Tris(dimethylamino)phosphane as a new ligand in gold(I) chemistry: Synthesis and crystal structures of [(Me(2)N)(3)P]AuCl, {[(Me(2)N)(3)PAu]O-3}(BF4-)-B-+, {[(Me(2)N)(3)PAu]3NP(NMe(2))(3)}(2+) {BF4-}(2) and the precursor molecule (Me(2)N)(3)PNSiMe(3)
Bauer A, Mitzel NW, Schier A, Rankin DWH, Schmidbaur H (1997)
CHEMISCHE BERICHTE-RECUEIL 130(3): 323-328.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
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Autor*in
Bauer, A;
Mitzel, Norbert W.UniBi;
Schier, A;
Rankin, DWH;
Schmidbaur, H
Abstract / Bemerkung
[Tris(dimethylamino)phosphane]gold(I) chloride, mu(3)-tris-{[tris(dimethylamino)phosphane]gold(I)}oxonium tetrafluoroborate, {mu(3)-tris(dimethylamino)phosphaneimidotris[tris(dimethylamino)phosphan e]gold(I)}(2+) bis(tetrafluoroborate) and N-trimethylsilyltris(dimethylamino)phosphaneimine were prepared using modifications of established procedures. Their structures were determined in single-crystal X-ray diffraction studies. The ligand (Me(2)N)(3)P, here introduced into gold(I) chemistry for the first time, lends high stability to these compounds through efficient steric shielding of the reaction sites and through a balanced electronic substituent effect. The structural details of the (Me(2)N)(3)P groups are of current interest because of the unusual nonequivalent configuration of the nitrogen atoms in the dimethylamino groups. This behaviour has been observed for most of the (Me(2)N)(3)P units in the compounds studied in this work.
Stichworte
gold;
phosphaneimines;
phosphanes
Erscheinungsjahr
1997
Zeitschriftentitel
CHEMISCHE BERICHTE-RECUEIL
Band
130
Ausgabe
3
Seite(n)
323-328
ISSN
0009-2940
eISSN
1099-0682
Page URI
https://pub.uni-bielefeld.de/record/1928980
Zitieren
Bauer A, Mitzel NW, Schier A, Rankin DWH, Schmidbaur H. Tris(dimethylamino)phosphane as a new ligand in gold(I) chemistry: Synthesis and crystal structures of [(Me(2)N)(3)P]AuCl, {[(Me(2)N)(3)PAu]O-3}(BF4-)-B-+, {[(Me(2)N)(3)PAu]3NP(NMe(2))(3)}(2+) {BF4-}(2) and the precursor molecule (Me(2)N)(3)PNSiMe(3). CHEMISCHE BERICHTE-RECUEIL. 1997;130(3):323-328.
Bauer, A., Mitzel, N. W., Schier, A., Rankin, D. W. H., & Schmidbaur, H. (1997). Tris(dimethylamino)phosphane as a new ligand in gold(I) chemistry: Synthesis and crystal structures of [(Me(2)N)(3)P]AuCl, {[(Me(2)N)(3)PAu]O-3}(BF4-)-B-+, {[(Me(2)N)(3)PAu]3NP(NMe(2))(3)}(2+) {BF4-}(2) and the precursor molecule (Me(2)N)(3)PNSiMe(3). CHEMISCHE BERICHTE-RECUEIL, 130(3), 323-328. https://doi.org/10.1002/cber.19971300304
Bauer, A, Mitzel, Norbert W., Schier, A, Rankin, DWH, and Schmidbaur, H. 1997. “Tris(dimethylamino)phosphane as a new ligand in gold(I) chemistry: Synthesis and crystal structures of [(Me(2)N)(3)P]AuCl, {[(Me(2)N)(3)PAu]O-3}(BF4-)-B-+, {[(Me(2)N)(3)PAu]3NP(NMe(2))(3)}(2+) {BF4-}(2) and the precursor molecule (Me(2)N)(3)PNSiMe(3)”. CHEMISCHE BERICHTE-RECUEIL 130 (3): 323-328.
Bauer, A., Mitzel, N. W., Schier, A., Rankin, D. W. H., and Schmidbaur, H. (1997). Tris(dimethylamino)phosphane as a new ligand in gold(I) chemistry: Synthesis and crystal structures of [(Me(2)N)(3)P]AuCl, {[(Me(2)N)(3)PAu]O-3}(BF4-)-B-+, {[(Me(2)N)(3)PAu]3NP(NMe(2))(3)}(2+) {BF4-}(2) and the precursor molecule (Me(2)N)(3)PNSiMe(3). CHEMISCHE BERICHTE-RECUEIL 130, 323-328.
Bauer, A., et al., 1997. Tris(dimethylamino)phosphane as a new ligand in gold(I) chemistry: Synthesis and crystal structures of [(Me(2)N)(3)P]AuCl, {[(Me(2)N)(3)PAu]O-3}(BF4-)-B-+, {[(Me(2)N)(3)PAu]3NP(NMe(2))(3)}(2+) {BF4-}(2) and the precursor molecule (Me(2)N)(3)PNSiMe(3). CHEMISCHE BERICHTE-RECUEIL, 130(3), p 323-328.
A. Bauer, et al., “Tris(dimethylamino)phosphane as a new ligand in gold(I) chemistry: Synthesis and crystal structures of [(Me(2)N)(3)P]AuCl, {[(Me(2)N)(3)PAu]O-3}(BF4-)-B-+, {[(Me(2)N)(3)PAu]3NP(NMe(2))(3)}(2+) {BF4-}(2) and the precursor molecule (Me(2)N)(3)PNSiMe(3)”, CHEMISCHE BERICHTE-RECUEIL, vol. 130, 1997, pp. 323-328.
Bauer, A., Mitzel, N.W., Schier, A., Rankin, D.W.H., Schmidbaur, H.: Tris(dimethylamino)phosphane as a new ligand in gold(I) chemistry: Synthesis and crystal structures of [(Me(2)N)(3)P]AuCl, {[(Me(2)N)(3)PAu]O-3}(BF4-)-B-+, {[(Me(2)N)(3)PAu]3NP(NMe(2))(3)}(2+) {BF4-}(2) and the precursor molecule (Me(2)N)(3)PNSiMe(3). CHEMISCHE BERICHTE-RECUEIL. 130, 323-328 (1997).
Bauer, A, Mitzel, Norbert W., Schier, A, Rankin, DWH, and Schmidbaur, H. “Tris(dimethylamino)phosphane as a new ligand in gold(I) chemistry: Synthesis and crystal structures of [(Me(2)N)(3)P]AuCl, {[(Me(2)N)(3)PAu]O-3}(BF4-)-B-+, {[(Me(2)N)(3)PAu]3NP(NMe(2))(3)}(2+) {BF4-}(2) and the precursor molecule (Me(2)N)(3)PNSiMe(3)”. CHEMISCHE BERICHTE-RECUEIL 130.3 (1997): 323-328.
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