Hydrogen-bonded networks: (phosphine)gold(I) 4-amino-2-pyrimidine-thiolates
Wilton-Ely JDET, Schier A, Mitzel NW, Nogai S, Schmidbaur H (2002)
JOURNAL OF ORGANOMETALLIC CHEMISTRY 643-644: 313-323.
Zeitschriftenaufsatz
| Veröffentlicht | Englisch
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Autor*in
Wilton-Ely, JDET;
Schier, A;
Mitzel, Norbert W.UniBi;
Nogai, S;
Schmidbaur, H
Abstract / Bemerkung
Treatment of the gold(I) halide complexes LAuCl (where L = PMe3, PEt3, PPh3, PPh2Py) and PP(AuCl)(2) [where PP = bis(diphenylphosphino)methane 1,1'-bis(diphenylphosphino)ferrocene] with 4-amino-2-pvrimidine-thiol (2-SPym-4-NH2) (one or two equivalents as required) in the presence of sodium methoxide provides the corresponding (phosphine)gold(I) thiolate complexes LAu(2-SPym-4-NH2) and PP[Au(2-SPym-4-NH2)](2), respectively. A polyaurated product [(Ph3PAu)(2)(2-SPym-4-NH2)]BF4 is obtained on treating the thiol with the oxonium complex [(Ph3PAu)(3)O]BF4. The compounds LAu(2-SPym-4-NH2) (L = PPh3, PPh2Py, PEt3) and [(dppm)Au-2(2-SPym-4-NH2)(2)] have been investigated crystallographically. (C) 2002 Elsevier Science B.V. All rights reserved.
Stichworte
4-amino-2-pyrimidine-thiol;
tertiary phosphine complexes;
thiolate complexes;
gold(I) complexes;
hydrogen bonding;
aurophilicity
Erscheinungsjahr
2002
Zeitschriftentitel
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Band
643-644
Seite(n)
313-323
ISSN
0022-328X
Page URI
https://pub.uni-bielefeld.de/record/1928781
Zitieren
Wilton-Ely JDET, Schier A, Mitzel NW, Nogai S, Schmidbaur H. Hydrogen-bonded networks: (phosphine)gold(I) 4-amino-2-pyrimidine-thiolates. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 2002;643-644:313-323.
Wilton-Ely, J. D. E. T., Schier, A., Mitzel, N. W., Nogai, S., & Schmidbaur, H. (2002). Hydrogen-bonded networks: (phosphine)gold(I) 4-amino-2-pyrimidine-thiolates. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 643-644, 313-323. https://doi.org/10.1016/S0022-328X(01)01284-0
Wilton-Ely, JDET, Schier, A, Mitzel, Norbert W., Nogai, S, and Schmidbaur, H. 2002. “Hydrogen-bonded networks: (phosphine)gold(I) 4-amino-2-pyrimidine-thiolates”. JOURNAL OF ORGANOMETALLIC CHEMISTRY 643-644: 313-323.
Wilton-Ely, J. D. E. T., Schier, A., Mitzel, N. W., Nogai, S., and Schmidbaur, H. (2002). Hydrogen-bonded networks: (phosphine)gold(I) 4-amino-2-pyrimidine-thiolates. JOURNAL OF ORGANOMETALLIC CHEMISTRY 643-644, 313-323.
Wilton-Ely, J.D.E.T., et al., 2002. Hydrogen-bonded networks: (phosphine)gold(I) 4-amino-2-pyrimidine-thiolates. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 643-644, p 313-323.
J.D.E.T. Wilton-Ely, et al., “Hydrogen-bonded networks: (phosphine)gold(I) 4-amino-2-pyrimidine-thiolates”, JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 643-644, 2002, pp. 313-323.
Wilton-Ely, J.D.E.T., Schier, A., Mitzel, N.W., Nogai, S., Schmidbaur, H.: Hydrogen-bonded networks: (phosphine)gold(I) 4-amino-2-pyrimidine-thiolates. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 643-644, 313-323 (2002).
Wilton-Ely, JDET, Schier, A, Mitzel, Norbert W., Nogai, S, and Schmidbaur, H. “Hydrogen-bonded networks: (phosphine)gold(I) 4-amino-2-pyrimidine-thiolates”. JOURNAL OF ORGANOMETALLIC CHEMISTRY 643-644 (2002): 313-323.
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