Photocycloaddition of Anthracene-Functionalized Monolayers on Silicon(100) Surface

Michelswirth M, Räkers M, Schäfer C, Mattay J, Neumann M, Heinzmann U (2010)
Journal of Physical Chemistry B 114(10): 3482-3487.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
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Autor/in
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Abstract / Bemerkung
Here we present detailed investigations of UV-photoinduced dimerization of anthracene Substructures Without solvent environment at the level of molecular monolayers prepared oil a surface. Monolayers prepared oil silicon(100) substrates were analyzed by means of X-ray photoelectron spectroscopy (XPS) in the valence band region revealing significant changes in the carbon C 2s region (11-20 eV). SVWN DFT calculations were performed to understand the influence of the Structural changes by dimerization. The geometric Structure of the functionality was retrieved through B3LYP DFT calculations, which were performed ahead of the SVWN DFT ones, and the result of these calculations matches with the measured vibration Signature. FTIR investigations of polybutadiene (PBD) Volume backboned Functionality were performed before and after irradiation.
Erscheinungsjahr
2010
Zeitschriftentitel
Journal of Physical Chemistry B
Band
114
Ausgabe
10
Seite(n)
3482-3487
ISSN
1520-6106
eISSN
1520-5207
Page URI
https://pub.uni-bielefeld.de/record/1796528

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Michelswirth M, Räkers M, Schäfer C, Mattay J, Neumann M, Heinzmann U. Photocycloaddition of Anthracene-Functionalized Monolayers on Silicon(100) Surface. Journal of Physical Chemistry B. 2010;114(10):3482-3487.
Michelswirth, M., Räkers, M., Schäfer, C., Mattay, J., Neumann, M., & Heinzmann, U. (2010). Photocycloaddition of Anthracene-Functionalized Monolayers on Silicon(100) Surface. Journal of Physical Chemistry B, 114(10), 3482-3487. doi:10.1021/jp910298a
Michelswirth, M., Räkers, M., Schäfer, C., Mattay, J., Neumann, M., and Heinzmann, U. (2010). Photocycloaddition of Anthracene-Functionalized Monolayers on Silicon(100) Surface. Journal of Physical Chemistry B 114, 3482-3487.
Michelswirth, M., et al., 2010. Photocycloaddition of Anthracene-Functionalized Monolayers on Silicon(100) Surface. Journal of Physical Chemistry B, 114(10), p 3482-3487.
M. Michelswirth, et al., “Photocycloaddition of Anthracene-Functionalized Monolayers on Silicon(100) Surface”, Journal of Physical Chemistry B, vol. 114, 2010, pp. 3482-3487.
Michelswirth, M., Räkers, M., Schäfer, C., Mattay, J., Neumann, M., Heinzmann, U.: Photocycloaddition of Anthracene-Functionalized Monolayers on Silicon(100) Surface. Journal of Physical Chemistry B. 114, 3482-3487 (2010).
Michelswirth, Martin, Räkers, Michael, Schäfer, Christian, Mattay, Jochen, Neumann, Manfred, and Heinzmann, Ulrich. “Photocycloaddition of Anthracene-Functionalized Monolayers on Silicon(100) Surface”. Journal of Physical Chemistry B 114.10 (2010): 3482-3487.

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