Dynamics of the interfacial film in bicontinuous microemulsions based on a partly ionic surfactant mixture: A neutron spin-echo study
Wellert S, Altmann H-J, Richardt A, Lapp A, Falus P, Farago B, Hellweg T (2010)
The European Physical Journal E 33(3): 243-250.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
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Autor*in
Wellert, S.;
Altmann, H. -J.;
Richardt, A.;
Lapp, A.;
Falus, P.;
Farago, B.;
Hellweg, ThomasUniBi
Abstract / Bemerkung
In a microemulsion system based on a mixture of nonionic and ionic surfactants the addition of alcohol instead of changing the temperature was used to tune the curvature of the surfactant interface. The influence of the addition of the short-chain alcohol 2-propanol in the system water-perchloroethylene-Marlowet IHF-2-propanol is studied using neutron spin-echo spectroscopy. In contrast to alcohols with long alkyl chains 2-propanol is no strong co-surfactant, but changes the properties of the solvents. The present contribution focuses on the bicontinuous phase in this system and a quantitative analysis of the obtained neutron spin-echo data is proposed within the theoretical framework given by Zilman and Granek for amphiphilic membranes. It turns out that, in addition to the local movements of the surfactant film, also a collective diffusional mode of the bicontinuous structure has to be taken into account. The presented approach allows to calculate the bending elastic constant kappa of the film. The approach is subsequently applied to follow changes of kappa as induced by changes of the alcohol concentration.
Erscheinungsjahr
2010
Zeitschriftentitel
The European Physical Journal E
Band
33
Ausgabe
3
Seite(n)
243-250
ISSN
1292-8941
eISSN
1292-895X
Page URI
https://pub.uni-bielefeld.de/record/1968131
Zitieren
Wellert S, Altmann H-J, Richardt A, et al. Dynamics of the interfacial film in bicontinuous microemulsions based on a partly ionic surfactant mixture: A neutron spin-echo study. The European Physical Journal E. 2010;33(3):243-250.
Wellert, S., Altmann, H. - J., Richardt, A., Lapp, A., Falus, P., Farago, B., & Hellweg, T. (2010). Dynamics of the interfacial film in bicontinuous microemulsions based on a partly ionic surfactant mixture: A neutron spin-echo study. The European Physical Journal E, 33(3), 243-250. https://doi.org/10.1140/epje/i2010-10668-1
Wellert, S., Altmann, H. -J., Richardt, A., Lapp, A., Falus, P., Farago, B., and Hellweg, Thomas. 2010. “Dynamics of the interfacial film in bicontinuous microemulsions based on a partly ionic surfactant mixture: A neutron spin-echo study”. The European Physical Journal E 33 (3): 243-250.
Wellert, S., Altmann, H. - J., Richardt, A., Lapp, A., Falus, P., Farago, B., and Hellweg, T. (2010). Dynamics of the interfacial film in bicontinuous microemulsions based on a partly ionic surfactant mixture: A neutron spin-echo study. The European Physical Journal E 33, 243-250.
Wellert, S., et al., 2010. Dynamics of the interfacial film in bicontinuous microemulsions based on a partly ionic surfactant mixture: A neutron spin-echo study. The European Physical Journal E, 33(3), p 243-250.
S. Wellert, et al., “Dynamics of the interfacial film in bicontinuous microemulsions based on a partly ionic surfactant mixture: A neutron spin-echo study”, The European Physical Journal E, vol. 33, 2010, pp. 243-250.
Wellert, S., Altmann, H.-J., Richardt, A., Lapp, A., Falus, P., Farago, B., Hellweg, T.: Dynamics of the interfacial film in bicontinuous microemulsions based on a partly ionic surfactant mixture: A neutron spin-echo study. The European Physical Journal E. 33, 243-250 (2010).
Wellert, S., Altmann, H. -J., Richardt, A., Lapp, A., Falus, P., Farago, B., and Hellweg, Thomas. “Dynamics of the interfacial film in bicontinuous microemulsions based on a partly ionic surfactant mixture: A neutron spin-echo study”. The European Physical Journal E 33.3 (2010): 243-250.
Daten bereitgestellt von European Bioinformatics Institute (EBI)
3 Zitationen in Europe PMC
Daten bereitgestellt von Europe PubMed Central.
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PMID: 28631792
Sharma VK, Hayes DG, Urban VS, O'Neill HM, Tyagi M, Mamontov E., Soft Matter 13(28), 2017
PMID: 28631792
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Hoffmann I, de Molina PM, Farago B, Falus P, Herfurth C, Laschewsky A, Gradzielski M., J Chem Phys 140(3), 2014
PMID: 25669409
Hoffmann I, de Molina PM, Farago B, Falus P, Herfurth C, Laschewsky A, Gradzielski M., J Chem Phys 140(3), 2014
PMID: 25669409
Temperature dependence of the surfactant film bending elasticity in a bicontinuous sugar surfactant based microemulsion: a quasielastic scattering study.
Wellert S, Karg M, Holderer O, Richardt A, Hellweg T., Phys Chem Chem Phys 13(8), 2011
PMID: 21152562
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PMID: 21152562
59 References
Daten bereitgestellt von Europe PubMed Central.
Langevin, Annu. Rev. Phys. Chem. 43(), 1992
Strey, Colloid Polym. Sci. 272(), 1994
Hoffmann, Adv. Mater. 6(), 1994
Gelbart, J. Phys. Chem. 100(), 1996
Gradzielski, J. Chem. Phys. 104(), 1996
Hellweg, Curr. Opin. Colloid Interface Sci. 7(), 2002
Komura, J. Phys.: Condens. Matter 19(), 2007
Klier, Adv. Mater. 12(), 2000
Nakamura, Langmuir 13(), 1997
Aubry, J. Am. Chem. Soc. 119(), 1997
Menger, Langmuir 15(), 1999
Inactivation of Ebola virus with a surfactant nanoemulsion.
Chepurnov AA, Bakulina LF, Dadaeva AA, Ustinova EN, Chepurnova TS, Baker JR Jr., Acta Trop. 87(3), 2003
PMID: 12875924
Chepurnov AA, Bakulina LF, Dadaeva AA, Ustinova EN, Chepurnova TS, Baker JR Jr., Acta Trop. 87(3), 2003
PMID: 12875924
Menger, J. Am. Chem. Soc. 113(), 1991
Schwuger, Chem. Rev. 95(), 1995
Hao, Colloid Polym. Sci 278(), 2000
Lade, Langmuir 16(), 2000
Haeger, Top. Curr. Chem. 227(), 2003
Helfrich, Z. Naturforsch. 28c(), 1973
Safran, Adv. Phys. 48(), 1999
Scriven, Nature 263(), 1976
Jahn, J. Phys. Chem. 92(), 1988
Gazeau, Europhys. Lett. 9(), 1989
Burauer, Coll. Surf. A 228(), 2003
Undulations and Dynamic Structure Factor of Membranes.
Zilman AG, Granek R., Phys. Rev. Lett. 77(23), 1996
PMID: 10062631
Zilman AG, Granek R., Phys. Rev. Lett. 77(23), 1996
PMID: 10062631
Sorlie, Macromolecules 21(), 1988
Zilman, Chem. Phys. 284(), 2002
Nonomura, J. Chem. Phys. 110(), 1999
Mihailescu, J. Chem. Phys. 115(), 2001
Dynamic properties of microemulsions modified with homopolymers and diblock copolymers: the determination of bending moduli and renormalization effects.
Holderer O, Frielinghaus H, Byelov D, Monkenbusch M, Allgaier J, Richter D., J Chem Phys 122(9), 2005
PMID: 15836182
Holderer O, Frielinghaus H, Byelov D, Monkenbusch M, Allgaier J, Richter D., J Chem Phys 122(9), 2005
PMID: 15836182
Hydrodynamic effects in bicontinuous microemulsions measured by inelastic neutron scattering.
Holderer O, Frielinghaus H, Monkenbusch M, Allgaier J, Richter D, Farago B., Eur Phys J E Soft Matter 22(2), 2007
PMID: 17356800
Holderer O, Frielinghaus H, Monkenbusch M, Allgaier J, Richter D, Farago B., Eur Phys J E Soft Matter 22(2), 2007
PMID: 17356800
Dynamical fluctuation of the mesoscopic structure in ternary C12E5-water-n-octane amphiphilic system.
Komura S, Takeda T, Kawabata Y, Ghosh SK, Seto H, Nagao M., Phys Rev E Stat Nonlin Soft Matter Phys 63(4 Pt 1), 2001
PMID: 11308838
Komura S, Takeda T, Kawabata Y, Ghosh SK, Seto H, Nagao M., Phys Rev E Stat Nonlin Soft Matter Phys 63(4 Pt 1), 2001
PMID: 11308838
Komura, Eur. Phys. J. E 5(), 2001
Monkenbusch, J. Phys.: Condens. Matter 17(), 2005
Farago, Physica B 226(), 1996
Hellweg, Phys. Rev. E 57(), 1998
Hellweg, Physica A 264(), 1999
Hellweg, Phys. Chem. Chem. Phys. 2(), 2000
Shape and size fluctuations of microemulsion droplets: The role of cosurfactant.
Farago B, Richter D, Huang JS, Safran SA, Milner ST., Phys. Rev. Lett. 65(26), 1990
PMID: 10042846
Farago B, Richter D, Huang JS, Safran SA, Milner ST., Phys. Rev. Lett. 65(26), 1990
PMID: 10042846
de, J. Phys. Chem. 86(), 1982
Paul, Curr. Sci. 80(), 2001
AUTHOR UNKNOWN, 0
Structure of biodiesel based bicontinuous microemulsions for environmentally compatible decontamination: A small angle neutron scattering and freeze fracture electron microscopy study.
Wellert S, Karg M, Imhof H, Steppin A, Altmann HJ, Dolle M, Richardt A, Tiersch B, Koetz J, Lapp A, Hellweg T., J Colloid Interface Sci 325(1), 2008
PMID: 18571191
Wellert S, Karg M, Imhof H, Steppin A, Altmann HJ, Dolle M, Richardt A, Tiersch B, Koetz J, Lapp A, Hellweg T., J Colloid Interface Sci 325(1), 2008
PMID: 18571191
Menger, J. Am. Chem. Soc. 112(), 1990
Binding of a designed substrate analogue to diisopropyl fluorophosphatase: implications for the phosphotriesterase mechanism.
Blum MM, Lohr F, Richardt A, Ruterjans H, Chen JC., J. Am. Chem. Soc. 128(39), 2006
PMID: 17002369
Blum MM, Lohr F, Richardt A, Ruterjans H, Chen JC., J. Am. Chem. Soc. 128(39), 2006
PMID: 17002369
Monitoring the hydrolysis of toxic organophosphonate nerve agents in aqueous buffer and in bicontinuous microemulsions by use of diisopropyl fluorophosphatase (DFPase) with (1)H- (31)P HSQC NMR spectroscopy.
Gab J, Melzer M, Kehe K, Wellert S, Hellweg T, Blum MM., Anal Bioanal Chem 396(3), 2009
PMID: 19943158
Gab J, Melzer M, Kehe K, Wellert S, Hellweg T, Blum MM., Anal Bioanal Chem 396(3), 2009
PMID: 19943158
Wellert, Colloid Polym. Sci. 285(), 2008
Kahlweit, J. Phys. Chem. 92(), 1988
AUTHOR UNKNOWN, 0
Sottmann, J. Chem. Phys. 106(), 1997
Schleger, Physica B 266(), 1999
AUTHOR UNKNOWN, 0
Brulet, J. Appl. Cryst. 40(), 2007
Teubner, J. Chem. Phys. 87(), 1987
Farago, Physica B 397(), 2007
Hellweg, Colloids Surf. A 183-185(), 2001
Stiffening effect of cholesterol on disordered lipid phases: a combined neutron spin echo + dynamic light scattering analysis of the bending elasticity of large unilamellar vesicles.
Arriaga LR, Lopez-Montero I, Monroy F, Orts-Gil G, Farago B, Hellweg T., Biophys. J. 96(9), 2009
PMID: 19413968
Arriaga LR, Lopez-Montero I, Monroy F, Orts-Gil G, Farago B, Hellweg T., Biophys. J. 96(9), 2009
PMID: 19413968
Fluctuation dynamics of spherical vesicles: frustration of regular bulk dissipation into subdiffusive relaxation.
Arriaga LR, Lopez-Montero I, Orts-Gil G, Farago B, Hellweg T, Monroy F., Phys Rev E Stat Nonlin Soft Matter Phys 80(3 Pt 1), 2009
PMID: 19905147
Arriaga LR, Lopez-Montero I, Orts-Gil G, Farago B, Hellweg T, Monroy F., Phys Rev E Stat Nonlin Soft Matter Phys 80(3 Pt 1), 2009
PMID: 19905147
Kahlweit, J. Phys. Chem. 95(), 1991
Kahlweit, Langmuir 11(), 1995
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