Dialkylaluminium-, -gallium-, and -indium-based poly-Lewis acids with a 1,8-diethynylanthracene backbone
Chmiel J, Neumann B, Stammler H-G, Mitzel NW (2010)
Chemistry 16(39): 11906-11914.
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Abstract / Bemerkung
Potential host systems based on a rigid 1,8-diethynylanthracendiyl backbone were synthesised by treatment of 1,8-diethynylanthracene with the Group 13 trialkyls AlMe(3), GaMe(3), InMe(3), AlEt(3) and GaEt(3). The resulting products were characterised by IR and multinuclear NMR spectroscopy, elemental analyses and determination of their crystal structures by X-ray diffraction. The compounds are dimeric in the solid state and comprise two M(2)C(2) heterocycles. Depending on the steric demand of the alkyl substituents at the metal atom, different types of binding modes were observed, which can be classified to lie between the ideals of side-on coordination with almost linear primary M-C C units and the 3c-2e coordination with symmetrically bridging alkynyl units in M-C-M bonds. As a solution in THF the dimers are broken into monomers and some are found to undergo ligand scrambling reactions.
Erscheinungsjahr
2010
Zeitschriftentitel
Chemistry
Band
16
Ausgabe
39
Seite(n)
11906-11914
ISSN
0947-6539
Page URI
https://pub.uni-bielefeld.de/record/1945111
Zitieren
Chmiel J, Neumann B, Stammler H-G, Mitzel NW. Dialkylaluminium-, -gallium-, and -indium-based poly-Lewis acids with a 1,8-diethynylanthracene backbone. Chemistry. 2010;16(39):11906-11914.
Chmiel, J., Neumann, B., Stammler, H. - G., & Mitzel, N. W. (2010). Dialkylaluminium-, -gallium-, and -indium-based poly-Lewis acids with a 1,8-diethynylanthracene backbone. Chemistry, 16(39), 11906-11914. https://doi.org/10.1002/chem.201001618
Chmiel, Jasmin, Neumann, Beate, Stammler, Hans-Georg, and Mitzel, Norbert W. 2010. “Dialkylaluminium-, -gallium-, and -indium-based poly-Lewis acids with a 1,8-diethynylanthracene backbone”. Chemistry 16 (39): 11906-11914.
Chmiel, J., Neumann, B., Stammler, H. - G., and Mitzel, N. W. (2010). Dialkylaluminium-, -gallium-, and -indium-based poly-Lewis acids with a 1,8-diethynylanthracene backbone. Chemistry 16, 11906-11914.
Chmiel, J., et al., 2010. Dialkylaluminium-, -gallium-, and -indium-based poly-Lewis acids with a 1,8-diethynylanthracene backbone. Chemistry, 16(39), p 11906-11914.
J. Chmiel, et al., “Dialkylaluminium-, -gallium-, and -indium-based poly-Lewis acids with a 1,8-diethynylanthracene backbone”, Chemistry, vol. 16, 2010, pp. 11906-11914.
Chmiel, J., Neumann, B., Stammler, H.-G., Mitzel, N.W.: Dialkylaluminium-, -gallium-, and -indium-based poly-Lewis acids with a 1,8-diethynylanthracene backbone. Chemistry. 16, 11906-11914 (2010).
Chmiel, Jasmin, Neumann, Beate, Stammler, Hans-Georg, and Mitzel, Norbert W. “Dialkylaluminium-, -gallium-, and -indium-based poly-Lewis acids with a 1,8-diethynylanthracene backbone”. Chemistry 16.39 (2010): 11906-11914.
Daten bereitgestellt von European Bioinformatics Institute (EBI)
12 Zitationen in Europe PMC
Daten bereitgestellt von Europe PubMed Central.
A Rational Approach to Tetra-Functional Photo-Switches.
Niermeier P, Lamm JH, Mix A, Neumann B, Stammler HG, Mitzel NW., ChemistryOpen 8(3), 2019
PMID: 30886788
Niermeier P, Lamm JH, Mix A, Neumann B, Stammler HG, Mitzel NW., ChemistryOpen 8(3), 2019
PMID: 30886788
Regiochemical Control in Triptycene Formation-An Exercise in Subtle Balancing Multiple Factors.
Lamm JH, Vishnevskiy YV, Ziemann E, Neumann B, Stammler HG, Mitzel NW., ChemistryOpen 7(1), 2018
PMID: 29344439
Lamm JH, Vishnevskiy YV, Ziemann E, Neumann B, Stammler HG, Mitzel NW., ChemistryOpen 7(1), 2018
PMID: 29344439
In(iii)In(iii) short contacts: an unnoticed metallophilic interaction?
Echeverría J., Chem Commun (Camb) 54(49), 2018
PMID: 29855644
Echeverría J., Chem Commun (Camb) 54(49), 2018
PMID: 29855644
Poly-Lewis-acids based on bowl-shaped tribenzotriquinacene.
Tomaschautzky J, Neumann B, Stammler HG, Mitzel NW., Dalton Trans 46(4), 2017
PMID: 28045169
Tomaschautzky J, Neumann B, Stammler HG, Mitzel NW., Dalton Trans 46(4), 2017
PMID: 28045169
Tridentate Lewis-acids based on triphenylsilane.
Tomaschautzky J, Neumann B, Stammler HG, Mix A, Mitzel NW., Dalton Trans 46(5), 2017
PMID: 28098286
Tomaschautzky J, Neumann B, Stammler HG, Mix A, Mitzel NW., Dalton Trans 46(5), 2017
PMID: 28098286
Fluoride complexation by bidentate silicon Lewis acids.
Horstmann J, Niemann M, Berthold K, Mix A, Neumann B, Stammler HG, Mitzel NW., Dalton Trans 46(6), 2017
PMID: 28106199
Horstmann J, Niemann M, Berthold K, Mix A, Neumann B, Stammler HG, Mitzel NW., Dalton Trans 46(6), 2017
PMID: 28106199
From Bidentate Gallium Lewis Acids to Supramolecular Complexes.
Horstmann J, Hyseni M, Mix A, Neumann B, Stammler HG, Mitzel NW., Angew Chem Int Ed Engl 56(22), 2017
PMID: 28418175
Horstmann J, Hyseni M, Mix A, Neumann B, Stammler HG, Mitzel NW., Angew Chem Int Ed Engl 56(22), 2017
PMID: 28418175
Trans-Metal-Trapping Meets Frustrated-Lewis-Pair Chemistry: Ga(CH2SiMe3)3-Induced C-H Functionalizations.
Uzelac M, Kennedy AR, Hevia E., Inorg Chem 56(15), 2017
PMID: 28485929
Uzelac M, Kennedy AR, Hevia E., Inorg Chem 56(15), 2017
PMID: 28485929
Tridentate Lewis acids with phenyl substituted 1,3,5-trisilacyclohexane backbones.
Weisheim E, Bücker L, Neumann B, Stammler HG, Mitzel NW., Dalton Trans 45(1), 2016
PMID: 26599621
Weisheim E, Bücker L, Neumann B, Stammler HG, Mitzel NW., Dalton Trans 45(1), 2016
PMID: 26599621
1,8-Bis(phenylethynyl)anthracene - gas and solid phase structures.
Lamm JH, Horstmann J, Stammler HG, Mitzel NW, Zhabanov YA, Tverdova NV, Otlyotov AA, Giricheva NI, Girichev GV., Org Biomol Chem 13(33), 2015
PMID: 26204511
Lamm JH, Horstmann J, Stammler HG, Mitzel NW, Zhabanov YA, Tverdova NV, Otlyotov AA, Giricheva NI, Girichev GV., Org Biomol Chem 13(33), 2015
PMID: 26204511
Mechanism of host-guest complex formation and identification of intermediates through NMR titration and diffusion NMR spectroscopy.
Lamm JH, Niermeier P, Mix A, Chmiel J, Neumann B, Stammler HG, Mitzel NW., Angew Chem Int Ed Engl 53(30), 2014
PMID: 24925835
Lamm JH, Niermeier P, Mix A, Chmiel J, Neumann B, Stammler HG, Mitzel NW., Angew Chem Int Ed Engl 53(30), 2014
PMID: 24925835
Confirmation of an early postulate: B-C-B two-electron-three-center bonding in organo(hydro)boranes.
Hübner A, Diefenbach M, Bolte M, Lerner HW, Holthausen MC, Wagner M., Angew Chem Int Ed Engl 51(50), 2012
PMID: 23161836
Hübner A, Diefenbach M, Bolte M, Lerner HW, Holthausen MC, Wagner M., Angew Chem Int Ed Engl 51(50), 2012
PMID: 23161836
71 References
Daten bereitgestellt von Europe PubMed Central.
AUTHOR UNKNOWN, 0
Stereospecific alkyl and alkynyl substitution reactions of epoxy sulfides with organoaluminums with double inversion of the configuration.
Sasaki M, Tanino K, Miyashita M., J. Org. Chem. 66(16), 2001
PMID: 11485460
Sasaki M, Tanino K, Miyashita M., J. Org. Chem. 66(16), 2001
PMID: 11485460
Powell, Tetrahedron Lett. 39(), 1998
Wilke, Justus Liebigs Ann. Chem. (), 1975
AUTHOR UNKNOWN, 0
Wilke, Chem. Ber. 89(), 1956
Wilke, Justus Liebigs Ann. Chem. 618(), 1958
AUTHOR UNKNOWN, 0
Binger, Angew. Chem. 75(), 1963
AUTHOR UNKNOWN, Angew. Chem. Int. Ed. 2(), 1963
Wilke, Justus Liebigs Ann. Chem. 629(), 1960
AUTHOR UNKNOWN, 0
Neutral and ionic aluminum, gallium, and indium compounds carrying two or three terminal ethynyl groups.
Schiefer M, Reddy ND, Ahn HJ, Stasch A, Roesky HW, Schlicker AC, Schmidt HG, Noltemeyer M, Vidovic D., Inorg Chem 42(16), 2003
PMID: 12895122
Schiefer M, Reddy ND, Ahn HJ, Stasch A, Roesky HW, Schlicker AC, Schmidt HG, Noltemeyer M, Vidovic D., Inorg Chem 42(16), 2003
PMID: 12895122
Fujiwara, Tetrahedron Lett. 25(), 1984
Pérez, Org. Lett. 1(), 1999
Balch, Inorg. Chem. 32(), 1993
AUTHOR UNKNOWN, 0
Stucky, J. Am. Chem. Soc. 96(), 1974
Tecle, Inorg. Chem. 20(), 1981
Schumann, J. Organomet. Chem. 479(), 1994
Uhl, Z. Anorg. Allg. Chem. 626(), 2000
AUTHOR UNKNOWN, 0
Zheng, J. Chem. Soc. Dalton Trans. (), 2002
Uhl, Z. Anorg. Allg. Chem. 630(), 2004
Uhl, Z. Anorg. Allg. Chem. 632(), 2006
Uhl, Eur. J. Inorg. Chem. (), 2009
Elschenbroich, Z. Anorg. Allg. Chem. 635(), 2009
Almenningen, J. Organomet. Chem. 155(), 1978
Katz, J. Org. Chem. 54(), 1989
Cottone, Organometallics 21(), 2002
AUTHOR UNKNOWN, 0
Gabbaï, Angew. Chem. 115(), 2003
AUTHOR UNKNOWN, Angew. Chem. Int. Ed. 42(), 2003
AUTHOR UNKNOWN, Organometallics 15(), 1996
AUTHOR UNKNOWN, J. Chem. Soc. Chem. Commun. (), 1996
Dorsey, Dalton Trans. (), 2008
Synthesis and properties of a cationic bidentate Lewis acid.
Lee MH, Gabbai FP., Inorg Chem 46(20), 2007
PMID: 17542577
Lee MH, Gabbai FP., Inorg Chem 46(20), 2007
PMID: 17542577
Jurkschat, Organometallics 8(), 1989
Newcomb, J. Am. Chem. Soc. 109(), 1987
Schulte, Organometallics 22(), 2003
Schulte, Chem. Eur. J. 7(), 2001
Tamao, J. Am. Chem. Soc. 112(), 1990
Tamao, Organometallics 11(), 1992
Brondani, Angew. Chem. 108(), 1996
AUTHOR UNKNOWN, Angew. Chem. Int. Ed. Engl. 35(), 1996
Uhl, Eur. J. Inorg. Chem. (), 1998
Uhl, J. Organomet. Chem. 579(), 1999
Uhl, J. Organomet. Chem. 664(), 2002
Uhl, Organometallics 24(), 2005
Uhl, Organometallics 25(), 2006
Yang, Angew. Chem. 103(), 1991
AUTHOR UNKNOWN, Angew. Chem. Int. Ed. Engl. 30(), 1991
Yang, J. Am. Chem. Soc. 114(), 1992
House, J. Org. Chem. 51(), 1986
Vögtle, Chem. Ber. 125(), 1992
AUTHOR UNKNOWN, 0
Jeffery, J. Organomet. Chem. 11(), 1968
Viktorova, Izv. Akad. Nauk SSSR Ser. Khim. (), 1968
Synthesis and reactivity of mixed alkynylalanes by direct triethylamine-catalyzed alumination of terminal alkynes.
Feuvrie C, Blanchet J, Bonin M, Micouin L., Org. Lett. 6(14), 2004
PMID: 15228272
Feuvrie C, Blanchet J, Bonin M, Micouin L., Org. Lett. 6(14), 2004
PMID: 15228272
AUTHOR UNKNOWN, 0
Schultz, Struct. Chem. 4(), 1993
Kasai, J. Am. Chem. Soc. 99(), 1977
Cox, J. Chem. Soc. Faraday Trans. 2 71(), 1975
Riedel, 1994
Ahmed, Acta Crystallogr. 5(), 1952
AUTHOR UNKNOWN, 0
Ketker, J. Mol. Struct. 77(), 1981
Almennmngen, Acta Crystallogr. 14(), 1961
AUTHOR UNKNOWN, 0
AUTHOR UNKNOWN, 0
AUTHOR UNKNOWN, 0
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