Crystal structures of the supramolecular aggregates of the methyl and chloro substituted gallanes MexGaCl3-x
Lustig C, Mitzel NW (2004)
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 59(2): 140-147.
Zeitschriftenaufsatz
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Autor*in
Lustig, C;
Mitzel, Norbert W.UniBi
Abstract / Bemerkung
The crystal structures of the complete series of compounds of the general formula MexGaCl3-x have been determined. New polymorphs of GaCl3 and MeGaCl2 were found. All chloro compounds MexGaCl3-x (x = 0, 1, 2) are dimers with Ga2Cl2 four-membered rings. (GaCl3)(2) and (MeGaCl2)(2) are aggregated into layers with the same aggregation motif (each molecule connected to four neighbouring molecules), (Me2GaCl)(2) is associated in a ladder-like structure (each molecule connected to two neighbouring molecules), GaMe3 forms weakly Ga (. . .) C bound pseudo-tetramers aggregated into layers by further Ga-. (.) (.) C contacts (each molecule has two shorter Ga (. . .) C' and C (. . .) Ga' and two weaker Ga (. . .) C' and C (. . .) Ga' contacts).
Stichworte
crystal structure;
gallium;
supramolecular chemistry;
aggregation
Erscheinungsjahr
2004
Zeitschriftentitel
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
Band
59
Ausgabe
2
Seite(n)
140-147
ISSN
0932-0776
Page URI
https://pub.uni-bielefeld.de/record/1928690
Zitieren
Lustig C, Mitzel NW. Crystal structures of the supramolecular aggregates of the methyl and chloro substituted gallanes MexGaCl3-x. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 2004;59(2):140-147.
Lustig, C., & Mitzel, N. W. (2004). Crystal structures of the supramolecular aggregates of the methyl and chloro substituted gallanes MexGaCl3-x. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 59(2), 140-147. https://doi.org/10.1515/znb-2004-0204
Lustig, C, and Mitzel, Norbert W. 2004. “Crystal structures of the supramolecular aggregates of the methyl and chloro substituted gallanes MexGaCl3-x”. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 59 (2): 140-147.
Lustig, C., and Mitzel, N. W. (2004). Crystal structures of the supramolecular aggregates of the methyl and chloro substituted gallanes MexGaCl3-x. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 59, 140-147.
Lustig, C., & Mitzel, N.W., 2004. Crystal structures of the supramolecular aggregates of the methyl and chloro substituted gallanes MexGaCl3-x. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 59(2), p 140-147.
C. Lustig and N.W. Mitzel, “Crystal structures of the supramolecular aggregates of the methyl and chloro substituted gallanes MexGaCl3-x”, ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, vol. 59, 2004, pp. 140-147.
Lustig, C., Mitzel, N.W.: Crystal structures of the supramolecular aggregates of the methyl and chloro substituted gallanes MexGaCl3-x. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 59, 140-147 (2004).
Lustig, C, and Mitzel, Norbert W. “Crystal structures of the supramolecular aggregates of the methyl and chloro substituted gallanes MexGaCl3-x”. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 59.2 (2004): 140-147.
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