
Wong JE, Gaharwar AK, Müller-Schulte D, Bahadur D, Richtering W., J Colloid Interface Sci 324(1-2), 2008
PMID: 18514212
Controllable synthesis of CuS-P(AM-co-MAA) composite microspheres with patterned surface structures.
Zhang Y, Liu H, Zhao Y, Fang Y., J Colloid Interface Sci 325(2), 2008
PMID: 18649893
Photodynamic thermoresponsive nanocarbon-polymer gel hybrids.
Miyako E, Nagata H, Hirano K, Hirotsu T., Small 4(10), 2008
PMID: 18770507
Thermoresponsive core-shell microgels with silica nanoparticle cores: size, structure, and volume phase transition of the polymer shell.
Karg M, Wellert S, Pastoriza-Santos I, Lapp A, Liz-Marzán LM, Hellweg T., Phys Chem Chem Phys 10(44), 2008
PMID: 18989484

49 References

Daten bereitgestellt von Europe PubMed Central.

Temperature-sensitive aqueous microgels.
Pelton R., Adv Colloid Interface Sci 85(1), 2000
PMID: 10696447

Nayak, Angew. Chem. 117(), 2005

AUTHOR UNKNOWN, Angew. Chem. Int. Ed. 44(), 2005

Kratz, Polymer 42(), 2001

Crowther, Colloids Surf. A 152(), 1999

Senff, J. Chem. Phys. 111(), 1999
Thermosensitive core-shell particles as carrier systems for metallic nanoparticles.
Lu Y, Mei Y, Ballauff M, Drechsler M., J Phys Chem B 110(9), 2006
PMID: 16509678
Small-angle neutron scattering study of structural changes in temperature sensitive microgel colloids.
Stieger M, Richtering W, Pedersen JS, Lindner P., J Chem Phys 120(13), 2004
PMID: 15267506

Kratz, Colloids Surf. A 170(), 2000

Tanaka, Phys. A 140(), 1986

Li, J. Chem. Phys. 90(), 1989

Li, J. Chem. Phys. 92(), 1990

Guenet, 1992

Antonietti, Angew. Chem. 100(), 1988

Freitas, Chem. Eng. Sci. 42(), 1987
A versatile approach for the preparation of thermosensitive PNIPAM core-shell microgels with nanoparticle cores.
Karg M, Pastoriza-Santos I, Liz-Marzan LM, Hellweg T., Chemphyschem 7(11), 2006
PMID: 17013983

Lu, Angew. Chem. 118(), 2006

AUTHOR UNKNOWN, Angew. Chem. Int. Ed. 45(), 2006

Kim, Macromol. Chem. Phys. 206(), 2005
Hybrid microgels with reversibly changeable multiple brilliant color.
Suzuki D, Kawaguchi H., Langmuir 22(8), 2006
PMID: 16584261

Nanostructures;, MRS Bull. 30(), 2005

Enüstün, J. Am. Chem. Soc. 85(), 1963

Liz-Marzán, Langmuir 12(), 1996

Pastoriza-Santos, Chem. Mater. 18(), 2006

Lofton, Adv. Funct. Mater. 15(), 2005

Malikova, Langmuir 18(), 2002

Kim, Angew. Chem. 116(), 2004

AUTHOR UNKNOWN, Angew. Chem. Int. Ed. 43(), 2004
Optical properties of star-shaped gold nanoparticles.
Nehl CL, Liao H, Hafner JH., Nano Lett. 6(4), 2006
PMID: 16608264

Kelly, J. Phys. Chem. B 107(), 2003

Pérez-Juste, Coord. Chem. Rev. 249(), 2005
Hybrid microgels photoresponsive in the near-infrared spectral range.
Gorelikov I, Field LM, Kumacheva E., J. Am. Chem. Soc. 126(49), 2004
PMID: 15584708

Bao, J. Macromol. Sci. Chem. 43(), 2006

Andersson, Colloid Polym. Sci. 285(), 2006

Gole, Chem. Mater. 17(), 2005

Kratz, Ber. Bunsenges. Phys. Chem. 102(), 1998

Gluodenis, J. Phys. Chem. B 106(), 2002

Thomas, J. Phys. Chem. B 108(), 2004
Selective detection of cysteine and glutathione using gold nanorods.
Sudeep PK, Joseph ST, Thomas KG., J. Am. Chem. Soc. 127(18), 2005
PMID: 15869256

Correa-Duarte, Angew. Chem. 117(), 2005

AUTHOR UNKNOWN, Angew. Chem. Int. Ed. 44(), 2005

Hellweg, Colloids Surf. A 202(), 2002

Höfl, Polymer 48(), 2007

Pelton, Colloids Surf. 20(), 1986

Provencher, Comput. Phys. Commun. 27(), 1982

Markieren/ Markierung löschen
Markierte Publikationen

Open Data PUB

Web of Science

Dieser Datensatz im Web of Science®

PMID: 17487899
PubMed | Europe PMC

Suchen in

Google Scholar