Synthesis and structures of simple (silylmethyl)(methyl)ethers

Mitzel NW (2003)
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 58(8): 759-763.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Abstract / Bemerkung
The compound Cl3SiCH2OCH3 was prepared by reacting ClCH2OCH3 with the Cl3SiH/NEt3 reagent. H3SiCH2OCH3 and F3SiCH2OCH3 were synthesized from Cl3SiCH2OCH3 by reduction with LiAlH4 and by fluorination with SbF3, respectively. The crystal structures of the low-melting compounds H3SiCH2OCH3 and F3SiCH2OCH3 were determined by X-ray diffraction of in situ grown crystals. Both compounds do not show any observable beta-donor-acceptor interactions, but behave structurally like usual dialkylethers or silanes, as is obvious from the structural parameters in H3SiCH2OCH3 (
Stichworte
hypercoordination; silicon; crystal structure
Erscheinungsjahr
2003
Zeitschriftentitel
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
Band
58
Ausgabe
8
Seite(n)
759-763
ISSN
0932-0776
Page URI
https://pub.uni-bielefeld.de/record/1928698

Zitieren

Mitzel NW. Synthesis and structures of simple (silylmethyl)(methyl)ethers. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 2003;58(8):759-763.
Mitzel, N. W. (2003). Synthesis and structures of simple (silylmethyl)(methyl)ethers. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 58(8), 759-763.
Mitzel, N. W. (2003). Synthesis and structures of simple (silylmethyl)(methyl)ethers. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 58, 759-763.
Mitzel, N.W., 2003. Synthesis and structures of simple (silylmethyl)(methyl)ethers. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 58(8), p 759-763.
N.W. Mitzel, “Synthesis and structures of simple (silylmethyl)(methyl)ethers”, ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, vol. 58, 2003, pp. 759-763.
Mitzel, N.W.: Synthesis and structures of simple (silylmethyl)(methyl)ethers. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 58, 759-763 (2003).
Mitzel, Norbert W. “Synthesis and structures of simple (silylmethyl)(methyl)ethers”. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 58.8 (2003): 759-763.